Process for producing polymer grade olefins

• US 5,914,433 A
• Filed: 07/22/1997
• Issued: 06/22/1999
• Est. Priority Date: 07/22/1997
• Status: Expired due to Term

• Current Assignee: UOP Llc (Honeywell International Inc.)
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Marker, Terry L.
• Primary Examiner(s): Caldarola, Glenn A.
• Assistant Examiner(s): Dang, Thuan D.
• Application Number:
  US08/898,283
• Time in Patent Office: 700 Days
• Field of Search: 585/312, 585/311, 585/313, 585/314, 585/315, 585/324, 585/328, 585/329, 585/330, 585/639, 585/648, 585/653, 208/57, 208/44
• US Class Current: 585/313
• CPC Class Codes: B01J 29/84 Aluminophosphates containing other elements, e.g. metals, boron
• CPC Class Codes: B01J 29/85 Silicoaluminophosphates [SAPO compounds]
• CPC Class Codes: B01J 29/90 Regeneration or reactivation
• CPC Class Codes: C07C 1/20 starting from organic compounds containing only oxygen atoms as heteroatoms
• CPC Class Codes: C07C 11/20 1, 3-Pentadiene
• CPC Class Codes: C07C 2529/85 Silicoaluminophosphates (SAPO compounds)
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts
• CPC Class Codes: Y02P 20/584 Recycling of catalysts
• CPC Class Codes: Y02P 30/20 using bio-feedstock
• CPC Class Codes: Y02P 30/40 Ethylene production

Abstract

The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from an oxygenate feedstock. The process comprises passing the oxygenate feedstock to an oxygenate conversion zone containing a metal aluminophosphate catalyst to produce a light olefin stream. A propylene stream and/or mixed butylene is fractionated from said light olefin stream and cracked to enhance the yield of ethylene and propylene products. This combination of light olefin product and propylene and butylene cracking in a riser cracking zone or a separate cracking zone provides flexibility to the process which overcomes the equilibrium limitations of the aluminophosphate catalyst. In addition, the invention provides the advantage of extended catalyst life and greater catalyst stability in the oxygenate conversion zone.

Claims

1. A process for producing polymer grade olefins comprising:

a) passing an oxygenate feedstock comprising an alcohol or an ether having from 1 to 4 carbon atoms per molecule to a fluidized reaction zone containing an aluminophosphate molecular sieve catalyst in the presence of a diluent at conditions effective to convert the oxygenate feedstock to a light olefin product stream comprising ethylene, propylene, butylene and to produce a spent aluminophosphate molecular sieve catalyst;

b) passing the light olefin product stream to a separation zone to separate the light olefin product stream into an ethylene stream, a propylene stream, and a mixed butylene and heavier stream;

c) withdrawing at least a portion of the spent aluminophosphate molecular sieve catalyst from the fluidized reaction zone and passing the spent aluminophosphate molecular sieve catalyst to a regenerator to regenerate the spent aluminophosphate molecular sieve catalyst with an oxygen-containing stream to produce a regenerated catalyst; and

,

d) returning a first portion of the regenerated catalyst to the fluidized reaction zone and admixing a second portion of the regenerated catalyst with a portion of the mixed butylene and heavier stream to provide a feed admixture and passing the feed admixture to a cracking reaction zone at conditions effective to convert the mixed butylene and heavier stream to produce a second product stream comprising additional amounts of ethylene and propylene and to produce a third regenerated catalyst portion; and

,

e) passing at least a portion of the second product stream to the fluidized reaction zone.

2. The process of claim 1 further comprising passing the third regenerated catalyst portion to the fluidized reaction zone.

3. The process of claim 2 further comprising preheating the mixed butylene and heavier stream prior to admixing the mixed butylene and heavier stream with the second portion of the regenerated catalyst.

4. The process of claim 1 further comprising passing the third regenerated catalyst portion to the regenerator.

5. The process of claim 1 where a weight ratio of catalyst to the mixed butylene and heavier stream in the second reaction zone is less than about 20.

6. The process of claim 1 further comprising passing the mixed butylene and heavier stream to a selective hydrogenation zone prior to admixing the mixed butylene and heavier stream with the second portion of the regeneration catalyst.

7. The process of claim 1 further comprising withdrawing a portion of the mixed butylene and heavier stream as a drag stream.

8. The process of claim 1 wherein said catalyst is characterized by an empirical composition on an anhydrous basis by the formula:

space="preserve" listing-type="equation">(EL.sub.x Al.sub.y P.sub.z)O.sub.2

where EL is an element selected from the group consisting of silicon, magnesium, zinc, iron, cobalt, nickel, manganese, chromium, and mixtures thereof, x is the mole fraction of EL and is at least 0.005, y is the mole fraction of Al and is at least 0.01, and z is the mole fraction of P and is at least 0.01 and x+y+z=1.

9. The process of claim 8, wherein said aluminophosphate catalyst is selected from the group consisting of SAPO-34, SAPO-17, and mixtures thereof.

10. The process of claim 1 wherein said aliphatic hetero compound feedstock is selected from the group of methanol, ethanol, propanol, dimethyl ether and mixtures thereof.

11. The process of claim 1 wherein said oxygenate feedstock comprises methanol.

12. The process of claim 1 further comprising withdrawing a portion of the propylene stream as a propylene product.

13. The process of claim 1 wherein said diluent comprises helium, argon, nitrogen, carbon monoxide, carbon dioxide, hydrogen, water, paraffins, aromatic compounds, and mixtures thereof.

14. The process of claim 1 wherein a weight ratio of the mixed butylene and heavier stream to the propylene stream comprises less than about 0.30.

15. A process for the production of light olefins comprising ethylene from a feedstock comprising methanol, said process comprising:

a) passing said feedstock in the presence of a diluent to a reaction zone containing an aluminophosphate catalyst at conditions effective to convert at least a portion of said feedstock to form a first reactor effluent stream comprising ethylene, propylene, and butylene and heavier olefins;

b) passing said first reactor effluent stream and a second reactor effluent stream to a C₂ fractionation zone to provide an ethylene product stream and a C₃ and heavier stream;

c) passing the C₃ and heavier stream to a C₃ fractionation zone to provide a propylene stream and a mixed butylene and heavier stream;

d) cracking at least a portion of said mixed butylene and heavier stream in a separate cracking zone to provide the second reactor effluent stream, and returning said second reactor effluent stream to said C₂ fractionation zone; and

e) passing a portion of the mixed butylene stream to a polymerization zone at conditions effective to produce a polymer gasoline and passing at least a portion of said polymer gasoline to said separate cracking zone.

16. The process of claim 15 wherein said aluminophosphate catalyst comprises SAPO-34.

17. The process of claim 15 wherein said aluminophosphate catalyst comprises SAPO-17.

18. The process of claim 15 further comprising passing at least a portion of said propylene to said separate cracking zone.

19. The process of claim 15 further comprising passing a portion of the propylene stream to said polymerization zone.