Adhesive articles comprising acrylic pressure sensitive adhesives with controlled humidity response

• US 5,916,693 A
• Filed: 04/11/1997
• Issued: 06/29/1999
• Est. Priority Date: 05/26/1994
• Status: Expired due to Fees

• Current Assignee: Rohm and Haas Company (Dow, Inc.)
• Original Assignee: Rohm and Haas Company (Dow, Inc.)
• Inventors: Van Rheenen, Paul Ralph
• Primary Examiner(s): Henderson, Christopher
• Application Number:
  US08/838,837
• Time in Patent Office: 809 Days
• Field of Search: 428/514, 428/516, 428/520, 428/286
• US Class Current: 428/516
• CPC Class Codes: C08L 2666/28 Non-macromolecular organic substances
• CPC Class Codes: C09J 133/08 Homopolymers or copolymers of acrylic acid esters
• CPC Class Codes: C09J 2301/122 the adhesive layer being present only on one side of the carrier, e.g. single-sided adhesive tape
• CPC Class Codes: C09J 2301/302 the adhesive being pressure-sensitive, i.e. tacky at temperatures inferior to 30°C
• CPC Class Codes: C09J 7/385 Acrylic polymers
• CPC Class Codes: Y10T 428/31906 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31913 Monoolefin polymer

Abstract

A pressure-sensitive adhesive composition includes from about 30 weight percent to about 70 weight percent solids in an aqueous medium. The solids include an acrylic polymer having a glass transition temperature of from about -25° C. to about -85° C. and having an acid number of from about 3 to about 30 and from about 0.75 parts by weight to about 5 parts by weight of a humectant per 100 parts polymer.

Claims

1. An adhesive article, comprising:

a substrate layer; and

an adhesive layer, said adhesive layer comprising an acrylic polymer dispersed in an aqueous medium having a glass transition temperature of from about -25°

C. to about -85°

C. and an acid number of from about 3 to about 30 and from about 1 part by weight to about 2 parts by weight per 100 parts polymer of a non-volatile humectant dissolved in the aqueous medium, provided that the humectant is not urea.

2. The article of claim 1, wherein the substrate layer is a sheet of paper, a polymer film, a textile fabric or a nonwoven fiber sheet.

3. The article of claim 1, further comprising a release layer covering the adhesive layer.

5. The article of claim 1, 2, 3, or 4, wherein the humectant is selected from the group consisting of a polyol, a sugar, a protein-based humectant, and mixtures thereof.

6. The article of claim 1, 2, 3, or 4, wherein the humectant is selected from the group consisting of glycerol, polyethylene glycols having a molecular weight of from about 100 to about 1000, and mixtures thereof.

7. The article of claim 1, 2, 3, or 4, wherein the polymer has a glass transition temperature in the range of from about -30°

C. to about -65°

C.

4. A composite article, comprising a first substrate, a second substrate and an adhesive later interposed between the first and second substrates and bonding the first and second substrates together, wherein the adhesive layer comprises an acrylic polymer dispersed in an aqueous medium having a glass transition temperature of from about -25°

C. to about -85°

C. and an acid number of from about 3 to about 30 and from about 1 part by weight to about 2 parts by weight per 100 parts polymer of a non-volatile humectant dissolved in the aqueous medium, provided that the humectant is not urea.