Desulfurization and decarbonation process

• US 5,895,634 A
• Filed: 05/20/1997
• Issued: 04/20/1999
• Est. Priority Date: 05/28/1996
• Status: Expired due to Term

• Current Assignee: mitsubishi hitachi power systems, ltd. (Mitsubishi Heavy Industries, Ltd.)
• Original Assignee: Mitsubishi Heavy Industries, Ltd.
• Inventors: Tanaka, Hiroshi, Iijima, Masaki, Mitsuoka, Shigeaki
• Primary Examiner(s): Straub, Gary P.
• Assistant Examiner(s): Vanoy, Timothy C.
• Application Number:
  US08/859,113
• Time in Patent Office: 700 Days
• Field of Search: 423/555, 423/243.08, 423/243.01, 423/229, 423/228, 423/220
• US Class Current: 423/220
• CPC Class Codes: B01D 53/507 by treating the gases with other liquids
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: B01D 53/75 Multi-step processes
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

This invention provides a process for effecting desulfurization and decarbonation in two stages. A gas containing sulfur oxides and carbon dioxide is first treated in a desulfurization step so as to cause sulfur oxides to be absorbed in the form of calcium-sulfur oxide compounds; the gas is then treated in a decarbonation step so as to cause carbon dioxide and any sulfur oxides escaping from the desulfurization step to be absorbed in the form of amine salts; the absorbing solution containing the amine salts is regenerated by liberating carbon dioxide therefrom; a part of the regenerated absorbing solution is recycled to the decarbonation step while the remainder of the absorbing solution is fed to a secondary regeneration step where it is treated with a basic calcium substance to regenerate basic amine compound for recycle and to form a solid containing calcium-sulfur oxide compounds and calcium carbonate.

Claims

1. A desulfurization and decarbonation process for treating a gas containing sulfur oxides and carbon dioxide which comprises:

a desulfurization step comprising treating the gas with a basic calcium substance, wherein the gas containing sulfur oxides and carbon dioxide is treated so as to cause sulfur oxides to be absorbed to result in the formation of calcium-sulfur oxide compounds;

a step for separating and discharging the resulting calcium salts;

a decarbonation step subsequent to the desulfurization step comprising further treating the gas with an absorbing solution containing a basic amine compound, that causes carbon dioxide and sulfur oxides escaping from the desulfurization step to be absorbed in the form of amine salts;

a first regeneration step for the absorbing solution, wherein the absorbing solution containing the amine salts is treated to liberate carbon dioxide therefrom;

recycling step, wherein a portion of the regenerated amine absorbing solution is recycled back to the decarbonation step,

a subsequent secondary regeneration step, wherein the remainder of the regenerated amine absorbing solution is treated with a basic calcium substance to result in the formation of calcium-sulfur oxide compounds, and

a subsequent solid-liquid separation step, wherein the calcium-sulfur compounds formed in the secondary regeneration step are separated from the absorbing solution, the separated solids are recycled to the desulfurization step for use as the basic calcium substance and the separated absorbing solution is recycled to the decarbonation step for use as the absorbing solution.

2. A desulfurization and decarbonation process as claimed in claim 1, wherein the regeneration of the absorbing solution in the secondary regeneration step is carried out using a basic calcium substance including at least one selected from the group consisting of calcium hydroxide, calcium oxide, calcium carbonate and calcium hydrogen carbonate.

3. A desulfurization and decarbonation process as claimed in claim 1, wherein the basic calcium substance used in the desulfurization step is a substance including at least one selected from the group consisting of calcium hydroxide, calcium oxide, calcium carbonate and calcium hydrogen carbonate.

4. A desulfurization and decarbonation process as claimed in claim 1, wherein the portion of the absorbing solution fed to the secondary regeneration step is in the range of 50 to 100% by volume based on the total of the absorbing solution.

5. A desulfurization and decarbonation process as claimed in claim 1, wherein said gas is a fuel or an exhaust gas resulting from the combustion of fuel.

6. A desulfurization and decarbonation process as claimed in claim 1, wherein said gas includes water, nitrogen oxides, oxygen and/or other acid gases.

7. A desulfurization and decarbonation process as claimed in claim 1, wherein said gas is a combustion exhaust gas comprising 300 to 5,000 ppm of sulfur oxides and 3 to 15% by volume of carbon dioxide.

8. A desulfurization and decarbonation process as claimed in claim 1, wherein the basic calcium substance is in the form of a solid, an aqueous solution or an aqueous suspension.

9. A desulfurization and decarbonation process as claimed in claim 1, wherein said basic amine compound is selected from the group consisting of monoethanolamine, diethanolamine, butylethanolamine, dimethylaminoethanol, methylpyrrolidone, methylaminocarboxylic acids, and mixtures thereof.

10. A desulfurization and decarbonation process as claimed in claim 1, wherein 90 to 99% of sulfur oxides present in said gas are removed in said desulfurization step by treating the gas with said basic calcium substance.

11. A desulfurization and decarbonation process as claimed in claim 1, wherein said solid-liquid separation is accomplished using a decanter or a dehydrator which optionally includes a rinsing mechanism.

12. A desulfurization and decarbonation process as claimed in claim 1, wherein the proportion of absorbing solution having liberated carbon dioxide fed to said secondary regeneration step is not less than 1% by volume based on the total volume of the absorbing solution.