Fiber reinforced ceramic matrix composite marine engine riser elbow

• US 5,910,095 A
• Filed: 02/21/1997
• Issued: 06/08/1999
• Est. Priority Date: 02/21/1997
• Status: Expired due to Term

• Current Assignee: Northrop Grumman Systems Corporation (Northrop Grumman Corporation)
• Original Assignee: Northrop Grumman Corporation
• Inventors: Atmur, Steven Donald, Strasser, Thomas Edward
• Primary Examiner(s): Denion, Thomas E.
• Application Number:
  US08/804,451
• Time in Patent Office: 837 Days
• Field of Search: 60/272, 60/274, 60/323, 60/310, 264/86, 428/367, 428/364, 181/235
• US Class Current: 60/272
• CPC Class Codes: C04B 2235/3217 Aluminum oxide or oxide forming salts thereof, e.g. bauxite, alpha-alumina
• CPC Class Codes: C04B 2235/3826 Silicon carbides
• CPC Class Codes: C04B 2235/3873 Silicon nitrides, e.g. silicon carbonitride, silicon oxynitride
• CPC Class Codes: C04B 2235/48 Organic compounds becoming part of a ceramic after heat treatment, e.g. carbonising phenol resins
• CPC Class Codes: C04B 2235/5212 Organic
• CPC Class Codes: C04B 2235/5224 Alumina or aluminates
• CPC Class Codes: C04B 2235/5228 Silica and alumina, including aluminosilicates, e.g. mullite
• CPC Class Codes: C04B 2235/5232 Silica or silicates other than aluminosilicates, e.g. quartz
• CPC Class Codes: C04B 2235/524 Non-oxidic, e.g. borides, carbides, silicides or nitrides
• CPC Class Codes: C04B 2235/5244 Silicon carbide
• CPC Class Codes: C04B 2235/5248 Carbon, e.g. graphite
• CPC Class Codes: C04B 2235/6022 Injection moulding
• CPC Class Codes: C04B 2235/6028 Shaping around a core which is removed later
• CPC Class Codes: C04B 2235/616 Liquid infiltration of green bodies or pre-forms
• CPC Class Codes: C04B 35/18 rich in aluminium oxide
• CPC Class Codes: C04B 35/571 obtained from Si-containing polymer precursors or organosilicon monomers
• CPC Class Codes: C04B 35/6267 Pyrolysis, carbonisation or auto-combustion reactions
• CPC Class Codes: C04B 35/6269 Curing of mixtures
• CPC Class Codes: C04B 35/62863 Silicon carbide
• CPC Class Codes: C04B 35/62868 Boron nitride
• CPC Class Codes: C04B 35/62871 : Silicon nitride
• CPC Class Codes: C04B 35/62873 : Carbon
• CPC Class Codes: C04B 35/62897 : Coatings characterised by their thickness
• CPC Class Codes: C04B 35/80 : Fibres, filaments, whiskers, platelets, or the like
• CPC Class Codes: F01N 13/005 : with parts constructed of non-metallic material, e.g. of rubber
• CPC Class Codes: F01N 13/14 : having thermal insulation exhaust manifolds F01N13/102
• CPC Class Codes: F01N 13/16 : Selection of particular materials
• CPC Class Codes: F01N 2530/18 : Plastics material, e.g. polyester resin
• CPC Class Codes: F01N 2590/02 : for marine vessels or naval applications
• CPC Class Codes: F01N 3/04 : using liquids
• CPC Class Codes: F01N 3/043 : without contact between liquid and exhaust gases
• CPC Class Codes: Y02T 10/12 : Improving ICE efficiencies

