Inkjet ink and process for the production thereof

• US 5,913,971 A
• Filed: 07/25/1997
• Issued: 06/22/1999
• Est. Priority Date: 03/17/1995
• Status: Expired due to Term

• Current Assignee: TOYO Ink Manufacturing Company Limited
• Original Assignee: TOYO Ink Manufacturing Company Limited
• Inventors: Ando, Motonori, Fujimatsu, Shinya, Iida, Yasuharu
• Primary Examiner(s): Mulcahy, Peter D.
• Application Number:
  US08/897,974
• Time in Patent Office: 697 Days
• Field of Search: 524/562, 106/20 D, 106/31.86
• US Class Current: 106/31.86
• CPC Class Codes: C09D 11/322 Pigment inks

Abstract

An inkjet ink having sufficient water resistance on a recording sheet but having excellent re-solubility in an ink in a head portion and excellent ejection stability through a nozzle, the inkject ink comprising an aqueous liquid, a pigment and a water-soluble resin, the water-soluble resin being a terpolymer obtained from acrylic acid, styrene and α-methyl styrene and having a weight average molecular weight of 2,000 to 8,000 and an acid value of 90 to 130, and a process for the production of the inkjet ink, which comprises preparing a concentrated aqueous dispersion of a pigment and a terpolymer obtained from acrylic acid, styrene and α-methylstyrene, adding water and an additive to the concentrated dispersion to dilute the concentrated dispersion and maintaining the diluted dispersion at a temperature between 60° C. and 80° C. for 5 to 48 hours.

Claims

1. An inkjet ink consisting essentially of an aqueous liquid containing water and a water-soluble solvent, a carbon black pigment and 0.5 to 10% by weight of a water-soluble resin, the water-soluble resin being a terpolymer obtained from acrylic acid, styrene and α

-methyl styrene and having a weight average molecular weight of 2,000 to 8,000 and an acid value of 90 to 130 and the styrene and the α

-methyl styrene being employed in a total amount of 3 to 5 mole per mole of the acrylic acid, said ink having a resistance value, measured at an inter-electrode distance of 5 mm, of at least 10⁶ Ω

on a set-solid print surface.

2. A process for the production of an inkjet ink as defined in claim 1, which comprises preparing a concentrated aqueous dispersion of a carbon black pigment and a water-soluble terpolymer resin obtained from acrylic acid, styrene and α

-methyl styrene and having a weight average molecular weight of 2,000 to 8,000 and an acid value of 90 to 130 and the styrene and α

-methyl styrene being employed in a total amount of 3 to 5 mole per mole of the acrylic acid, adding water and an additive to the concentrated dispersion to dilute the concentrated dispersion and maintaining the diluted dispersion at a temperature between 60° and

80°

C. for 5 to 48 hours the amount of the water-soluble terpolymer resin in the inkjet ink being 0.5 to 10% by weight.

3. An inkjet ink according to claim 1, wherein the terpolymer is a product obtained using 1.5 to 4.0 mol, per mole of the acrylic acid, of the styrene and 0.3 to 2.5 mol, per mole of the acrylic acid, of the α

-methyl styrene.

4. An inkjet ink according to claim 1, wherein the inkjet ink contains the terpolymer and a neutralizing agent in an amount which is equimolar to an amount of the terpolymer or greater than the amount of the terpolymer by several percent.

5. An inkjet ink according to claim 1, wherein the inkjet ink contains 85 to 95% by weight of the aqueous liquid, 0.5 to 5% by weight of the pigment and 0.5 to 10% by weight of the terpolymer.

6. An inkjet ink according to claim 5, wherein the inkjet ink further contains 0.03 to 0.5% by weight of a biocide.

7. An inkjet ink according to claim 1, wherein the inkjet ink is a product obtained by filtering through a filter having a pore size of 0.65 μ

m or smaller.

8. An inkjet ink according to claim 1, wherein the inkjet ink has a viscosity, measured at 25°

C., of 0.8 to 15 cps.

9. A process according to claim 2, wherein the additive is at least one member selected from the group consisting of a biocide, a water-soluble solvent, a dye, a neutralizing agent, a penetrant, a chelating agent, a pH adjuster, an anti-foaming agent and a dispersing agent.