Inline solid state polymerization of pet flakes for manufacturing plastic strap

• US 5,886,058 A
• Filed: 02/03/1997
• Issued: 03/23/1999
• Est. Priority Date: 02/03/1997
• Status: Expired due to Term

• Current Assignee: Signode Industrial Group LLC (Crown Holdings Incorporated)
• Original Assignee: Illinois Tool Works Inc.
• Inventors: Van Erden, Donald, Enriquez, Manuel C., Vadnais, Gary L., Nelson, James P., Adams, Karl G.
• Primary Examiner(s): Short, Patricia A.
• Application Number:
  US08/794,538
• Time in Patent Office: 778 Days
• Field of Search: 521/48, 525/444, 528/308.3
• US Class Current: 521/48
• CPC Class Codes: B29B 17/02 Separating plastics from other materials
• CPC Class Codes: B29B 2017/0203 Separating plastics from plastics
• CPC Class Codes: B29B 2017/0279 Optical identification, e.g. cameras or spectroscopy
• CPC Class Codes: B29C 48/07 Flat, e.g. panels
• CPC Class Codes: B29C 48/285 Feeding the extrusion material to the extruder
• CPC Class Codes: B29C 48/287 Raw material pre-treatment while feeding B29C48/78 takes precedence
• CPC Class Codes: B29C 48/288 in solid form, e.g. powder or granules
• CPC Class Codes: B29K 2027/06 PVC, i.e. polyvinylchloride
• CPC Class Codes: B29K 2067/003 PET, i.e. poylethylene terephthalate
• CPC Class Codes: C08G 63/80 Solid-state polycondensation
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: C08J 2367/00 Characterised by the use of polyesters obtained by reactions forming a carboxylic ester link in the main chain of polyester-amides C08J2377/12; of polyester-imides C08J2379/08; Derivatives of such polymers
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling

Abstract

The present invention describes a process of making strap using both post consumer and non-post consumer PET of wide distribution intrinsic viscosity (IV) through direct solid state polymerization in a flaked state to produce PET with increased, heterogenous IV suitable for high performance strap extrusion. The process increases the IV of post-consumer resins, consisting principally of polyethylene terephthalate (PET), by chopping the post-consumer plastic into flakes and chunks, rolling the flakes and chunks, preheating the flakes, and further heating the flakes and chunks in an atmosphere of hot nitrogen gas, thereby increasing the intrinsic viscosity. PET polymers having increased viscosities according to the present invention provide a polymer useful in manufacturing high performance strap.

Claims

1. A process for making a polyethylene terephthalate (PET) material, comprising the steps of:

collecting diverse PET material having a wide distribution of intrinsic viscosity (IV) values, primarily within the range of 0.60 dl/g to 0.80 dl/g, but as high as 0.90 dl/g, and wherein the difference in said IV values of said collected PET material is at least 0.20 dl/g;

co-mingling said collected PET material and reforming said co-mingled PET material into a heterogeneous IV mixture of PET material comprised substantially of a plurality of non-uniform flake-like and chunk-like pieces; and

directly subjecting said heterogeneous IV mixture of PET material to solid state polymerization (SSP) so as to form a heterogeneous PET material having an average IV value of at least 0.85 dl/g.

2. The process of claim 1, further comprising the step of:

further reforming said co-mingled heterogeneous IV mixture of flake-like and chunk-like pieces by refining the chunk-like pieces into flake-like pieces.

3. The process of claim 2, wherein the step of further reforming said co-mingled heterogeneous IV mixture comprises the step of:

rolling said heterogeneous IV mixture of flake-like and chunk-like pieces under pressure so as to flatten said chunk-like pieces into flake-like pieces.

4. The process as set forth in claim 1, further comprising the step of:

identifying any PVC particles, found in said heterogeneous IV mixture of PET material formed during said collecting, co-mingling, and reforming steps, and removing said identified PVC particles, prior to said solid-state polymerization.

5. The process as set forth in claim 4, wherein the step of identifying and removing said PVC particles comprises the steps of:

heating said reformed heterogeneous IV mixture to a temperature at which said PVC particles turn a brown color; and

removing substantially all of said brown colored particles from said reformed heterogeneous IV mixture.

6. The process of claim 1 wherein said solid state polymerization step comprises the steps of:

incorporating a nitrogen cycle within said solid state polymerization; and

removing a majority of HCl contaminant, formed during said nitrogen cycle portion of said solid state polymerization step, by passing the nitrogen said nitrogen cycle, and including said HCl contaminant, through a guard bed of basic material.

7. The process as set forth in claim 1, wherein:

said formed heterogeneous PET material has an average IV value of at least 0.90 dl/g.

8. The process as set forth in claim 7, wherein:

said formed heterogeneous PET material has an IV range of 0.90 dl/g to 1.5 dl/g.

9. A process for making a polyethylene terephthalate (PET) material, suitable for use in making a high performance plastic strap, comprising the steps of:

collecting diverse PET material having a wide distribution of intrinsic viscosity (IV) values. Primarily within the range of 0.60 dl/g to 0.80 dl/g, but as high as 0.90 dl/g, and wherein the difference in said IV values of said collected PET material is at least 0.20 dl/g;

co-mingling said collected PET material and reforming said co-mingled PET material into a heterogeneous IV mixture of PET material comprised substantially of a plurality of non-uniform flake-like and chunk-like pieces; and

directly subjecting said heterogeneous IV mixture of PET material to solid state polymerization (SSP) so as to form a heterogeneous PET material having an average IV value of at least 0.85 dl/g.

10. The process as set forth in claim 9, further comprising the step of:

extruding said solid stated PET material so as to make a high performance plastic strap.

11. The process as set forth in claim 10 wherein:

said high performance plastic strap made with said solid stated PET material has an IV value of at least 0.90 dl/g.

12. The process as set forth in claim 9 wherein:

said formed heterogeneous PET material has an IV range of 0.90 dl/g to 1.5 dl/g.

13. The process as set forth in claim 9, wherein:

said formed heterogeneous PET material has an average IV value of at least 0.9 dl/g.

14. The process as set forth in claim 9, further comprising the step of:

further reforming said co-mingled heterogeneous IV mixture of flake-like and chunk-like pieces by refining said chunk-like pieces into flake-like pieces.

15. The process as set forth in claim 14, wherein the step of further reforming said co-mingled heterogeneous IV mixture comprises the step of:

rolling said heterogeneous IV mixture of flake-like and chunk-like pieces under pressure so as to flatten said chunk-like pieces into flake-like pieces.

16. The process as set forth in claim 9, further comprising the step of:

identifying any PVC particles, found in said heterogeneous IV mixture of PET material formed during said collecting, co-mingling, and reforming steps, and removing said identified PVC particles, prior to said solid-state polymerization.

17. The process as set forth in claim 16, Wherein the step of identifying and removing said PVC particles comprises the steps of:

heating said reformed heterogeneous IV mixture to a temperature at which said PVC particles turn a brown color; and

removing substantially all of said brown colored particles from said reformed heterogeneous IV mixture.

18. The process as set forth in claim 16, wherein said solid state polymerization step comprises the steps of:

incorporating a nitrogen cycle wihtin said solid state polymerization; and

removing a majority of HCl contaminant, formed during siad nitrogen cycle portion of said solid state polymerization step, by passing the nitrogen in said nitrogen cycle, and including said HCl contaminant, through a guard bed of basic material.