Electrophotographic photosensitive member and electrophotographic apparatus and process cartridge including same

• US 5,912,098 A
• Filed: 03/26/1997
• Issued: 06/15/1999
• Est. Priority Date: 03/27/1996
• Status: Expired due to Term

• Current Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Original Assignee: Canon Kabushiki Kaisha (Canon Inc.)
• Inventors: Yoshida, Akira, Kitamura, Wataru, Tanaka, Takakazu, Hirano, Hidetoshi, Anayama, Hideki
• Primary Examiner(s): Goodrow, John
• Application Number:
  US08/824,334
• Time in Patent Office: 811 Days
• Field of Search: 430/66, 430/67, 399/147
• US Class Current: 430/67
• CPC Class Codes: G03G 5/14704 comprising inorganic material
• CPC Class Codes: G03G 5/14773 Polycondensates comprising silicon atoms in the main chain
• CPC Class Codes: G03G 5/14791 Macromolecular compounds characterised by their structure, e.g. block polymers, reticulated polymers, or by their chemical properties, e.g. by molecular weight or acidity

Abstract

An electrophotographic photosensitive member is constituted by at least a support, a photosensitive layer disposed on the support, and a protective layer disposed on the photosensitive layer. The protective layer comprises a cured product obtained from a condensation product between a silyl acrylate compound and colloidal silica. The protective layer is effective in providing the photosensitive member with improved potential stability against a change in environmental conditions and an excellent durability.

Claims

1. An electrophotographic photosensitive member, comprising:

at least a support, a photosensitive layer disposed on the support, and a protective layer disposed on the photosensitive layer,

wherein said protective layer comprises a cured product obtained from a condensation product between a silyl acrylate compound and colloidal silica.

2. A member according to claim 1, wherein said silyl acrylate compound has at least one alkoxysilyl group and at least one double bond.

3. A member according to claim 1, wherein said silyl acrylate compound is represented by the following formula (1):

##STR12## wherein R denotes an alkyl group;

R² denotes an alkyl group, an alkoxy group or an aryl group;

R³, R⁴, R⁵ and R⁶ independently denote hydrogen atom, an alkyl group, an alkoxy group or an aryl group;

R⁷ denotes an alkylene group;

m is an integer of 0-2 and n is an integer of 1-3 satisfying 0<

m+n≦

3; and

p and q independently denotes an integer of at least 0.

4. A member according to claim 1, wherein said cured product is obtained from said condensation product and a polyfunctional acrylic monomer.

5. A member according to claim 1, wherein said protective layer comprises electroconductive particles.

6. A member according to claim 5, wherein said electroconductive particles comprise a metal oxide.

13. An electrophotographic apparatus, comprising:

an electrophotographic photosensitive member according to claim 1 or 7, charging means for charging said photosensitive member, imagewise exposure means for exposing imagewise the charged photosensitive member to form an electrostatic latent image on said photosensitive member, and developing means for developing the latent image with a toner.

14. A process cartridge, comprising:

an electrophotographic photosensitive member according to claim 1 or 7 and charging means for charging said photosensitive member.

15. A process cartridge according to claim 14, which comprises developing means for developing an electrostatic image formed on said photosensitive member.

7. An electrophotographic photosensitive member, comprising:

at least a support, and a charge generation layer, a charge transport layer and a protective layer disposed in this order on the support,

wherein said charge transport layer comprises a polysilane, and said protective layer comprises a cured product obtained from a condensation product between a silyl acrylate compound and colloidal silica.

8. A member according to claim 7, wherein said silyl acrylate compound has at least one alkoxysilyl group and at least one double bond.

9. A member according to claim 7, wherein said silyl acrylate compound is represented by the formula (1) shown below and said polysilane is represented by the formula (2) shown below:

##STR13## wherein R¹ denotes an alkyl group;

R² denotes an alkyl group, an alkoxy group or an aryl group;

R³, R⁴, R⁵ and R⁶ independently denote hydrogen atom, an alkyl group, an alkoxy group or an aryl group;

R⁷ denotes an alkylene group;

m is an integer of 0-2 and n is an integer of 1-3 satisfying 0<

m+n≦

3; and

p and q independently denotes an integer of at least 0; and

##STR14## wherein R⁸, R⁹ and R¹⁰ independently denote an alkyl group or an aryl group each optionally having a substituent;

each X independently denotes an alkyl group optionally having a substituent, an alkoxy group optionally having a substituent, an aryl group optionally having a substituent, or a halogen atom; and

r, s and t independently denote an integer of at least 0 satisfying r+s+t>

10.

10. A member according to claim 7, wherein said cured product is obtained from said condensation product and a polyfunctional acrylic monomer.

11. A member according to claim 7, wherein said protective layer comprises electroconductive particles.

12. A member according to claim 11, wherein said electroconductive particles comprise a metal oxide.