Liquefaction process

• US 5,916,260 A
• Filed: 07/13/1998
• Issued: 06/29/1999
• Est. Priority Date: 10/05/1995
• Status: Expired due to Fees

• Current Assignee: BHP Billiton Petroleum Pty Limited (BHP Group Ltd.)
• Original Assignee: BHP Petroleum (Pakistan) Pty Ltd.
• Inventors: Dubar, Christopher A. T.
• Primary Examiner(s): DOERRLER, WILLIAM CHARLES
• Application Number:
  US09/051,221
• Time in Patent Office: 351 Days
• Field of Search: 62/613, 62/614, 62/619, 62/912
• US Class Current: 62/613
• CPC Class Codes: F25J 1/0022 Hydrocarbons, e.g. natural gas
• CPC Class Codes: F25J 1/0042 by liquid expansion with extraction of work
• CPC Class Codes: F25J 1/005 by expansion of a gaseous refrigerant stream with extraction of work
• CPC Class Codes: F25J 1/0072 Nitrogen
• CPC Class Codes: F25J 1/0097 Others, e.g. F-, Cl-, HF-, HClF-, HCl-hydrocarbons etc. or mixtures thereof
• CPC Class Codes: F25J 1/0204 as a single flow SCR cycle
• CPC Class Codes: F25J 1/025 Details related to the refrigerant production or treatment, e.g. make-up supply from feed gas itself
• CPC Class Codes: F25J 1/0259 Modularity and arrangement of parts of the liquefaction unit and in particular of the cold box, e.g. pre-fabrication, assembling and erection, dimensions, horizontal layout "plot"
• CPC Class Codes: F25J 1/0267 using flash gas as heat sink
• CPC Class Codes: F25J 1/0278 Unit being stationary, e.g. on floating barge or fixed platform
• CPC Class Codes: F25J 1/0283 Gas turbine as the prime mechanical driver
• CPC Class Codes: F25J 1/0288 using work extraction by mechanical coupling of compression and expansion of the refrigerant, so-called companders
• CPC Class Codes: F25J 1/0294 Multiple compressor casings/strings in parallel, e.g. split arrangement
• CPC Class Codes: F25J 1/0297 using an externally chilled fluid, e.g. chilled water
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/70 Refluxing the column with a condensed part of the feed stream, i.e. fractionator top is stripped or self-rectified
• CPC Class Codes: F25J 2215/04 Recovery of liquid products
• CPC Class Codes: F25J 2230/22 Compressor driver arrangement, e.g. power supply by motor, gas or steam turbine
• CPC Class Codes: F25J 2230/60 the fluid being hydrocarbons or a mixture of hydrocarbons
• CPC Class Codes: F25J 2240/30 Dynamic liquid or hydraulic expansion with extraction of work, e.g. single phase or two-phase turbine
• CPC Class Codes: F25J 2245/02 : Recycle of a stream in general, e.g. a by-pass stream
• CPC Class Codes: F25J 2270/16 : with mutliple gas expansion loops of the same refrigerant
• CPC Class Codes: F25J 2290/10 : Mathematical formulae, modeling, plot or curves; Design methods
• CPC Class Codes: F25J 2290/60 : Details about pipelines, i.e. network, for feed or product distribution
• CPC Class Codes: F25J 2290/72 : Processing device is used off-shore, e.g. on a platform or floating on a ship or barge
• CPC Class Codes: F25J 3/0209 : Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 : separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0257 : separation of nitrogen from air F25J3/04, production of nitrogen in general C01B21/00
• CPC Class Codes: Y10S 62/912 : External refrigeration system

Abstract

A natural gas liquefaction process comprises passing natural gas through a series of heat exchangers in countercurrent relationship with a gaseous refrigerant circulated through a work expansion cycle. The work expansion cycle comprises compressing the refrigerant, dividing and cooling the refrigerant to produce at least first and second cooled refrigerant streams, substantially isentropically expanding the first refrigerant stream to a coolest refrigerant temperature, substantially isentropically expanding the second refrigerant stream to an intermediate refrigerant temperature warmer than said coolest refrigerant temperature, and delivering the refrigerant in the first and second refrigerant streams to a respective heat exchanger for cooling the natural gas through corresponding temperature ranges. The refrigerant in the first stream is isentropically expanded to a pressure at least 10 times greater than the total pressure drop of the first refrigerant stream across said series of heat exchangers, said pressure being in the range of 1.2 to 2.5 MPa.

