Electrochemical sensor

• US 5,900,128 A
• Filed: 05/30/1997
• Issued: 05/04/1999
• Est. Priority Date: 05/31/1996
• Status: Expired due to Term

• Current Assignee: Sphere Medical Limited (Sphere Medical Holding Ltd.)
• Original Assignee: Siemens AG
• Inventors: Montag, Bernhard, Kress, Reinhard, Gumbrecht, Walter
• Primary Examiner(s): TUNG, TA HSUNG
• Application Number:
  US08/866,103
• Time in Patent Office: 704 Days
• Field of Search: 204/415, 204/421-429, 205/782.5, 205/783, 205/783.5, 205/784
• US Class Current: 204/415
• CPC Class Codes: G01N 27/4141 specially adapted for gases

Abstract

An electrochemical sensor is provided on a substrate whereby a precious metal layer is arranged in an inner region under an electrolyte layer that is surrounded by a polyimide structure. A hydrophobic layer is surrounded by an outer polyimide structure and further is located on top of the electrolyte layer and extends laterally beyond the electrolyte layer. A lead for electrical connection of the precious metal layer extends under the hydrophobic layer laterally from the electrolyte layer is sealed from the hydrophobic layer by a protective layer. The protective layer prevents the penetration of analysis fluid into the gap between the hydrophobic layer and the surrounding polyimide structure into the inner region of the sensor. The material of the protective layer is preferably a double layer of PECVD oxide and PECVD nitride.

Claims

1. An electrochemical sensor comprising:

at least one electrode fabricated from a precious metal disposed on top of a substrate,

an electrolyte layer being disposed on top of at least a portion of the electrode, the electrolyte layer being surrounded by a first polymer structure,

the first polymer structure further surrounding an electrochemically sensitive region of the substrate,

a hydrophobic layer being disposed on top of the electrolyte layer and the first polymer structure and extending laterally beyond the first polymer structure and the electrolyte layer, the hydrophobic layer being surrounded by a second polymer structure and engaged by the second polymer structure at an outer periphery of the hydrophobic layer,

a further portion of the electrode extending laterally beyond the electrolyte layer and the first polymer structure and between the substrate and the hydrophobic layer and further between the second polymer structure and the substrate,

a protective layer being disposed between the further portion of the electrode and the hydrophobic layer, between the further portion of the electrode and the second polymer structure, and between the further portion of the electrode and the periphery of the hydrophobic layer where the second polymer structure engages the hydrophobic layer.

2. The sensor of claim 1 wherein the hydrophobic layer comprises a material that exhibits a high diffusion coefficient for at least one specific gas.

3. The sensor of claim 2 wherein the protective layer comprises a material that enters into a covalent bond with the material of the hydrophobic layer.

4. The sensor of claim 3 wherein the hydrophobic layer comprises a polysiloxane and wherein the protective layer comprises oxygen.

5. The sensor of claim 4 wherein the protective layer comprises an oxide layer.

6. The sensor of claim 5 wherein the oxide layer is a silicon oxide.

7. The sensor of claim 5 wherein the oxide layer is SiO_x N_y.

8. The sensor of claim 5 wherein the protective layer further comprises the oxide layer disposed on top of a silicon nitride layer.

9. The sensor of claim 3 wherein the protective layer comprises a double layer comprising a lower oxide layer and an upper nitride layer, the oxide layer being disposed on top of the electrode and the nitride layer being disposed between the oxide layer and the hydrophobic layer.

10. The sensor of claim 9 wherein an upper oxide layer is formed on the surface of the upper nitride layer.

11. The sensor of claim 9 wherein the oxide is a PECVD oxide layer.

12. The sensor of claim 9 wherein the nitride layer is a PECVD nitride layer.

13. An electrochemical sensor comprising:

at least one electrode disposed on top of a substrate, at least a first portion of the electrode being disposed between the substrate and an electrolyte layer,

the electrolyte layer being surrounded by a first polymer structure, the electrolyte layer and first polymer structure being disposed underneath a hydrophobic layer that extends laterally beyond the first polymer structure and the electrolyte layer,

the hydrophobic layer being surrounded by a second polymer structure and engaged by the second polymer structure at an outer periphery of the hydrophobic layer,

a second portion of the electrode extending laterally beyond the electrolyte layer and between the substrate and the hydrophobic layer and further between the second polymer structure and the substrate,

the second portion of the electrode being disposed underneath a protective layer,

the protective layer being disposed between the second portion of the electrode and the hydrophobic layer between the second portion of the electrode and the second polymer structure and between the second portion of the electrode and the periphery of the hydrophobic layer where the second polymer engages the hydrophobic layer.

14. The sensor of claim 13 wherein the first polymer structure surrounds an electrochemically sensitive region of the substrate.

15. The sensor of claim 13 wherein the electrode is fabricated from a precious metal.

16. The sensor of claim 13 wherein the hydrophobic layer comprises a material that exhibits a high diffusion coefficient for at least one specific gas and wherein the protective layer comprises a material that enters into a covalent bond with the material of the hydrophobic layer.

17. The sensor of claim 16 wherein the protective layer comprises a double layer comprising a lower oxide layer and an upper nitride layer, the oxide layer being disposed on top of the electrode and the nitride layer being disposed between the oxide layer and the hydrophobic layer.

18. The sensor of claim 17 wherein the oxide layer is a PECVD oxide layer and wherein the nitride layer is a PECVD nitride layer. protective layer comprises a material that enters into a covalent bond with the material of the hydrophobic layer.

19. The sensor of claim 13 wherein the hydrophobic layer comprises a polysiloxane and wherein the protective layer comprises an oxide layer.

20. An electrochemical sensor comprising:

at least one electrode fabricated from a precious metal disposed on top of a substrate,

an electrolyte layer being disposed on top of at least a portion of the electrode, the electrolyte layer being surrounded by a first polymer structure,

the first polymer structure further surrounding an electrochemically sensitive region of the substrate,

a hydrophobic layer being disposed on top of the electrolyte layer and the first polymer structure and extending laterally beyond the first polymer structure and the electrolyte layer, the hydrophobic layer being surrounded by a second polymer structure and engaged by the second polymer structure at an outer periphery of the hydrophobic layer, the hydrophobic layer comprising a material that exhibits a high diffusion coefficient for at least one specific gas, the hydrophobic layer comprising polysiloxane,

a further portion of the electrode extending laterally beyond the electrolyte layer and between the substrate and the hydrophobic layer and further between the second polymer structure and the substrate,

a protective layer being disposed between the further portion of the electrode and the hydrophobic layer between the further portion of the electrode and the second polymer structure, and between the further portion of the electrode and the periphery of the hydrophobic layer where the second polymer structure engages the hydrophobic layer, the protective layer comprising a double layer comprising a lower oxide layer and an upper nitride layer, the oxide layer being disposed on top of the further portion of the electrode and the nitride layer being disposed between the oxide layer and the hydrophobic layer and between the oxide layer and the second polymer structure and between the oxide layer and an area where the second polymer structure engages the hydrophobic layer, the nitride layer entering into a covalent bond with the material of the hydrophobic layer.