Method of making a vessel having a wall surface having a barrier coating

• US 5,900,285 A
• Filed: 11/21/1997
• Issued: 05/04/1999
• Est. Priority Date: 10/27/1994
• Status: Expired due to Term

• Current Assignee: Schott AG (Carl-Zeiss-Stiftung)
• Original Assignee: Schott Glaswerke
• Inventors: Walther, Marten, Zschaschler, Gudrun, Spallek, Michael, Heming, Martin
• Primary Examiner(s): King, Roy V.
• Application Number:
  US08/976,425
• Time in Patent Office: 529 Days
• Field of Search: 427/237, 427/238, 427/575, 427/576, 427/491, 427/255.7, 428/35.7, 428/35.9, 428/36.7, 428/36.91
• US Class Current: 427/491
• CPC Class Codes: B05D 1/62 Plasma-deposition of organic layers plasma deposition in general C23C14/00, C23C16/00
• CPC Class Codes: B65D 1/0215 multilayered B65D81/3837 takes precedence
• CPC Class Codes: B65D 23/0814 characterised by the composition of the material
• CPC Class Codes: C08J 7/0423 with at least one layer of inorganic material and at least one layer of a composition containing a polymer binder
• CPC Class Codes: C08J 7/043 Improving the adhesiveness of the coatings per se, e.g. forming primers adhesives in the form of films or foils characterised by the primer layers between the polymer carriers and the adhesives C09J7/50
• CPC Class Codes: C08J 7/048 Forming gas barrier coatings
• CPC Class Codes: C23C 16/045 Coating cavities or hollow spaces, e.g. interior of tubes; Infiltration of porous substrates
• CPC Class Codes: C23C 16/30 Deposition of compounds, mixtures or solid solutions, e.g. borides, carbides, nitrides
• CPC Class Codes: C23C 16/34 Nitrides C23C16/303 takes precedence
• CPC Class Codes: C23C 16/401 containing silicon
• CPC Class Codes: C23C 16/402 Silicon dioxide
• CPC Class Codes: C23C 16/405 of refractory metals or yttrium
• CPC Class Codes: Y10T 428/1321 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1352 Polymer or resin containing [i.e., natural or synthetic]
• CPC Class Codes: Y10T 428/1359 Three or more layers [continuous layer]
• CPC Class Codes: Y10T 428/1383 Vapor or gas barrier, polymer derived from vinyl chloride or vinylidene chloride, or polymer containing a vinyl alcohol unit is sandwiched between layers [continuous layer]
• CPC Class Codes: Y10T 428/1393 Multilayer [continuous layer]

Abstract

A plastic vessel has a barrier coating comprising sequentially arranged barrier layers of organic polymer and of inorganic oxides, nitrides or oxynitrides. The barrier coating preferably has at least two inorganic barrier layers. The thickness of the inorganic barrier layers lies between 2 and 300 nm and the thickness of the organic barrier layer lies between 2 and 1000 nm. The total thickness of the layer packet should not exceed 0.1 mm.

Claims

1. The method of making a plastic vessel having a wall surface having a barrier coating, the method comprising the steps of:

sequentially depositing individual inorganic and individual organic barrier layers to said wall surface by the PCVD (Plasma-Chemical-Vapor-Depositing) process to define said barrier coating with the first barrier layer deposited on and in contact with said wall surface always being organic and the last barrier layer deposited and in contact with a substance stored in said vessel always being inorganic;

ending the application of said barrier layers when at least one inorganic barrier layer has been applied and at least one organic barrier layer has been applied;

the inorganic barrier layer being made of at least one of the following substances;

oxides, nitrides, oxynitrides and a mixture of said oxides, nitrides and oxynitrides; and

,

the organic barrier layer being made of an organic polymer material.

2. The method of claim 1, wherein the inorganic barrier layers are applied to have a thickness of 2 to 300 nm and the organic barrier layers are applied to have a thickness of 2 to 1,000 nm.

3. The method of claim 1, wherein the individual ones of said layers are applied utilizing a PICVD (Plasma-Impulse-Chemical-Vapor-Deposition) process.

4. The method of claim 1, wherein said barrier layers are applied so that said barrier coating has an overall thickness of at most 0.1 mm.

5. The method of claim 1, wherein said individual barrier layers are deposited only by said PCVD (Plasma-Chemical-Vapor-Deposition) process.

6. A method of making a plastic vessel having a wall surface having a barrier coating, the method comprising the steps of:

sequentially depositing-individual inorganic and individual organic barrier layers on said wall surface by the PCVD process (Plasma-Chemical-Vapor-Deposition) to thereby define said barrier coating;

ending the application of said barrier layers when at least one inorganic barrier layer has been applied and at least one organic barrier layer has been applied;

the inorganic barrier layer being made of at least one of the following substances;

oxides, nitrides, oxynitrides and a mixture of said oxides, nitrides and oxynitrides;

the organic barrier layer being made of an organic polymer material; and

,

the organic barrier layer being doped with 0.1 to 10 metal atoms per carbon atom.

7. A method of making a plastic vessel having a wall surface having a barrier coating, the method comprising the steps of:

sequentially depositing individual inorganic and individual organic barrier layers on said wall surface by the PCVD process (Plasma-Chemical-Vapor-Deposition) to thereby define said barrier coating;

ending the application of said barrier layers when at least one inorganic barrier layer has been applied and at least one organic barrier layer has been applied;

the inorganic barrier layer being made of at least one of the following substances;

oxides, nitrides, and oxynitrides and a mixture of said oxides, nitrides and oxynitrides;

the organic barrier layer being made of an organic polymer material; and

the organic barrier layer and said inorganic barrier layer being doped with the same metal atoms.

8. The method of claim 7, wherein the organic barrier layer and the adjoining inorganic barrier layer conjointly define a boundary interface;

and, wherein said organic barrier layer contains metal atoms and the content of said metal atoms varies over the thickness of said organic barrier layer with said content being less at the center of said organic barrier layer than at said boundary interface.

9. A method of making a plastic vessel having a wall surface having a barrier coating, the method comprising the steps of:

sequentially depositing individual inorganic and individual organic barrier layers on said wall surface by the PCVD process (Plasma-Chemical-Vapor-Depositing) to thereby define said barrier coating;

ending the application of said barrier layers when at least one inorganic barrier layer has been applied and at least one organic barrier layer has been applied;

the inorganic barrier layer being made of at least one of the following substances;

oxides, nitrides, oxynitrides and a mixture of said oxides, nitrides and oxynitrides;

the organic barrier layer being made of an organic polymer material; and

said individual barrier layers being so deposited that said inorganic barrier layer and the adjoining organic barrier layer conjointly define a transition region wherein the composition of the inorganic barrier layer changes continuously into the composition of the organic barrier layer.