Desulfurization and decarbonation process
First Claim
1. A desulfurization and decarbonation process for treating a gas containing sulfur oxides and carbon dioxide which comprises:
- a desulfurization step comprising treating the gas with a basic calcium substance, wherein the gas containing sulfur oxides and carbon dioxide is treated so as to cause sulfur oxides to be absorbed to result in the formation of calcium-sulfur oxide compounds;
a step for separating and discharging the resulting calcium salts;
a decarbonation step subsequent to the desulfurization step comprising further treating the gas with an absorbing solution containing a basic amine compound, that causes carbon dioxide and sulfur oxides escaping from the desulfurization step to be absorbed in the form of amine salts;
a first regeneration step for the absorbing solution, wherein the absorbing solution containing the amine salts is treated to liberate carbon dioxide therefrom;
recycling step, wherein a portion of the regenerated amine absorbing solution is recycled back to the decarbonation step,a subsequent secondary regeneration step, wherein the remainder of the regenerated amine absorbing solution is treated with a basic calcium substance to result in the formation of calcium-sulfur oxide compounds, anda subsequent solid-liquid separation step, wherein the calcium-sulfur compounds formed in the secondary regeneration step are separated from the absorbing solution, the separated solids are recycled to the desulfurization step for use as the basic calcium substance and the separated absorbing solution is recycled to the decarbonation step for use as the absorbing solution.
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Abstract
This invention provides a process for effecting desulfurization and decarbonation in two stages. A gas containing sulfur oxides and carbon dioxide is first treated in a desulfurization step so as to cause sulfur oxides to be absorbed in the form of calcium-sulfur oxide compounds; the gas is then treated in a decarbonation step so as to cause carbon dioxide and any sulfur oxides escaping from the desulfurization step to be absorbed in the form of amine salts; the absorbing solution containing the amine salts is regenerated by liberating carbon dioxide therefrom; a part of the regenerated absorbing solution is recycled to the decarbonation step while the remainder of the absorbing solution is fed to a secondary regeneration step where it is treated with a basic calcium substance to regenerate basic amine compound for recycle and to form a solid containing calcium-sulfur oxide compounds and calcium carbonate.
25 Citations
12 Claims
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1. A desulfurization and decarbonation process for treating a gas containing sulfur oxides and carbon dioxide which comprises:
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a desulfurization step comprising treating the gas with a basic calcium substance, wherein the gas containing sulfur oxides and carbon dioxide is treated so as to cause sulfur oxides to be absorbed to result in the formation of calcium-sulfur oxide compounds; a step for separating and discharging the resulting calcium salts; a decarbonation step subsequent to the desulfurization step comprising further treating the gas with an absorbing solution containing a basic amine compound, that causes carbon dioxide and sulfur oxides escaping from the desulfurization step to be absorbed in the form of amine salts; a first regeneration step for the absorbing solution, wherein the absorbing solution containing the amine salts is treated to liberate carbon dioxide therefrom; recycling step, wherein a portion of the regenerated amine absorbing solution is recycled back to the decarbonation step, a subsequent secondary regeneration step, wherein the remainder of the regenerated amine absorbing solution is treated with a basic calcium substance to result in the formation of calcium-sulfur oxide compounds, and a subsequent solid-liquid separation step, wherein the calcium-sulfur compounds formed in the secondary regeneration step are separated from the absorbing solution, the separated solids are recycled to the desulfurization step for use as the basic calcium substance and the separated absorbing solution is recycled to the decarbonation step for use as the absorbing solution. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 11, 12)
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Specification