Degradable polymer and preparation process of the same
First Claim
1. A process for preparing a degradable polymer comprising reacting, by dehydration condensation in the presence of a catalyst,component (A):
- aliphatic hydroxycarboxylic acid,component (B);
only one material selected from the group consisting of;
(b-1) polycarboxylic acid having three or more carboxyl groups and/or anhydride thereof,and (b-3) aliphatic polyhydric alcohol having three or more hydroxyl groups with the proviso that the aliphatic polyhydric alcohol having three or more hydroxyl groups is not a polysaccharide, andcomponent (C);
only one material which can conduct an esterification reaction with compound (B) and is selected from the group consisting of(c-1) polycarboxylic acid having two or more carboxyl groups and/or anhydride thereof, and(c-3) aliphatic polyhydric alcohol having two or more hydroxyl groups wherein the amount of component (B) corresponds to 0.005-10% by weight for the theoretical amount of the polymer resulting from complete hompolycondensation of component (A) and an equivalent ratio of component (B) to component (C) is 100;
90-110.
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Abstract
A degradable polymer and a process for preparing the degradable polymer which has a structure resulting from combination of a star-shaped polymer comprising a polyfunctional base compound of polycarboxylic acid having three or more carboxyl groups and/or anhydride of the same or aliphatic polyhydric alcohol having three or more hydroxyl groups and a unit of aliphatic hydroxycarboxylic acid, with aliphatic polyhydric alcohol having two or more hydroxyl groups or polycarboxylic acid having two or more carboxyl groups or anhydrides of the same. The degradable polymer leads to remarkably low coloration as compared with a polymer comprising polysaccharide as a polyfunctional base compound, has high melt tension as compared to common aliphatic polyester is excellent in processability on various molding methods, foam molding and blow molding in particular, and high transparency.
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Citations
18 Claims
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1. A process for preparing a degradable polymer comprising reacting, by dehydration condensation in the presence of a catalyst,
component (A): - aliphatic hydroxycarboxylic acid,
component (B);
only one material selected from the group consisting of;(b-1) polycarboxylic acid having three or more carboxyl groups and/or anhydride thereof, and (b-3) aliphatic polyhydric alcohol having three or more hydroxyl groups with the proviso that the aliphatic polyhydric alcohol having three or more hydroxyl groups is not a polysaccharide, and component (C);
only one material which can conduct an esterification reaction with compound (B) and is selected from the group consisting of(c-1) polycarboxylic acid having two or more carboxyl groups and/or anhydride thereof, and (c-3) aliphatic polyhydric alcohol having two or more hydroxyl groups wherein the amount of component (B) corresponds to 0.005-10% by weight for the theoretical amount of the polymer resulting from complete hompolycondensation of component (A) and an equivalent ratio of component (B) to component (C) is 100;
90-110. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8, 9, 10, 13, 14, 15)
- aliphatic hydroxycarboxylic acid,
- 11. A process for preparing a degradable polymer comprising reacting, in the presence of a catalyst, only a), b) and c) wherein a) is a cyclic dimer and/or lactone of aliphatic hydroxycarboxylic acid, b) is an aliphatic polyhydric alcohol having three or more hydroxyl groups with the proviso that the aliphatic polyhydric alcohol is not a polysaccharide, and c) is a polycarboxylic acid having two or more carboxyl groups and/or anhydride of the same.
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16. A degradable polymer having a structure resulting from combination of a star-shaped polymer comprising only a polyfunctional base compound of polycarboxylic acid having three or more carboxyl groups and/or anhydride of the same and a unit of aliphatic hydroxycarboxylic acid, with aliphatic polyhydric alcohol having two or more hydroxyl groups with the proviso that the aliphatic polyhydric alcohol is not a polysaccharide.
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17. A degradable polymer having a structure resulting from combination of a star-shaped polymer comprising only a polyfunctional base compound of polyhydric alcohol having three or more hydroxyl groups with the proviso that the aliphatic polyhydric alcohol is not a polysaccharide and a unit of aliphatic hydroxycarboxylic acid, with polycarboxylic acid having two or more carboxyl groups and/or anhydride of the same.
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18. A process for preparing a degradable polymer comprising reacting by dehydrating condensation in the presence of a catalyst, L-lactic acid, pentacrythritol and succinic acid.
Specification