Post foamable multiple-sequential-foaming composition

• US 5,902,225 A
• Filed: 04/17/1997
• Issued: 05/11/1999
• Est. Priority Date: 10/11/1994
• Status: Expired due to Term

• Current Assignee: SC Johnson & Son Incorporated
• Original Assignee: James A. Monson
• Inventors: Monson, James A.
• Primary Examiner(s): Lovering, Richard D.
• Assistant Examiner(s): Metzmaier, Daniel S.
• Application Number:
  US08/839,932
• Time in Patent Office: 754 Days
• Field of Search: 252/307, 514/945, 424/45, 424/47, 424/73, 510/159, 510/406, 516/10
• US Class Current: 516/10
• CPC Class Codes: A61K 8/046 Aerosols; Foams
• CPC Class Codes: A61K 9/122 Foams; Dry foams edible foams A61K9/0056
• CPC Class Codes: A61Q 19/10 Washing or bathing preparations
• CPC Class Codes: A61Q 5/02 Preparations for cleaning the hair
• CPC Class Codes: A61Q 9/02 Shaving preparations
• CPC Class Codes: B65D 81/3211 coaxially and provided with means facilitating admixture
• CPC Class Codes: B65D 83/42 Filling or charging means
• CPC Class Codes: B65D 83/752 characterised by the use of specific products or propellants
• CPC Class Codes: C11D 1/02 Anionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/38 Cationic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/66 Non-ionic compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 1/88 Ampholytes; Electroneutral compounds C11D1/002, C11D1/004, C11D1/008 take precedence
• CPC Class Codes: C11D 17/0043 For use with aerosol devices
• CPC Class Codes: C11D 2111/42 Application of foam or a temporary coating on the surface to be cleaned
• CPC Class Codes: C11D 3/0094 High foaming compositions
• CPC Class Codes: C11D 3/18 Hydrocarbons C11D3/164 takes precedence
• CPC Class Codes: C11D 3/24 containing halogen C11D3/162, C11D3/164, C11D3/166, C11D3/168 take precedence

Abstract

This invention provides compositions which are dispensed as initial-stage foams and which post-foam upon spreading during use, thereby exhibiting multiple levels of foam. Each such composition includes a foamable utilitarian constituent, a liquid post-foaming agent, and a compressed gas.

Claims

1. A low-pressure multiple-sequential-foaming composition to be dispensed from a suitable container at pressures between about 10-60 psig in the form of an initial-stage continuous foam body of post-foamable foam which, upon subsequent spreading action, post-foams to form a second stage of a substantially greater level of post-foamed foam, including:

about 0.1-60% by weight of a foamable, post-foamable utilitarian constituent including a surface active agent selected from the group consisting of nonionic, anionic, amphoteric and cationic surfactants and mixtures thereof, such constituent having a viscosity sufficient for dispensing as an initial-stage continuous foam body with a foam density of about 0.15-0.9 g/cc;

about 16.0-99.4% by weight of water;

about 0.50-24% by weight of a volatile liquid post-foaming agent selected from the group consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons and mixtures thereof, for post-foaming the initial-stage continuous foam body upon spreading to an extended second-stage foam exhibiting a reduced density of about 0.04-0.30 g/cc, the post-foaming agent having a vapor pressure low enough such that it is dispensed substantially as a liquid with the utilitarian constituent; and

a compressed gas in an amount sufficient (a) to provide the composition, when contained, with dispensing pressure of about 10-60 psig and (b) to dispense the composition as said initial-stage continuous foam body;

whereby, upon dispensing, the composition exits the container initially as an initial-stage continuous foam body of spreadable foam which, upon spreading, post-foams to a substantially extended foam exhibiting a lower density.

2. The composition of claim 1 wherein the compressed gas is selected from the group consisting of carbon dioxide, nitrous oxide, nitrogen, argon, neon, krypton, xenon, helium and mixtures thereof.

3. The composition of claim 1 wherein the liquid post-foaming agent has a vapor pressure of about 6-14 psig at 90 to 100°

F.

