Method for screen printing glass articles

• US 5,891,520 A
• Filed: 06/30/1997
• Issued: 04/06/1999
• Est. Priority Date: 06/30/1997
• Status: Expired due to Fees

• Current Assignee: MCC Dec Tech, LLC
• Original Assignee: Avery Dennison Corporation
• Inventors: Caruso, Paul J., Makar, Onsy Y.
• Primary Examiner(s): Beck, Shrive
• Assistant Examiner(s): PARKER, FREDERICK JOHN
• Application Number:
  US08/884,713
• Time in Patent Office: 645 Days
• Field of Search: 427/282, 427/389, 427/384, 427/407.2, 427/269, 427/287, 101/129, 106/31.05, 106/31.49, 106/31.58, 106/31.78, 106/31.86, 524/88, 524/560, 524/601, 524/847
• US Class Current: 427/269
• CPC Class Codes: B32B 17/10247 Laminated safety glass or glazing containing decorations or patterns for aesthetic reasons containing metal wires for aesthetic reasons B32B17/10422
• CPC Class Codes: B32B 17/10266 on glass pane
• CPC Class Codes: B32B 17/10688 Adjustment of the adherence to the glass layers
• CPC Class Codes: B41M 1/12 Stencil printing; Silk-screen printing
• CPC Class Codes: B41M 1/34 on glass or ceramic surfaces ink-jet printing on glass or ceramic surfaces B41M5/00
• CPC Class Codes: B41M 7/009 using thermal means, e.g. infrared radiation, heat
• CPC Class Codes: C03C 17/34 with at least two coatings having different compositions C03C17/44 takes precedence
• CPC Class Codes: C03C 17/3405 with at least two coatings of organic materials C03C17/36, C03C17/42 take precedence
• CPC Class Codes: C03C 2217/445 Organic continuous phases
• CPC Class Codes: C03C 2217/477 Titanium oxide
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2217/485 Pigments
• CPC Class Codes: C04B 2103/54 Pigments; Dyes
• CPC Class Codes: C04B 33/00 Clay-wares monolithic refractories or refractory mortars C04B35/66; porous products C04B38/00
• CPC Class Codes: C04B 41/0072 Heat treatment
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/463 Organic solvents
• CPC Class Codes: C04B 41/48 Macromolecular compounds
• CPC Class Codes: C04B 41/4922 applied to the substrate as monomers, i.e. as organosilanes RnSiX4-n, e.g. alkyltrialkoxysilane, dialkyldialkoxysilane
• CPC Class Codes: C04B 41/5089 Silica sols, alkyl, ammonium or alkali metal silicate cements
• CPC Class Codes: C04B 41/52 : Multiple coating or impregnating multiple coating or impregnating with the same composition or with compositions only differing in the concentration of the constituents, is classified as single coating or impregnation
• CPC Class Codes: C04B 41/89 : for obtaining at least two superposed coatings having different compositions
• CPC Class Codes: C09D 11/10 : based on artificial resins

Abstract

A method for decorating and/or labelling glass articles and like ceramic ware by screen printing. The present method comprises the steps of (a) treating a glass article or the like with a silane adhesion promoter; and (b) applying a non-ceramic screen ink directly onto the silane-treated glass article by screen printing. The non-ceramic screen ink is preferably a heat-set ink which includes an organic resinous binder, a non-heavy metal colorant and a vaporizable solvent system. Examples of the binder include, but are not limited to, one or more of polyamide, polyester, polyester-vinyl, acrylic, vinyl and acrylic-vinyl resins. Examples of the non-heavy metal colorant include titanium dioxide and organic colorants (e.g., insoluble derivatives of organic dyes). The non-ceramic screen ink may additionally comprise one or more rheology-adjusting agents for making the ink well-suited for screen printing and may additionally include other additives of the type commonly found in screen or other printing inks. Once the ink has been applied to the glass article by screen printing, the printed article is preferably heated, causing the solvent system to be driven off and causing the binder, colorant and other non-volatile components of the ink to be set on the article.

Claims

1. A method for decorating a glass article, said method comprising the steps of:

(a) treating the glass article with a silane adhesion promoter;

(b) screen printing a screen ink directly onto the silane-treated glass article, said screen ink being a heat-set ink comprising an organic resinous binder, a non-heavy metal colorant and an organic solvent system; and

(c) heating the screen-printed, silane-treated glass article to a temperature of about 400°

F. whereby the organic solvent system is evaporated therefrom and the organic resinous binder and the non-heavy metal colorant become set thereon.

2. The method as claimed in claim 1 wherein said organic resinous binder is selected from the group consisting of one or more of polyamide, polyester, polyester-vinyl, acrylic, vinyl and acrylic-vinyl binders.

3. The method as claimed in claim 2 wherein said organic resinous binder is a polyamide binder.

4. The method as claimed in claim 2 wherein said organic resinous binder is a polyester binder.

5. The method as claimed in claim 2 wherein said organic resinous binder is an acrylic binder.

6. The method as claimed in claim 1 wherein said non-heavy metal colorant is selected from the group consisting of titanium dioxide and organic colorants.

7. The method as claimed in claim 6 wherein said non-heavy metal colorant is titanium dioxide.

8. The method as claimed in claim 6 wherein said non-heavy metal colorant is an organic colorant.

9. The method as claimed in claim 1 wherein said screen ink further includes a rheology-adjusting agent.

10. The method as claimed in claim 9 wherein said rheology-adjusting agent is a silica.

11. The method as claimed in claim 1 wherein said screen ink comprises 18.0%, by weight, of a copolyester resin having a tensile strength of 7000 psi and 4% elongation;

7.0%, by weight, of phthalocyanine;

45.0%, by weight, of toluene;

27.0%, by weight, of n-propyl acetate; and

3.0%, by weight, of a synthetic amorphous silica.

12. The method as claimed in claim 1 wherein said screen ink comprises 21.0%, by weight, of an isobutyl methacrylate resin having an inherent viscosity of 0.64 as measured in a solution containing 0.25 g of polymer in 50 ml methylene chloride, measured at 20°

C. using a No. 50 Cannon-Fenske Viscometer;

7.0%, by weight, of phthalocyanine;

36.0%, by weight, of toluene;

33.0%, by weight, of methyl ethyl ketone; and

3.0%, by weight, of a synthetic amorphous silica.

13. The method as claimed in claim 1 wherein said treating step comprises applying a silane solution to the glass article and then heating the glass article so as to evaporate the volatile components of the silane solution from the glass article.