Metal nanolaminate composite

• US 5,912,069 A
• Filed: 12/19/1996
• Issued: 06/15/1999
• Est. Priority Date: 12/19/1996
• Status: Expired due to Term

• Current Assignee: Sigma Laboratories Of Arizona LLC
• Original Assignee: Sigma Laboratories Of Arizona LLC
• Inventors: Yializis, Angelo, Ellwanger, Richard E.
• Primary Examiner(s): Smith, Lynette F.
• Assistant Examiner(s): LEE, DATQUAN HUU
• Application Number:
  US08/769,422
• Time in Patent Office: 908 Days
• Field of Search: 427/44, 427/81, 427/251, 427/255.5, 427/255.6, 428/660, 428/610, 428/627, 428/632, 428/635, 428/698, 428/702, 428/628, 428/629, 428/213, 428/212, 428/411.1, 428/402, 428/457
• US Class Current: 428/213
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: Y10T 428/24942 including components having same physical characteristic in differing degree
• CPC Class Codes: Y10T 428/2495 Thickness [relative or absolute]
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/31504 Composite [nonstructural laminate]
• CPC Class Codes: Y10T 428/31678 Of metal

Abstract

Metal-polymer nanolaminate products are fabricated from a bulk nanolaminate material composed of thousands of alternating metal and polymer layers. The nanolaminate material is produced by a prior art ultra high speed vacuum nanotechnology process that forms metal layers separated by radiation cross linked multifunctional acrylate polymer materials. The polymer to metal ratio in the nanolaminate composite can be successfully controlled. The polymer chemistry in the nanolaminate can be varied to incorporate a broad range of functional groups. The nanolaminate products are safe to handle and are environmentally and chemically stable at least up to 250° C. A change in polymer chemistry can be used to lower or enhance the thermal degradation point of the polymer material.

Claims

1. A metal-polymer laminate wherein at least 50% of the weight comprises at least one metal component, said metal-polymer laminate having at least 1,000 alternating metal and polymer layers and produced in a vacuum environment by successive, sequential deposition of the metal and polymer layers, wherein each metal layer has a thickness of at least 20 nm, wherein each polymer layer has a thickness of at least 20 nm, and wherein the ratio of the metal layer thickness to the polymer layer thickness is at least 0.9.

2. The metal-polymer laminate of claim 1 wherein the bulk multilayer material is reduced to a powder.

3. The metal-polymer laminate of claim 1 wherein said at least one metal component is selected from the following group of metallic elements, all of which release heat upon combustion to the oxide:

Al, B, Si, Ti, Li, Na, K, Fe, Mg, and Hf.

4. The metal-polymer laminate of claim 1 wherein the polymer includes at least one functional group, which is chosen to enhance combustion of the metal component.

5. The metal-polymer laminate of claim 4 wherein the polymer contains at least one of the following elements, all of which can enhance combustion of the metal component:

O, F, Cl, N.

6. The metal-polymer laminate of claim 1 wherein the polymer is chosen to form bonds to propellant binders.

12. The metal-polymer laminate of claim 6 wherein said propellant binders comprise hydroxy-terminated polybutadiene.

7. A metal-polymer-liquid laminate wherein at least 50% of the weight is comprised of one or more metal components, having at least 1000 alternating metal and polymer layers, having at least one liquid layer, and which is produced in a vacuum environment by successive, sequential deposition of the metal and polymer layers, wherein each metal layer has a thickness of least 20 nm, wherein each polymer layer has a thickness of at least 20 nm, each liquid layer has a thickness of less than 20 nm, and the ratio of the metal layer thickness to the polymer layer thickness is at least 0.9.

8. The metal-polymer laminate of claim 7 wherein the bulk multilayer material is reduced to a powder.

9. The metal-polymer laminate of claim 7 wherein said at least one metal component is selected from the following group of metallic elements, all of which release heat upon combustion to the oxide:

Al, B, Si, Ti, Li, Na, K, Fe, Mg, and Hf.

10. The metal-polymer laminate of claim 7 wherein the polymer has at least one functional group and wherein either the polymer or the liquid layer or both are chosen to enhance combustion of the metal component.

11. The metal-polymer laminate of claim 10 wherein the polymer contains at least one of the following elements, all of which can enhance combustion of the metal component:

O, F, Cl, N.