4. The composition of claim 1 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

5. The composition of claim 1 wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

6. The composition of claim 1 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.

7. The composition of claim 1 wherein the container consists of clear or translucent plastic.

8. The composition of claim 1 wherein the post-foaming agent comprises a mixture of isopentane and isobutane.

9. A low-pressure multiple-sequential-foaming composition to be dispensed from a suitable container at pressures between about 10-60 psig in the form of an immediately-forming initial-stage of post-foamable foam which, upon subsequent spreading action, post-foams to form a second stage of a substantially greater level of post-foamed foam, including:

about 0.1-60% by weight of a foamable, post-foamable utilitarian constituent including a surface active agent selected from the group consisting of nonionic, anionic, amphoteric and cationic surfactants and mixtures thereof, for dispensing as an immediately-forming initial-stage foam with a foam density of about 0.15-0.9 g/cc;

about 16.0-99.4% by weight of water;

about 0.50-24% by weight of a volatile liquid post-foaming agent selected from the group consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons and mixtures thereof, for post-foaming the immediately-forming initial-stage foam upon spreading to an extended second-stage foam exhibiting a reduced density of about 0.04-0.30 g/cc, the post-foaming agent having a vapor pressure low enough such that it is dispensed substantially as a liquid with the utilitarian constituent; and

a compressed gas in an amount sufficient (a) to provide the composition, when contained, with dispensing pressure of about 10-60 psig and (b) to dispense the composition as said immediately-forming initial-stage foam;

whereby, upon dispensing, the composition exits the container initially as an immediately-forming initial-stage foam of spreadable foam which, upon spreading, post-foams to a substantially extended foam exhibiting a lower density.

10. The composition of claim 9 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

11. The composition of claim 9 wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

12. The composition of claim 9 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.

13. A multiple-secuential-foaming cleansing or cosmetic composition dispensed from a suitable container by a compressed gas, at a dispensing pressure of about 10-60 psig in the form of a post-foamable foam comprising:

a dispensed initial-stage continuous foam body of post-foamable foam formed immediately upon dispensing by the compressed gas as the composition is dispensed from the container, the initial-stage continuous foam body of post-foamable foam exhibiting a density of about 0.15-0.90 g/cc and comprising a liquid aqueous mixture consisting essentially of;

about 10-85% by volume of dispersed gas;

a foamable, post-foamable utilitarian constituent; and

a volatile liquid post-foaming agent selected from the group consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons and mixtures thereof, for post-foaming the initial-stage continuous foam body upon spreading and having a vapor pressure low enough within the dispensed initial-stage post-foamable foam to remain essentially as a liquid with the utilitarian constituent until subsequent spreading action; and

a second stage of a substantially greater volume of post-foamed foam formed essentially by vaporization of the post-foaming agent upon spreading, the second stage of foam exhibiting a lower density of about 0.04-0.3 g/cc and consisting of about 70-96% by volume of dispersed gas within the foamable post-foamed utilitarian constituent.

14. The composition of claim 13 wherein the foamable utilitarian constituent includes a surface active agent selected from the group consisting of nonionic, anionic, amphoteric and cationic surfactants and mixtures thereof.

15. The composition of claim 14 wherein the utilitarian constituent includes a diluent.

16. The composition of claim 13 wherein the compressed gas is selected from the group consisting of carbon dioxide, nitrous oxide, nitrogen, argon, neon, krypton, xenon, helium and mixtures thereof.

17. The composition of claim 13 wherein the liquid post-foaming agent has a vapor pressure of about 6-14 psig at 90 to 100°

F.

18. The composition of claim 13 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

19. The composition of claim 13, wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

20. The composition of claim 13 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.

21. The composition of claim 13 wherein the container consists of clear or translucent plastic.

22. The composition of claim 13 wherein the post-foaming agent comprises a mixture of isopentane and isobutane.

23. A multiple-sequential-foaming cleansing or cosmetic composition dispensed from a suitable container by a compressed gas, at a dispensing pressure of about 10-60 psig in the form of a post-foamable foam comprising:

a dispensed immediately-forming initial-stage of post-foamable foam formed immediately upon dispensing by the compressed gas as the composition is dispensed from the container, the immediately-forming initial-stage of post-foamable foam exhibiting a density of about 0.15-0.90 g/cc and comprising a liquid aqueous mixture consisting essentially of;

about 10-85% by volume of dispersed gas;

a foamable, post-foamable utilitarian constituent; and

a volatile liquid post-foaming agent selected from the group consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons and mixtures thereof, for post-foaming the immediately-forming initial-stage foam upon spreading and having a vapor pressure low enough within the dispensed initial-stage post-foamable foam to remain essentially as a liquid with the utilitarian constituent until subsequent spreading action; and

a second stage of a substantially greater volume of post-foamed foam formed essentially by vaporization of the post-foaming agent upon spreading, the second stage of foam exhibiting a lower density of about 0.04-0.3 g/cc and consisting of about 70-96% by volume of dispersed gas within the foamable post-foamed utilitarian constituent.

