Apparatus comprising a catalytic distillation zone comprising a reaction zone with distribution of hydrogen

• US 5,888,355 A
• Filed: 12/27/1996
• Issued: 03/30/1999
• Est. Priority Date: 12/27/1995
• Status: Expired due to Term

• Current Assignee: Institut Francais Du Petrole
• Original Assignee: Institut Francais Du Petrole
• Inventors: Mikitenko, Paul, Didillon, Blaise, Dorbon, Michel, Montecot, Francoise, Cosyns, Jean, Nocca, Jean-Luc, Viltard, Jean-Charles, Travers, Christine, Cameron, Charles
• Primary Examiner(s): YILDIRIM, BEKIR L
• Application Number:
  US08/774,841
• Time in Patent Office: 823 Days
• Field of Search: 203/DIG. 6, 422/191, 422/192, 422/193, 422/194, 422/195
• US Class Current: 422/610
• CPC Class Codes: B01D 3/009 in combination with chemical reactions
• CPC Class Codes: B01J 8/0257 in a cylindrical annular shaped bed
• CPC Class Codes: B01J 8/0278 Feeding reactive fluids for solid material B01J8/0015
• CPC Class Codes: C07C 11/09 Isobutene
• CPC Class Codes: C07C 5/02 by hydrogenation simultaneous hydrogenation and dehydrogenation C07C5/52
• CPC Class Codes: C07C 5/2767 Changing the number of side-chains
• CPC Class Codes: C10G 45/00 Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
• CPC Class Codes: C10G 45/40 containing platinum group metals or compounds thereof
• CPC Class Codes: C10G 45/44 Hydrogenation of the aromatic hydrocarbons
• CPC Class Codes: C10G 49/002 Apparatus for fixed bed hydrotreatment processes
• CPC Class Codes: Y02P 20/10 Process efficiency
• CPC Class Codes: Y10S 203/06 Reactor-distillation

Abstract

The invention concerns a reactive distillation apparatus comprising a distillation zone, associated with a reaction zone which is at least in part internal to said distillation zone and comprises at least one catalytic bed in which the feed is transformed in the presence of a catalyst and at least one gas stream containing hydrogen, characterized in that each catalytic bed in the internal portion of said reaction zone is traversed by said gas stream and liquid in ascending co-current mode. The invention also concerns selective hydrogenation processes for light unsaturated hydrocarbons, mainly any olefins and benzene, comprised in a mixture the major portion of which is constituted by hydrocarbons containing at least five carbon atoms per molecule, and the hydroisomerisation of at least a portion of the 1-butene contained in a feed the major portion of which is constituted by olefinic hydrocarbons including isobutene, also 1-butene and 2-butenes in a ratio which substantially corresponds to the thermodynamic equilibrium.

Claims

1. A reactive distillation apparatus comprising a distillation section for producing distillation vapor and which comprises a stripping section and a rectification section associated with a reaction section, at least a portion of said reaction section being internal to said distillation section and comprising means for containing at least one catalytic bed enabling a feed to be transformed in the presence of a catalyst and at least one gas stream comprising hydrogen, said apparatus further comprising means for introducing said gas stream into said reaction section and means for passing an ascending co-current of said gas stream and liquid across the catalytic bed in the internal portion of said reaction section, means for compressing hydrogen, and further means for preventing distillation vapor from contacting the catalyst during operation of the apparatus.

2. An apparatus according to claim 1, comprising:

at least one means for distributing the major portion of the liquid from the bottom to the top through the catalyst;

at least one means for circulating the major portion of the distillation vapour from the bottom to the top through the catalytic bed such that said vapour is not in contact with the catalyst; and

a at least one means for distributing the major portion of the gas stream from the bottom to the top through the catalyst.

3. An apparatus according to claim 2 in which, for each catalytic bed in the internal portion of the reaction zone, the liquid distribution means is located below the catalytic bed and the gas stream distribution means is located below or in the catalytic bed.

4. An apparatus according to claim 2, in which the apparatus for introducing the gas stream into each catalytic bed is identical to the apparatus for distributing liquid in the catalytic bed, and that there is a means for introducing gas into the liquid upstream of the liquid distribution apparatus with respect to the direction of liquid circulation.

5. An apparatus according to claim 2, in which the gas stream introduction means is located substantially at the level of the liquid distribution means, the gas and liquid being introduced separately into the catalytic bed.

6. An apparatus according to claim 5, in which the gas stream introduction means is located in the catalytic bed.

7. An apparatus according to claim 5, in which the gas stream introduction means is located below the catalytic bed.

8. An apparatus according to claim 6, in which the gas stream introduction means is located near to the liquid distribution apparatus.

9. An apparatus according to claim 1, in which the reaction zone is completely internal to the distillation zone.

10. An apparatus according to claim 1, in which the internal portion of the reaction zone is at least partially incorporated in the rectification zone.

11. A reactive distillation apparatus according to claim 1, said apparatus further comprising means for recovering excess hydrogen.

12. A reactive distillation apparatus comprising a distillation section for producing distillation vapor and which comprises a stripping section and a rectification section associated with a reaction section, at least a portion of said reaction section being internal to said distillation section and comprising means for containing at least one catalytic bed enabling a feed to be transformed in the presence of a catalyst and at least one gas stream comprising hydrogen, said apparatus further comprising means for introducing said gas stream into said reaction section and means for passing an ascending co-current of said gas stream and liquid across the catalytic bed in the internal portion of said reaction section, and further means for preventing distillation vapor from contacting the catalyst during operation of the apparatus.

13. The apparatus according to claim 12, comprising:

at least one means for distributing the major portion of the liquid from the bottom to the top through the catalyst;

at least one means for circulating the major portion of the distillation vapor from the bottom to the top through the catalytic bed such that said vapor is not in contact with the catalyst; and

at least one means for distributing the major portion of the gas stream from the bottom to the top through the catalyst.

14. The apparatus according claim 13, in which, for each catalytic bed in the internal portion of the reaction zone, the liquid distribution means is located below the catalytic bed and the gas stream distribution means is located below or in the catalytic bed.

15. The apparatus according to claim 13, in which the apparatus for introducing the gas stream into each catalytic bed is identical to the apparatus for distributing liquid in the catalytic bed, and that there is a means for introducing gas into the liquid upstream of the liquid distribution apparatus (with respect to the direction of liquid circulation).

16. The apparatus according to claim 13, in which the gas stream introduction means is located substantially at the level of the liquid distribution means, the gas and liquid being introduced separately into the catalytic bed.

17. The apparatus according to claim 16, in which the gas stream introduction means is located in the catalytic bed.

18. The apparatus according to claim 16, in which the gas stream introduction means is located below the catalytic bed.

19. The apparatus according to claim 17, in which the gas stream introduction means is located near to the liquid distribution means.

20. The apparatus according to claim 12, in which the reaction section is completely internal to the distillation section.

21. The apparatus according to claim 12, in which the major portion of the gas stream is hydrogen.

22. The apparatus according to claim 12, in which the internal portion of the reaction section is at least partially incorporated in the rectification section.