Agriculture residue based absorbent material and method for manufacture

• US 5,891,937 A
• Filed: 03/11/1996
• Issued: 04/06/1999
• Est. Priority Date: 12/12/1994
• Status: Expired due to Term

• Current Assignee: Regents of The University of Minnesota (University of Minnesota)
• Original Assignee: Regents of The University of Minnesota (University of Minnesota)
• Inventors: Adams, Roy D., Brashaw, Brian K., Vatalaro, Robert J., Berg, Larry E., Edwardson, Chris F.
• Primary Examiner(s): Seidleck, James J.
• Assistant Examiner(s): Asinovsky, Olga
• Application Number:
  US08/614,954
• Time in Patent Office: 1,121 Days
• Field of Search: 524/13, 524/14, 524/15, 524/18, 524/25, 524/35, 524/47, 428/221, 428/224, 428/243, 428/393, 428/394, 428/503, 428/507
• US Class Current: 524/13
• CPC Class Codes: A01G 13/0262 Mulches, i.e. covering material not-pre-formed in mats or sheets A01G13/0281 takes precedence; composition of mulches C09K17/52
• CPC Class Codes: A01G 24/22 containing plant material
• CPC Class Codes: A01G 24/44 in block, mat or sheet form
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: C08L 99/00 Compositions of natural macromolecular compounds or of derivatives thereof not provided for in groups C08L89/00 - C08L97/00
• CPC Class Codes: E02B 15/06 Barriers therefor E02B15/08 takes precedenceconstrued for applying processing agents or for collecting pollutants, e.g. absorbent
• CPC Class Codes: Y10T 428/249921 Web or sheet containing structurally defined element or component
• CPC Class Codes: Y10T 428/2965 Cellulosic
• CPC Class Codes: Y10T 428/2967 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/31866 Impregnated or coated cellulosic material

Abstract

An absorbent agriculture residue product and method of making the product. Preferably the agriculture residue material is reduced in size, adhesive added, consolidated to form panels or other shapes and heated to cure the adhesive. Preferably, the agriculture material is reduced in size from less than about 2 inches and the adhesive is present in an amount ranging from between about 2% to about 20% by dry weight. The products possess good absorption characteristics, durability and the ability to retain absorbed liquids upon application of pressure to saturated panels.

Claims

1. A process for producing a rigid absorbent panel from an agriculture residue material and an adhesive, comprising the steps of:

(a) reducing the agriculture residue material to form particles of a predetermined size;

(b) admixing the adhesive to the particles, wherein the adhesive is present in an amount sufficient to form a pliable blend of the agricultural residue material and the adhesive;

(c) forming a mass of particles from the pliable blend; and

(d) subjecting the mass of particles to a predetermined pressure per square inch and an elevated temperature for a pre-determined period of the to cure the adhesive and to form a rigid panel of desired thickness capable of withstanding varied loads and having a modulus of rupture of at least about 60 psi or greater, a modulus of elasticity of approximately 16,500 psi or greater and a density of approximately 40 pcf or less;

wherein said absorbent panel has oil absorbing properties, strength, low density, is hard and rigid, and has essentially no thickness swell with oil absorption.

2. The process of claim 1 wherein the agriculture residue material is selected from a group consisting of:

corn residue, wheat straw, rye, barley, prairie grass, alfalfa straw, flax straw, and combinations thereof.

3. The process of claim 2 further comprising the step of classifying the reduced agriculture residue particles by passage through a number 2 screen and being retained by a number 150 screen prior to admixing the adhesive.

4. The process of claim 1 further comprising the step of:

drying the particles of the agriculture residue material to a moisture content from between about 1% to about 10% prior to admixing the adhesive.

5. The process of claim 1, wherein the adhesive is added in an amount ranging from between about 2% to about 20% based on total dry weight of the agricultural residue material, wherein the adhesive is selected from a group consisting of:

synthetic resins and natural resins.

6. The process of claim 5, wherein the adhesive is added in an amount between about 5% to about 8% based on total dry weight of the agricultural residue product, and wherein the adhesive is selected from a group consisting of:

phenol-formaldehyde resins, phenol-resorcinol-formaldehyde resins, urea-formaldehyde resins, melamine resins, melamine-urea resins, polyvinyl resin emulsions, thermosetting polyvinyl acetate emulsions, polyurethane-based resins, isocyanate-based resins, acrylics, polyesters, and epoxy resins.

7. The process of claim 1 wherein the predetermined pressure is applied perpendicularly to the surface of the mass of particles, the predetermined pressure being about 500 pounds per square inch.

8. The process of claim 7 further comprising:

heating the mass of particles at a temperature about 380 degrees Fahrenheit for the predetermined period of time; and

reducing the pressure to about 100 pounds per square inch, and wherein the predetermined period of time ranges from about 10 minutes to about 20 minutes.

9. The process of claim 8 wherein the panel has a surface, and wherein the process further comprises the step of:

applying a textured sheet to the surface of the panel, such that an irregular surface is produced on the panel.

12. The process of claim 1 wherein the mass of particles is subjected to an elevated temperature and pressure simultaneously.

13. The process of claim 12 wherein the mass of particles is subjected to an elevated temperature for between approximately 1 minute to 30 minutes to cure the adhesive to form a rigid panel having sufficient strength.

14. The process of claim 12 wherein the mass of particles is subjected to a pressure of approximately 500 psi for a predetermined period of time and subjected to a reduced pressure of 100 psi thereafter until the adhesive is cured to form a rigid panel having sufficient strength.

15. The process of claim 14 wherein the mass of particles is subjected to a pressure of approximately 500 psi for about 30 seconds and thereafter 100 psi until the adhesive is cured to form a rigid panel.

16. The process of claim 1 wherein the adhesive is cured at a temperature ranging between 300°

-500°

F.

10. An absorbent panel comprising:

agricultural residue particles; and

a cured adhesive mixed with the agricultural residue particles,

wherein the absorbent panel absorbs oil products, is hard and rigid, has essentially no thickness swell with oil absorption, has a density from between about 15 to about 40 pounds per cubic foot, has a modulus of rupture of at least about 60 psi or greater, and has a modulus of elasticity of approximately 16,500 psi or greater.

11. The absorbent panel of claim 10 wherein the agriculture residue material comprises approximately 90%-98% corn residue particles having a size less than about 1 inch.

17. The absorbing panel of claim 10 wherein the agricultural residue particles comprise about 80% to 95% and the adhesive comprises about 5% to 20%.

18. The absorbing panel of claim 10 wherein the adhesive comprises 1 to about 5 parts of a dry adhesive, and water at about 15 to about 19 parts relative to the dry adhesive.