Baffle for conversion of fine bubbles to coarse while filtering with a vertical skein of hollow fibers

• US 5,910,250 A
• Filed: 06/16/1997
• Issued: 06/08/1999
• Est. Priority Date: 08/11/1995
• Status: Expired due to Term

• Current Assignee: Zenon Technology Partnership
• Original Assignee: Zenon Environmental Incorporated (Veolia Environnement SA)
• Inventors: Behmann, Henry, Henshaw, Wayne Jerald, Mahendran, Mailvaganam, Deutschmann, Ake Adolf
• Primary Examiner(s): FORTUNA, ANA M
• Application Number:
  US08/896,517
• Time in Patent Office: 722 Days
• Field of Search: 210/500.23, 210/636, 210/650, 210/321.69, 210/356, 210/321.8, 210/321.89, 210/257.2, 210/220, 210/258
• US Class Current: 210/636
• CPC Class Codes: B01D 2315/06 Submerged-type; Immersion type
• CPC Class Codes: B01D 2321/04 Backflushing
• CPC Class Codes: B01D 2321/12 Use of permeate
• CPC Class Codes: B01D 2321/185 Aeration
• CPC Class Codes: B01D 2321/2066 Pulsated flow
• CPC Class Codes: B01D 61/18 Apparatus therefor
• CPC Class Codes: B01D 61/20 Accessories; Auxiliary operations
• CPC Class Codes: B01D 63/0222 using centrifugal forces
• CPC Class Codes: B01D 63/023 Encapsulating materials
• CPC Class Codes: B01D 63/0231 using supporting structures, e.g. filaments for weaving mats
• CPC Class Codes: B01D 63/026 Wafer type modules or flat-surface type modules
• CPC Class Codes: B01D 63/027 Twinned or braided type modules
• CPC Class Codes: B01D 63/04 comprising multiple hollow fibre assemblies
• CPC Class Codes: B01D 63/043 with separate tube sheets
• CPC Class Codes: B01D 65/02 Membrane cleaning or sterilisation ; Membrane regeneration
• CPC Class Codes: B01D 65/08 Prevention of membrane fouling or of concentration polarisation
• CPC Class Codes: C02F 1/444 by ultrafiltration or microfiltration
• CPC Class Codes: C02F 3/1273 Submerged membrane bioreactors
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 264/48 Processes of making filters

Abstract

A filtration device is provided for withdrawing permeate essentially continuously from a multicomponent aqueous substrate containing growing microorganisms in a reservoir. A vertical skein of fiber is scrubbed with coarse bubbles which emanate from a conversion baffle positioned under the skein. The substrate is aerated with fine bubbles in a size range small enough to transfer oxygen to the substrate efficiently. The baffle traps the fine bubbles and converts them to coarse bubbles which are effective to scrub the fibers. In the most preferred embodiment, the finished headers of the skein are derived from composite headers comprising a fixing lamina of resin in which the fibers are potted near their terminal ends, and a fugitive lamina of fugitive powdery material in which the terminal ends of the fibers are potted. The fugitive lamina is removed, preferably by dissolving the powder, e.g. finely divided common salt in water.

Claims

1. In a filtration device for withdrawing permeate essentially continuously from a multicomponent liquid substrate in a reservoir while increasing the concentration of particulate material therein, said membrane device including:

a multiplicity of hollow fiber membranes, or fibers;

a first header and a second header disposed in transversely spaced-apart relationship with at least said second header within said substrate;

said first header having a terminal end portion of each fiber secured therein, and said second header having an opposed terminal end portion of each fiber secured therein, all said fibers extending from a face of each said header and essentially all said fibers being open at their ends;

said fibers being sealingly secured with open ends of the fibers secured in fluid-tight relationship with each other in each of said headers;

permeate collection means to collect said permeate, sealingly connected in open fluid communication with a permeate-discharging face of each of said headers; and

, means to withdraw said permeate;

said fibers, said headers and said permeate collection means together forming a vertical skein wherein said fibers are essentially vertically disposed;

said first header being upper and disposed in vertically spaced-apart relationship above said second header, with opposed faces at a fixed distance;

each of said fibers having substantially the same length, the improvement comprising, a foraminous conversion baffle removably secured to said second header near the permeate discharging face thereof, said baffle being adapted to trap and discharge gas flowing under said baffle in a vertically upward direction, said baffle having through-openings therein sized to discharge said gas as coarse bubbles in a size range effective to scrub outer surfaces of said fibers.

