Hardened hydraulic cement, ceramic or coarse concrete aggregate treated with high pressure fluids

• US 5,897,704 A
• Filed: 05/19/1997
• Issued: 04/27/1999
• Est. Priority Date: 05/19/1997
• Status: Expired due to Fees

• Current Assignee: Materials Technology Ltd.
• Original Assignee: Materials Technology Ltd.
• Inventors: Baglin, Frank Geile
• Primary Examiner(s): MARCANTONI, PAUL D
• Application Number:
  US08/858,415
• Time in Patent Office: 708 Days
• Field of Search: 106/738, 106/740, 106/743, 106/696, 106/724, 106/802, 106/822, 106/823
• US Class Current: 106/696
• CPC Class Codes: C04B 18/08 Flue dust , i.e. fly ash
• CPC Class Codes: C04B 2103/0046 added as monomers or as oligomers
• CPC Class Codes: C04B 2103/0067 the ingredients being formed in situ by chemical reactions or conversion of one or more of the compounds of the composition
• CPC Class Codes: C04B 2103/007 Supercritical fluids
• CPC Class Codes: C04B 22/064 of the alkaline-earth metals
• CPC Class Codes: C04B 22/12 containing halogen in the anion
• CPC Class Codes: C04B 28/02 containing hydraulic cements other than calcium sulfates
• CPC Class Codes: C04B 41/0018 Coating or impregnating "in situ", e.g. impregnating of artificial stone by subsequent melting of a compound added to the artificial stone composition
• CPC Class Codes: C04B 41/009 characterised by the material treated
• CPC Class Codes: C04B 41/4505 characterised by the method of application
• CPC Class Codes: C04B 41/4556 coating or impregnating with a product reacting with the substrate, e.g. generating a metal coating by surface reduction of a ceramic substrate
• CPC Class Codes: C04B 41/48 Macromolecular compounds
• CPC Class Codes: C04B 41/63 Macromolecular compounds
• CPC Class Codes: Y02W 30/91 Use of waste materials as fillers for mortars or concrete

Abstract

The properties of cement matrices are improved by one or more of the three processes, which can be performed individually, sequentially, or in any desired combination. In each instance a supercritical fluid is or includes a solvent for one of two (or more) reactants such as a monomer and a polymer initiator. The resulting mixture is infused into the matrix under supercritical conditions. The other reactant is placed into the matrix; for example, by incorporating it in the wet cement paste prior to curing. When the mixture is infused into the matrix, the reactants react and change the cement matrix in predictable, desired ways. The solvent itself may or may not be supercritical, and if it is not, it is mixed with a supercritical fluid, which might or might not be another solvent. In this manner, the inside of the matrix may be coated and/or sealed with a polymer, for example, or the entire cement matrix may be rendered relatively flexible and ductile.

Claims

1. A method for changing a characteristic of a hardened cement matrix, the method comprising the steps of providing a monomer, a polymer initiator and a solvent for one of the monomer and the polymer initiator, dissolving the one of the monomer and the polymer initiator in the solvent, placing the other one of the monomer and the polymer initiator on an inside of the matrix, infusing the solvent and the monomer or polymer initiator dissolved therein into the matrix under supercritical conditions, and reacting the monomer and the polymer initiator inside the matrix.

2. A method according to claim 1 wherein the step of infusing the solvent under supercritical conditions comprises subjecting the solvent to a temperature and pressure effectively rendering it a supercritical solvent.

3. A method according to claim 2 including the step of adding a second solvent to the first-mentioned solvent to form a mixture, and wherein the step of infusing comprises infusing the mixture into the matrix.

4. A method according to claim 1 including the step of combining the solvent with a second fluid prior to the step of infusing.

5. A method according to claim 4 wherein the step of infusing the solvent under supercritical conditions comprises subjecting the second fluid to a temperature and pressure effectively rendering the second fluid a supercritical fluid to thereby infuse the mixture under supercritical conditions into the matrix.

6. A method according to claim 1 wherein the matrix comprises a hardened cement matrix.

7. A method according to claim 6 including the step of forming the cement matrix from a cement paste and curing the paste into the hardened cement matrix, and including the step of placing the one of the monomer and the polymer initiator in the cement paste prior to the curing step.

8. A method according to claim 7 wherein the step of forming the paste further comprises forming the paste with fly ash, calcium oxide, and vanadium chloride, and wherein at least one of styrene, butadiene and dicyclopentadiene is dissolved in the solvent so that upon infusing the solvent into the matrix reactions occur inside the matrix which render it flexible and ductile.