Production process of active carbon used for electrode for organic solvent type electric double layer capacitor

• US 5,891,822 A
• Filed: 09/16/1997
• Issued: 04/06/1999
• Est. Priority Date: 09/17/1996
• Status: Expired due to Term

• Current Assignee: Honda Giken Kogyo Kabushiki Kaisha (Honda Motor Company)
• Original Assignee: Honda Giken Kogyo Kabushiki Kaisha (Honda Motor Company)
• Inventors: Noguchi, Minoru, Oyama, Shigeki, Oki, Naohiko
• Primary Examiner(s): Lewis, Michael
• Assistant Examiner(s): Hendrickson, Stuart L.
• Application Number:
  US08/931,685
• Time in Patent Office: 567 Days
• Field of Search: 423/460, 423/445 R, 502/423, 502/427
• US Class Current: 502/427
• CPC Class Codes: C01B 32/342 characterised by non-gaseous activating agents
• CPC Class Codes: H01G 11/24 characterised by structural features of the materials making up or comprised in the electrodes, e.g. form, surface area or porosity; characterised by the structural features of powders or particles used therefor
• CPC Class Codes: H01G 11/34 characterised by carbonisation or activation of carbon
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors

Abstract

Disclosed herein is a process for producing active carbon suitable for use in electrodes for an organic solvent type electric double layer capacitor, comprising calcining an easily graphitizable organic substance and then subjecting the resultant carbonized product to an alkali activation treatment, wherein the alkali activation treatment comprises a first alkali activation treatment at a temperature within a first range and a second alkali activation treatment at a temperature within a second range, said temperature within the second range being higher than that of the first activation treatment, and one of both alkali activation treatments is performed after the other alkali activation treatment.

Claims

1. A process for producing active carbon suitable for use in an electrode of an organic solvent-containing electric double layer capacitor, the process comprising

(a) carbonizing an organic substance, to produce a carbonized product;

(b) combining the carbonized product with an activator comprising an alkali metal hydroxide, to produce an activatable product; and

(c) (1) subjecting the activatable product to a first activation treatment by heating the activatable product to a first temperature between 600°

C. and 950°

C., and

(2) subjecting the activatable product to a second activation treatment by heating the activatable product to a second temperature, wherein the second temperature is higher than the first temperature,

wherein the second activation treatment is conducted subsequent to the first activation treatment, or vice versa.

2. The process of claim 1, wherein the second activation treatment is conducted subsequent to the first activation treatment.

3. The process of claim 1, wherein the first activation treatment is conducted subsequent to the second activation treatment.

4. The process of claim 1, wherein the organic substance is a vinyl chloride resin.

5. The process of claim 1, wherein the carbonizing step (a) comprises heating the organic substance to a temperature lower than 700°

C.

6. The process of claim 1, wherein the subjecting step (c)(1) comprises heating the activatable product to a first temperature between 600°

C. and 950°

C. for a time period of 1-20 hours.

7. The process of claim 1, wherein the second temperature is between 800°

C. and 1000°

C.

8. The process of claim 1, wherein the subjecting step (c)(2) comprises heating the activatable product to a second temperature between 800°

C. and 1000°

C. for a time period of at most 2 hours.

9. The process of claim 1, wherein the subjecting step (c)(2) comprises heating the activatable product to a second temperature between 800°

C. and 1000°

C., and thereafter immediately lowering the temperature.

10. The process of claim 1, wherein the alkali metal hydroxide is selected from the group consisting of lithium hydroxide, sodium hydroxide and potassium hydroxide.

11. The method of claim 1, wherein the activator is present in an amount of from 1-4 parts by weight per 1 part by weight of the carbonized product.

12. The method of claim 1, further comprising, between steps (a) and (b), grinding the carbonized product into particles having a particle size between 0.1 and 300 μ

m.