24. The composition of claim 23 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

25. The composition of claim 23 wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

26. The composition of claim 23 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.

27. A low-pressure multiple-sequential-foaming composition to be dispensed from a plastic container at pressures of below about 60 psig as an initial-stage continuous foam body and which post-foams upon spreading, to a second stage of foam, including:

about 0.1-60% by weight of a thickened aqueous foamable utilitarian constituent, such constituent having a viscosity sufficient for dispensing as an initial-stage continuous foam body with a foam density of about 0.15-0.9 g/cc;

about 16.0-99.4% by weight of water;

about 0.50-24% by weight of a volatile liquid post-foaming agent selected from the croup consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons, and mixtures thereof dispensable with the utilitarian constituent for post-foaming the initial-stage continuous foam body upon spreading to an extended second-stage foam exhibiting a reduced density of about 0.04-0.3 g/cc, the post-foaming agent having a vapor pressure low enough such that it is dispensed substantially as a liquid with the utilitarian constituent; and

a compressed gas selected from the group consisting of carbon dioxide, nitrous oxide, nitrogen, argon, neon, kryoton, xenon, helium and mixtures thereof in an amount sufficient (a) to provide the composition, when contained, with dispensing pressure of below about 60 psig and (b) to dispense the composition as said initial-stage continuous foam body;

whereby, upon dispensing, the composition exits the container initially as an initial-stage continuous foam body of spreadable foam with a density of about 0.15-0.9 g/cc which post-foams upon spreading to a substantially extended foam exhibiting a lower density of about 0.04-0.3 g/cc.

28. The composition of claim 27 wherein the foamable utilitarian constituent includes a surface active agent selected from the group consisting of nonionic, anionic, amphoteric and cationic surfactants and mixtures thereof.

29. The composition of claim 27 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

30. The composition of claim 27 wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

31. The composition of claim 27 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.

32. The composition of claim 27 wherein the container consists of clear or translucent plastic.

33. The composition of claim 27 wherein the post-foaming agent comprises a mixture of isopentane and isobutane.

34. The composition of claim 27 wherein the liquid post-foaming agent has a vapor pressure of about 6-14 psig at 90 to 100°

F.

35. A low-pressure multiple-sequential-foaming composition to be dispensed from a plastic container at pressures of below about 60 psig as an immediately-forming initial-stage foam and which post-foams upon spreading, to a second stage of foam, including:

about 0.1-60% by weight of a thickened aqueous foamable utilitarian constituent, for dispensing as an immediately-forming initial-stage foam with a foam density of about 0.15-0.9 g/cc;

about 16.0-99.4% by weight of water;

about 0.50-24% by weight of a volatile liquid post-foaming agent selected from the group consisting of saturated aliphatic hydrocarbons, halogenated hydrocarbons, and mixtures thereof dispensable with the utilitarian constituent for post-foaming the immediately-forming initial-stage foam upon spreading to an extended second-stage foam exhibiting a reduced density of about 0.04-0.3 g/cc, the post-foaming agent having a vapor pressure low enough such that it is dispensed substantially as a liquid with the utilitarian constituent; and

a compressed gas selected from the group consisting of carbon dioxide, nitrous oxide, nitrogen, argon, neon, krypton, xenon, helium and mixtures thereof in an amount sufficient (a) to provide the composition, when contained, with dispensing pressure of below about 60 psig and (b) to dispense the composition as said immediately-forming initial-stage foam;

whereby, upon dispensing, the composition exits the container initially as an immediately-forming initial-stage of spreadable foam with a density of about 0.15-0.9 g/cc which post-foams upon spreading to a substantially extended foam exhibiting a lower density of about 0.04-0.3 g/cc.

36. The composition of claim 35 wherein the initial stage of post-foamable foam has a density of about 0.15-0.30 g/cc, thereby exhibiting 70-85% by volume of undissolved dispersed gas within the post-foamable foam.

37. The composition of claim 35 wherein the second stage of post-foamable foam has a density of about 0.05-0.10 g/cc, thereby exhibiting 90-95% by volume of undissolved dispersed gas within the foamable post-foamed utilitarian constituent.

38. The composition of claim 35 wherein the dispensing pressure of the compressed gas is between about 10 psig and 35 psig.