Abstract

A corrosion-resistant, thermally insulative riser elbow for a marine engine. The riser elbow has an exhaust gas conduit made of fiber reinforced ceramic matrix composite (FRCMC) material formed from a polymer-derived ceramic resin in its ceramic state and fibers. Employing a FRCMC material results in a low-cost, light-weight, corrosion-resistant exhaust gas conduit not available with existing riser elbows. In addition, a FRCMC exhaust gas conduit is thermally insulative and so more of the heat of the exhaust is retained rather than being transferred to the conduit. This allows the cooling requirements for the riser elbow to be lowered, while still maintaining a touch temperature below prescribed levels. FRCMC can also be formed into practically any shape and size desired and can be very ductile thereby making the exhaust gas conduit fracture resistant and capable of withstanding thermally-induced strains typical of the environment of a marine engine'"'"'s exhaust system. The riser elbow also includes a water jacket sleeve formed integrally with and surrounding the exhaust gas conduit so as to define a cooling water channel between the outer wall of the exhaust gas conduit and the inner wall of the water jacket sleeve. Preferably, a plastic material capable of withstanding long-term exposure to at least 250 degree Fahrenheit cooling water, which can be salt water, without structural degradation is employed to form the water jacket sleeve. In addition, the plastic material should have a sufficient ductility to withstand handling and thermally-induced strains associated with the riser elbow of a marine engine.

Claims

1. A corrosion-resistant, thermally insulative riser elbow for a marine engine, comprising an exhaust gas conduit having a generally uniformly fiber-reinforced single layer wall structure with a non-brittle interior surface and fabricated of fiber reinforced ceramic matrix composite (FRMC) material formed from a polymer-derived ceramic resin in its ceramic form and fibers.

2. The riser elbow of claim 1, further comprising a water jacket sleeve formed integrally with and surrounding the exhaust gas conduit so as to define a cooling water channel between an outer wall of the exhaust gas conduit and an inner wail of the water jacket sleeve.

3. The riser elbow of claim 2, wherein an outlet side of the water jacket sleeve terminates at a location back from the termination point of an outlet side of the exhaust gas conduit, thereby causing the exhaust gas conduit to extend past the end of the water jacket sleeve.

4. The riser elbow of claim 2, wherein the exhaust gas conduit has a flange portion at an inlet side thereof, said flange portion having a centrally located opening which is in correspondence with an exhaust gas passageway formed by the interior of the exhaust gas conduit and which is interfaceable with an exhaust gas outlet of the marine engine.

5. The riser elbow of claim 4, wherein the flange portion of the exhaust gas conduit further comprises at least one peripheral opening adjacent the centrally located opening, said at least one peripheral opening being in correspondence with the cooling water channel and interfaceable with a cooling water outlet of the marine engine.

6. The riser elbow of claim 1, wherein the exhaust gas conduit comprises a cooling water mixing structure formed on the outside of the conduit at an outlet end thereof.

7. The riser elbow of claim 2, further comprising a support structure formed within the cooling water channel to support and maintain a concentric relationship between the exhaust gas conduit and the water jacket sleeve.

8. The riser elbow of claim 1 wherein the polymer-derived ceramic resin is chosen from silicon-carboxyl resin, or alumina silicate resin.

9. The riser elbow of claim 1 wherein the fibers comprise at least one of alumina, Nextel 312, Nextel 440, Nextel 510, Nextel 550, silicon nitride, silicon carbide, HPZ, graphite, carbon, and peat.

10. The riser elbow of claim 1, wherein the degree of ductility is selectable and varies with the percentage by volume and quantity of the fibers in the FRCMC material.

11. The riser elbow of claim 10, wherein the percentage by volume of the FRCMC material consisting of the fibers is within a range of about 25 to 55 percent, so as to produce a degree of ductility between about 0.10 to 0.55 percent strain.

12. The riser elbow of claim 10, wherein the form of the fibers incorporated into the FRCMC material has at least one of a continuous configuration and a non-continuous configuration, said fiber form also affecting the degree of ductility exhibited, and wherein the fiber form employed is chosen to, in combination with the quantity of fibers, produce the desired degree of ductility.

13. The riser elbow of claim 1, wherein the fibers are coated with an interface material which increases the degree of ductility exhibited by the FRCMC material.

14. The riser elbow of claim 13 wherein the interface material comprises at least one 0.1-5.0 micron thick layer of at least one of carbon, silicon nitride, silicon carbide, and boron nitride.

15. The riser elbow of claim 1, wherein the FRCMC material further comprises a filler material which increases the thermal insulating capability of the material.