2. The membrane device of claim 1 wherein said through-openings are adjacent a major portion of said second header'"'"'s periphery.

3. The membrane device of claim 2 wherein said baffle is disposed between opposed walls adapted to confine said fine bubbles under said baffle, and, to maintain said baffle in vertically spaced-apart relationship with said reservoir'"'"'s floor.

4. The membrane device of claim 3 wherein said first and second headers are each a rectangular parallelpiped, said first header is disposed parallel to said second header, and said baffle is rectangular and generally coextensive with said second header.

5. The membrane device of claim 4 wherein said fibers are unconfined in a shell of a module, said fibers together haven surface area >

1 m², said fibers are subject to a transmembrane pressure differential in the range from about 0.7 kPa (0.1 psi) to about 345 kPa (50 psi), and each fiber has a length >

0.5 meter.

6. In a gas-scrubbed assembly comprising, a filtration membrane device in combination with a gas-distribution means adapted concurrently to provide a growth environment for microorganisms and to minimize build-up of particulate deposits only the surfaces of hollow fiber membranes ("fibers") in said device, and to recover permeate from a multicomponent liquid substrate while leaving particulate matter therein, said membrane device comprising,

a multiplicity of fibers secured at opposed ends in first and second headers disposed in spaced-apart relationship within said substrate, all said fibers extending from a face of each said header and essentially all said fibers being open at their ends;

said fibers being sealingly secured with open ends thereof secured in fluid-tight relationship with each other in each of said headers;

permeate collection means to collect said permeate, sealingly connected in open fluid communication with a permeate-discharging face of each of said headers;

means for withdrawing said permeate; and

,

said gas-distribution means is located within a zone beneath said skein, said gas-distribution means discharges gas to generate enough bubbles flowing in a column of rising bubbles through and around said skein fibers, to keep surfaces of said fibers awash in bubbles;

said fibers, said headers and said permeate collection means together forming a skein wherein said fibers are essentially vertically disposed;

said first header being upper and disposed in vertically spaced-apart relationship above said second header at a fixed distance;

each of said fibers having substantially the same length,

the improvement comprising,

a foraminous conversion baffle removably secured to said second header at the permeate discharging face thereof, said baffle being adapted to trap and discharge said gas flowing under said baffle in a vertically upward direction, said baffle having through-openings therein sized to discharge said gas as coarse bubbles in a size range effective to scrub outer surfaces of said fibers; and

,

said gas-distribution means is adapted to discharge fine bubbles directly beneath said baffle in a size range adapted to provide a desirable utilization rate by microorganisms in said substrate;

whereby said permeate is essentially continuously withdrawn while concentration of said particulate matter in said substrate is increased.

7. The gas-scrubbed assembly of claim 6 wherein said fine bubbles are in the size range from about 0.5 mm to about 3 mm in average diameter, measured within a fine-bubble discharge zone about 10 cm from said gas-distribution means'"'"' gas-discharging surface.

8. The gas-scrubbed assembly of claim 6 wherein said coarse bubbles are in the size range from about 10 mm to about 50 mm in average diameter, measured within a coarse-bubble discharge zone about 10 cm from said baffle'"'"'s gas-discharging surface.

9. In a process for maintaining the outer surfaces of hollow fiber membranes of a vertical skein having fibers of substantially the same length secured at opposed ends in first and second headers, essentially free from a build-up of deposits of particulate material while separating a permeate from a multi component liquid substrate having growing microorganisms therein requiring an environment of gas by submerging skein fibers in a reservoir of said substrate,

said process comprising,

flowing said gas through a gas-distribution means disposed beneath said skein,

collecting said permeate in said collection means;

and, withdrawing said permeate,

the improvement comprising,

introducing said gas as fine bubbles, in a size range adapted to provide a desirable utilization rate by microorganism in said substrate, beneath a fine-bubble trapping zone bounded by a foraminous conversion baffle under said second header near the permeate discharging face thereof; and

,

discharging said gas from said baffle adjacent a major portion of said second header'"'"'s periphery, as coarse bubbles in a size range effective to scrub outer surfaces of said fibers.