Magnetorheological fluid

• US 5,906,767 A
• Filed: 10/28/1997
• Issued: 05/25/1999
• Est. Priority Date: 06/13/1996
• Status: Expired due to Term

• Current Assignee: Lord Corporation (Parker-Hannifin Corporation), R. T. Vanderbilt Company, Inc.
• Original Assignee: Lord Corporation (Parker-Hannifin Corporation)
• Inventors: Munoz, Beth C., Margida, Anthony J., Karol, Thomas J.
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US08/959,514
• Time in Patent Office: 574 Days
• Field of Search: 252/62.52, 252/62.51 R, 252/62.54
• US Class Current: 252/62.52
• CPC Class Codes: H01F 1/447 characterised by magnetoviscosity, e.g. magnetorheological, magnetothixotropic, magnetodilatant liquids electrorheological fluids C10M171/001

Abstract

A magnetorheological fluid that includes magnetic-responsive particles, a carrier fluid and a phosphorus additive. The magnetorheological fluid does not include an organomolybdenum, a thiophosphorus additive or a thiocarbamate additive.

Claims

1. A magnetorheological fluid comprising magnetic-responsive particles, a carrier fluid and at least one phosphorus additive, wherein the magnetorheological fluid does not include an organomolybdenum, a thiophosphorus additive or a thiocarbamate additive and the phosphorus additive has a structure represented by formula A:

##STR4## wherein R¹ and R² are each independently hydrogen, an amino group or an alkyl group having 1 to 22 carbon atoms;

X, Y and Z are each independently --CH₂ --, a nitrogen heteroatom or an oxygen heteroatom, provided that at least one of X, Y or Z is an oxygen heteroatom;

a is 0 or 1; and

n is the valence of M;

provided that if X, Y and Z are each an oxygen heteroatom, M is a salt moiety formed from an amine of the formula B;

##STR5## wherein R³, R⁴ and R⁵ are each independently hydrogen or aliphatic groups having 1 to 18 carbon atoms and, if at least one of X, Y or Z is not an oxygen heteroatom, M is selected from the group consisting of a metallic ion, a non-metallic moiety and a divalent moiety, provided that if Z is --CH₂ -- then M is a divalent moiety and if Z is a nitrogen heteroatom then M is not an amine of formula B.

2. A magnetorheological fluid according to claim 1, wherein X, Y and Z are each an oxygen heteroatom and M is the amine moiety of formula B.

3. A magnetorheological fluid according to claim 1, wherein the phosphorus additive is present in an amount of 0.1 to 15 volume percent, based on the total volume of the magnetorheological fluid.

4. A magnetorheological fluid according to claim 1, wherein the magnetic-responsive particles have an average particle size of 0.1 to 500 μ

m.

5. A magnetorheological fluid according to claim 1, wherein the magnetic-responsive particles have an average particle size of at least 1 μ

m.

6. A magnetorheological fluid according to claim 1, wherein the carrier fluid comprises at least one fluid selected from the group consisting of natural fatty oil, mineral oil, polyphenylether, phosphate ester, polyester, cycloparaffin oil, paraffin oil, unsaturated hydrocarbon oil, synthetic hydrocarbon oil, monobasic acid ester, glycol ester, glycol ether, synthetic hydrocarbon, perfluorinated polyether and halogenated hydrocarbon.

7. A magnetorheological fluid according to claim 6, wherein the carrier fluid is selected from the group consisting of mineral oil, paraffin oil, cycloparaffin oil and synthetic hydrocarbon.

8. A magnetorheological fluid according to claim 7, wherein the carrier fluid comprises a synthetic hydrocarbon derived from polyalphaolefin.

9. A magnetorheological fluid according to claim 6, wherein the carrier fluid comprises neopentylpolyol ester.

10. A magnetorheological fluid according to claim 1, wherein the magnetic-responsive particles have an average particle size of 0.1 to 500 μ

m and the carrier fluid is selected from the group consisting of mineral oil, paraffin, cycloparaffin, and synthetic hydrocarbon.

11. A magnetorheological fluid according to claim 1, further comprising at least one second phosphate.

12. A magnetorheological fluid according to claim 11 wherein the second phosphate is selected from the group consisting of tricresyl phosphate, trixylenyl phosphate, dilauryl phosphate, octadecyl phosphate, hexadecyl phosphate, dodecyl phosphate and didodecyl phosphate.

13. A magnetorheological fluid according to claim 1, further comprising a sulfur-containing compound.

14. A magnetorheological fluid according to claim 1, further comprising at least one carboxylate soap.

15. A magnetorheological fluid according to claim 14, wherein the carboxylate soap is selected from the group consisting of lithium stearate, calcium stearate, aluminum stearate, ferrous oleate, ferrous stearate, zinc stearate, sodium stearate and strontium stearate.

16. A magnetorheological fluid according to claim 1, further comprising a polymer-modified metal oxide.

17. A magnetorheological fluid according to claim 1, further comprising a carboxylate soap and a polymer-modified metal oxide.

18. A magnetorheological fluid according to claim 2, wherein the phosphorus additive comprises a C_12-14 -alkylamine salt of tert-octylphosphate.

19. A magnetorheological fluid according to claim 2, wherein the phosphorus additive is present in an amount of 0.1 to 10 volume percent, based on the total volume of the magnetorheological fluid, the magnetic-responsive particles have an average particle size of at least 1 μ

m and the carrier fluid comprises at least one fluid selected from the group consisting of natural fatty oil, mineral oil, polyphenylether, phosphate ester, polyester, cycloparaffin oil, paraffin oil, unsaturated hydrocarbon oil, synthetic hydrocarbon oil, monobasic acid ester, glycol ester, glycol ether, synthetic hydrocarbon, perfluorinated polyether and halogenated hydrocarbon.

20. A magnetorheological fluid according to claim 2, further comprising at least one carboxylate soap.

21. A magnetorheological fluid according to claim 1 wherein X and Y are each an oxygen heteroatom and Z is --CH₂ --.