Electrically conductive transparent film and coating composition for forming such film

• US 5,908,585 A
• Filed: 04/23/1998
• Issued: 06/01/1999
• Est. Priority Date: 10/23/1995
• Status: Expired due to Fees

• Current Assignee: Hyperion Catalysis International Incorporated, Mitsubishi Materials Corporation
• Original Assignee: Hyperion Catalysis International Incorporated, Mitsubishi Materials Corporation
• Inventors: Shibuta, Daisuke
• Primary Examiner(s): Kopec, Mark
• Assistant Examiner(s): Mruk, Brian
• Application Number:
  US09/051,803
• Time in Patent Office: 404 Days
• Field of Search: 252/506, 252/507, 252/508, 428/922, 428/924
• US Class Current: 252/506
• CPC Class Codes: C03C 17/007 containing a dispersed phase, e.g. particles, fibres or flakes, in a continuous phase
• CPC Class Codes: C03C 2217/211 SnO2
• CPC Class Codes: C03C 2217/23 Mixtures
• CPC Class Codes: C03C 2217/28 Other inorganic materials
• CPC Class Codes: C03C 2217/452 Glass
• CPC Class Codes: C03C 2217/475 Inorganic materials
• CPC Class Codes: C03C 2217/476 Tin oxide or doped tin oxide
• CPC Class Codes: C03C 2217/478 Silica
• CPC Class Codes: C03C 2217/48 having a specific function
• CPC Class Codes: C03C 2217/70 Properties of coatings
• CPC Class Codes: C03C 2218/113 by sol-gel processes
• CPC Class Codes: C03C 2218/116 by spin-coating, centrifugation
• CPC Class Codes: H01B 1/14 Conductive material dispersed in non-conductive inorganic material
• CPC Class Codes: H01B 1/18 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: H01B 1/20 Conductive material dispersed in non-conductive organic material organic macromolecular compounds or compositions C08
• CPC Class Codes: H01B 1/24 the conductive material comprising carbon-silicon compounds, carbon or silicon
• CPC Class Codes: Y10S 428/922 Static electricity metal bleed-off metallic stock
• CPC Class Codes: Y10S 428/924 Composite

Abstract

A transparent electrically conductive film having a surface resistivity of 10² -10¹⁰ Ω/.sup.□, an overall light transmittance of at least 70%, and a haze value of at most 20% comprises an organic or inorganic transparent matrix having dispersed therein 0.01%-1 wt % of hollow carbon microfibers and 1%-40 wt % of an electrically conductive metal oxide powder (such as antimony-doped tin oxide) with an average primary particle diameter of 0.5 μm or smaller. The matrix can be an organic polymer which is thermoplastic, thermosetting, or curable by ultraviolet radiation, or a metal oxide sol which can form an inorganic glass film, a hydrolyzable or heat decomposable organic metal compound, or the like.

Claims

1. An electrically conductive transparent film comprising an organic or inorganic transparent matrix having, dispersed therein, 0.01%-1% by weight of hollow carbon microfibers and 1%-40% by weight of a transparent electrically conductive metal oxide powder having an average primary particle diameter of 0.5 μ

m or smaller.

2. The conductive transparent film of claim 1, wherein said carbon microfibers have an outer diameter of 3.5-70 nm and an aspect ratio of at least 5.

3. The conductive transparent film of claim 1, wherein said transparent electrically conductive metal oxide powder is selected from the group consisting of powders of tin oxide, antimony-tin mixed oxides, tin-indium mixed oxides, zinc oxide, aluminum-doped zinc oxide, titanium oxide, tungsten oxide, molybdenum oxide, and vanadium oxide and wherein it has an average primary particle diameter of 0.2 μ

m or less and a volume resistivity of at most 10⁷ Ω

·

cm as measured at a pressure of 100 kg/cm².

4. The conductive transparent film of claim 1, wherein said matrix is formed from a light- or radiation-curable organic polymer.

8. A transparent antistatic layer made of the electrically conductive transparent film of claim 1 to 4.

9. A transparent organic or inorganic film, sheet, or panel having, on at least one surface thereof, the transparent antistatic layer of claim 8.

5. An electrically conductive transparent film-forming coating composition, comprising a binder capable of forming an organic or inorganic transparent film, 0.01%-1% by weight, based on the total solids content of the composition, of hollow carbon microfibers, and 1%-40% by weight, based on the total solids content of the composition, of an electrically conductive transparent metal oxide powder having an average primary particle diameter of 0.5 μ

m or smaller.

6. The coating composition of claim 5, wherein said carbon microfibers have an outer diameter of 3.5-70 nm and an aspect ratio of at least 5.

7. The coating composition of claim 5, wherein said electrically conductive transparent metal oxide powder is selected from the group consisting of powders of tin oxide, antimony-tin mixed oxides, tin-indium mixed oxides, zinc oxide, aluminum-doped zinc oxide, titanium oxide, tungsten oxide, molybdenum oxide, and vanadium oxide and wherein it has an average primary particle diameter of 0.2 μ

m or less and a volume resistivity of at most 10⁷ Ω

·

cm as measured at a pressure of 100 kg/cm².