Coating composition with improved water and mar resistance

• US 5,891,942 A
• Filed: 05/01/1997
• Issued: 04/06/1999
• Est. Priority Date: 05/01/1997
• Status: Expired due to Fees

• Current Assignee: Fibre Glass-Evercoat Company, Inc.
• Original Assignee: Fibre Glass-Evercoat Company, Inc.
• Inventors: Fron, William Ronald, Parish, David Michael
• Primary Examiner(s): Morgan, Kriellion S.
• Application Number:
  US08/847,115
• Time in Patent Office: 705 Days
• Field of Search: 524/181, 524/284, 524/493, 524/789, 526/318, 526/318.1
• US Class Current: 524/284
• CPC Class Codes: C08F 283/00 Macromolecular compounds obtained by polymerising monomers on to polymers provided for in subclass C08G
• CPC Class Codes: C08F 291/00 Macromolecular compounds obtained by polymerising monomers on to macromolecular compounds according to more than one of the groups C08F251/00 - C08F289/00
• CPC Class Codes: C09D 4/06 Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09D159/00 - C09D187/00

Abstract

The present invention is directed to a sprayable coating composition having improved water resistance, improved mar resistance and generally improved physical properties, and a method of using such a coating. The sprayable coating composition comprises a resin system comprising from about 30 to about 96 weight percent of a resin component, from about 1 to about 30 weight percent of a multifunctional acrylate component, and from about 1 to about 15 weight percent of a monofunctional acrylate component; and a catalyst component. The resin system is blended with the catalyst component, either internally or externally of a spray nozzle, and the resultant sprayable coating composition is sprayed onto a substrate. The resulting cured coating provides a surface which is water resistant, is mar resistant, and has generally improved physical properties.

Claims

1. A sprayable coating composition comprising, by approximate weight percent:

a resin system comprising from about 30 to about 96 weight percent of a resin component including a resin and a reactive diluent, from about 1 to about 30 weight percent of a mixture of a difunctional acrylate component selected from the group consisting of alkoxylated aliphatic diacrylate, 1,4-butanediol diacrylate, 1,4-butanediol dimethacrylate, 1,3-butylene glycol diacrylate, 1,3-butylene glycol dimethacrylate, 1,6-hexanediol diacrylate (HDODA), 1,6-hexanediol dimethacrylate, neopentyl glycol diacrylate, neopentyl glycol dimethacrylate, polyethylene glycol diacrylate, polyethylene glycol dimethacrylate, propoxylated neopentyl glycol diacrylate, tetraethylene glycol diacrylate, tetraethylene glycol dimethacrylate, triethylene glycol diacrylate, triethylene glycol dimethacrylate, tripropylene glycol diacrylate and mixtures thereof and a trifunctional acrylate component, selected from the group consisting of propoxylated glyceryl triacrylate, ethoxylated trimethylol propane triacrylate, pentaerythritol triacrylate, propoxylated glyceryl triacrylate, propoxylated timethylpropane triacrylate, trimethylolpropane triacrylate (TMPTA), trimethylolpropane trimethacrylate, tris (2-hydroxyethyl) isocyanurate triacrylate, tris (2-hydroxyethyl) isocyanurate trimethacrylate and mixtures thereof and from about 1 to about 15 weight percent of a monofunctional acrylate component; and

a catalyst component.

2. The composition of claim 1 wherein the resin component is styrene free.

3. The coating composition of claim 2 wherein the resin is selected from the group consisting of isophthalic esters, vinyl esters, vinyl polyesters, bisphenols, unsaturated acrylic resins, and mixtures thereof.

4. The composition of claim 1 wherein the monofunctional acrylate component is selected from the group consisting of allyl methacrylate, caprolactone methacrylate, 2(2-ethoxyethoxy)ethylacrylate, ethoxylated nonyl phenol acrylate, glycidyl methacrylate, isobornyl acrylate, isobornyl methacrylate, isodecyl acrylate, isodecyl methacrylate, isoctyl acrylate, lauryl acrylate, lauryl methacrylate, 2-phenoxy acrylate, 2-phenoxy methacrylate, polypropylene glycol monomethacrylate, stearyl acrylate, stearyl methacrylate, tetrahydrofurfuryl acrylate, tetrahydrofurfuryl methacrylate, tridecyl acrylate, tridecyl methacrylate, 2-hydroxyethyl acrylate, 2-hydroxyethyl methacrylate (HEMA) and mixtures thereof.

5. The composition of claim 1 further including up to about 0.75 weight percent of a polymerization promoter.

6. The composition of claim 5 wherein the polymerization promoter is a cobalt salt of an organic acid.

7. The composition of claim 5 further including up to about 2 weight percent of a co-promoter.

8. The composition of claim 7 wherein the co-promoter is a potassium salt of an organic acid.

9. The composition of claim 1 further including up to about 1.0 weight percent of an air release agent selected from the group consisting of a solution of foam destroying polymers, polydimethylsiloxanes and mixtures thereof.

10. The composition of claim 1 further including up to about 1.0 weight percent of an anti-settling additive selected from the group consisting of a solution of polyamine amides and acidic polyesters, organoclays and mixtures thereof.

11. The composition of claim 1 further including up to 30 weight percent of a pigment.

12. The composition of claim 11 wherein the pigment is selected from the group consisting of organic pigments, inorganic pigments and mixtures thereof.

13. The composition of claim 12 further including up to about 30 weight percent of a pigment extender selected from the group consisting of alumina trihydrate, calcium carbonate, lithopone and mixtures thereof.

14. The composition of claim 1 further including up to about 2.0 weight percent of a thixotropic agent selected from the group consisting of hydrophilic fumed silica, hydrophobic fumed silica, and organoclay compounds.

15. The composition of claim 14 further including up to about 0.5 weight percent of a synergist for the thixotropic agent.

16. The composition of claim 1 further including up to 1.0 weight percent of a UV stabilizer.

17. The composition of claim 1 further including up to about 0.5 weight percent of on accelerating agent.

18. The composition of claim 1 wherein the resin system comprises from about 40 to about 70 weight percent of the resin component;

from about 1 to about 15 weight percent of the difunctional acrylate component and from about 1 to about 15 weight percent of the trifunctional acrylate component and from about 1 to about 12 weight percent of the monofunctional acrylate component.

19. The composition of claim 18 further comprising up to about 1.5 wt. % of a thixotropic agent;

up to about 0.3 wt. % of an activating agent;

up to about 20 wt. % of a pigment;

up to about 20 wt. % of a pigment extender;

up to about 0.75 wt. % of an anti-settling additive;

up to about 0.75 wt. % of an anti-foaming additive;

up to about 0.25 wt. % of an accelerating agent;

up to about 0.75 wt. % of an UV stabilizer;

up to about 0.5 wt. % of a promoter; and

up to about 1.5 wt. % of a co-promoter.

20. The composition of claim 19 further comprising up to about 1.0 wt. % of a thixotropic agent;

up to about 0.25 wt. % of an activating agent;

up to about 10 wt. % of a pigment;

up to about 10 wt. % of a pigment extender;

up to about 0.5 wt. % of an anti-settling additive;

up to about 0.5 wt. % of an anti-foaming additive;

up to about 0.10 wt. % of an accelerating agent;

up to about 0.5 wt. % of an UV stabilizer;

up to about 0.3 wt. % of a promoter; and

up to about 1.0 wt. % of a co-promoter.