Claims

1. A natural gas liquefaction process comprising passing natural gas through a series of heat exchangers in countercurrent relationship with a gaseous refrigerant circulated through a work expansion cycle, said work expansion cycle comprising compressing the refrigerant, dividing and cooling the refrigerant to produce at least first and second cooled refrigerant streams, substantially isentropically expanding the first refrigerant stream to a coolest refrigerant temperature, substantially isentropically expanding the second refrigerant stream to an intermediate refrigerant temperature warmer than said coolest refrigerant temperature, and delivering the refrigerant in the first and second refrigerant streams to a respective heat exchanger for cooling the natural gas through corresponding temperature ranges, wherein the refrigerant of the first stream is isentropically expanded to a pressure at least 10 times greater than the total pressure drop of the refrigerant of the first refrigerant stream across said series of heat exchangers, said pressure being in the range 1.2 to 2.5 MPa.

2. A process according to claim 1, wherein the refrigerant is compressed to a pressure in the range 5.5 to 10 MPa.

3. A process according to claim 1, wherein the first stream is isentropically expanded to a pressure in the range 1.5 to 2.5 MPa.

4. A process according to claim 1, wherein the refrigerant in the first stream is isentropically expanded to a pressure at least 20 times greater than the total pressure drop of the first refrigerant stream across said series of heat exchangers.

5. A process according to claim 1, wherein the refrigerant in the first stream is isentropically expanded to a pressure not more than 100 times greater than the total pressure drop of the first refrigerant stream across said series of heat exchangers.

6. A process according to claim 1, wherein the refrigerant is compressed to a pressure in the range 7.5 to 9.0 MPa, the refrigerant in the first refrigerant stream is expanded to a pressure in the range 1.7 to 2.0 MPa, and the refrigerant in the first stream is isentropically expanded to a pressure in the range 15 to 20 times the total pressure drop of the first refrigerant stream across said series of heat exchangers.

7. A process according to any preceding claim, wherein the series of heat exchangers includes a final heat exchanger that receives refrigerant from the first refrigerant stream, the relative flowrates of the first and second refrigerant streams are such that the warming curve for the refrigerant comprises a plurality of segments of different gradient, the refrigerant is warmed in said final heat exchanger to a temperature below -80°

C., and the coolest refrigerant temperature and the flowrate of refrigerant in said first refrigerant stream are such that a part of the refrigerant warming curve relating to the final heat exchanger is at all times within 1 to 10°

C. of the corresponding part of the cooling curve for the natural gas.

8. A process according to claim 7, wherein coolest refrigerant temperature and the flowrate of refrigerant in said first refrigerant stream is such that the part of the refrigerant warming curve relating to the final heat exchanger is at all times within 1 to 5°

C. of the corresponding part of the cooling curve for the natural gas.

9. A process according to claim 7, wherein the first refrigerant stream is combined with the second refrigerant stream after the first refrigerant stream has passed through the final heat exchanger, and said combined first and second refrigerant streams are delivered to the intermediate heat exchanger.

10. A process according to claim 9, wherein the coolest refrigerant temperature is no greater than -130°

C.

11. A process according to claim 9, wherein the coolest refrigerant temperature is in the range -140°

C. to -160°

C.

12. A process according to claim 1, wherein the temperature of each refrigerant stream after each isentropic expansion is greater than 1-2°

C. above the saturation temperature of the refrigerant, whereby the refrigerant is essentially dry.

13. A process according to claim 1, wherein the second refrigerant stream is isentropically expanded to a pressure within 0.05 MPa of the pressure to which the first refrigerant stream is isentropically expanded.

14. A process according to claim 1, further comprising cooling the refrigerant between the compression and isentropic expansion steps to a temperature in the range -10 to 20°

C. by countercurrent heat exchange with a liquid coolant.

15. A process according to claim 14, wherein the liquid coolant is water.

16. A process according to claim 1, wherein the pressure of the natural gas fed to said series of heat exchangers is greater than 5.5 MPa.

17. A process according to claim 1, wherein the refrigerant contains at least 50 vol % nitrogen.

18. A process according to claim 17, wherein the refrigerant contains 100 vol % nitrogen.