16. The riser elbow of claim 15, wherein the filler material comprises a ceramic powder.

17. The riser elbow of claim 15, wherein the filler material comprises at least one of silicon carbide, alumina, and silicon nitride.

18. The riser elbow of claim 15, wherein the degree of thermal insulation provided by the filler material is selectable and varies with the percentage by volume of the structure consisting of the filler material.

19. The riser elbow of claim 2, wherein the water jacket sleeve comprises a plastic material capable of withstanding long-term exposure to at least 250 degree Fahrenheit salt water without structural degradation.

20. The riser elbow of claim 19, wherein the plastic material further has sufficient ductility to withstand handling and thermally-induced strains associated with the riser elbow of a marine engine.

21. The riser elbow of claim 20, wherein the plastic material comprises a thermosetting plastic material.

22. A method for forming a corrosion-resistant, thermally insulative riser elbow for a marine engine, comprising the step of:

forming an exhaust gas conduit comprising fiber reinforced ceramic matrix composite (FRCMC) material derived from a polymer-derived ceramic resin in its ceramic form and fibers generally directly adjacent each other.

23. The method of claim 22, further comprising the step of forming a water jacket sleeve integrally with and surrounding the exhaust gas conduit so as to define a cooling water channel between an outer wall of the exhaust gas conduit and an inner wall of the water jacket sleeve.

24. The method of claim 23, wherein the step of forming the exhaust gas conduit comprises forming a flange portion at an inlet side of the conduit, said flange portion having a centrally located opening which is in correspondence with an exhaust gas passageway formed by the interior of the exhaust gas conduit and which is interfaceable with an exhaust gas outlet of the marine engine.

25. The method of claim 24, wherein the step of forming the flange portion of the exhaust gas conduit comprises forming at least one peripheral opening adjacent the centrally located opening, said at least one peripheral opening being in correspondence with the cooling water channel and interfaceable with a cooling water outlet of the marine engine.

26. The method of claim 22, wherein the step of forming the exhaust gas conduit comprises the steps of:

(a) placing a mandrel having the shape of the interior surface of the conduit into a cavity of a mold, said cavity having the shape of the exterior of the conduit;

(b) injecting a quantity of bulk molding compound into the cavity of the mold, said bulk molding compound comprising a pre-ceramic resin and fibers;

(c) heating the mold at a temperature and for a time associated with the pre-ceramic resin which polymerizes the resin to form a fiber-reinforced polymer composite conduit;

(d) removing the polymerized composite conduit from the mold;

(e) removing the mandrel; and

(f) firing the polymerized composite conduit for a temperature and for a time associated with the polymerized resin which pyrolizes it.

27. The method of claim 26, further comprising upon the completion of step (e), the steps of:

(f) immersing the conduit containing pores formed during firing into a bath of a pre-ceramic resin to fill the pores;

(g) heating the conduit at a temperature and for a time associated with the resin filling said pores so as to transform it to a ceramic material;

(h) repeating steps (f) and (g) until the pore density within the exhaust gas conduit is less than a prescribed percentage by volume.

28. The method of claim 26, wherein the mandrel comprises a melt-out material and the step of removing the mandrel comprises melting it.

29. The method of claim 26, wherein the mandrel comprises a washout material and the step of removing the mandrel comprises dissolving it.

30. The method of claim 23, wherein the step of forming the water jacket sleeve comprises the steps of:

(a) centering the exhaust gas conduit in a cavity of a mold, said cavity corresponding to the dimensions of an interior wall of the water jacket sleeve;

(b) introducing one of a melt-out or wash-out material into the cavity of the mold so as to coat the exhaust gas conduit and form a mandrel;

(c) centering the mandrel into a cavity of a second mold, said second mold cavity corresponding to the dimensions of the exterior surface of the water jacket sleeve;

(d) injecting a plastic material into the cavity of the second mold;

(e) removing the riser elbow from the second mold; and

(f) one of (i) removing the melt-out material by melting it, or (ii) removing the wash-out material by dissolving it.

31. The method of claim 30, wherein the plastic material is capable of withstanding long-term exposure to at least 250 degree Fahrenheit salt water without structural degradation.