Toner process with cationic salts

• US 5,919,595 A
• Filed: 01/13/1998
• Issued: 07/06/1999
• Est. Priority Date: 01/13/1998
• Status: Expired due to Term

• Current Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Original Assignee: Xerox Corporation (Xerox Holdings Corp.)
• Inventors: Sacripante, Guerino G., Ong, Beng S., Mychajlowskij, Walter, Patel, Raj D., Foucher, Daniel A.
• Primary Examiner(s): GOODROW, JOHN L
• Application Number:
  US09/006,553
• Time in Patent Office: 539 Days
• Field of Search: 430/137, 430/106
• US Class Current: 430/137.14
• CPC Class Codes: G03G 9/0804 whereby the components are brought together in a liquid dispersing medium
• CPC Class Codes: G03G 9/08755 Polyesters

Abstract

A process for the preparation of toner comprising mixing an emulsion latex, a colorant dispersion, and monocationic salt, and which mixture possesses an ionic strength of from about 0.001 molar (M) to about 5 molar, and optionally cooling.

Claims

1. A process for the preparation of toner comprising mixing an emulsion latex, a colorant dispersion, and monocationic salt, and which mixture possesses an ionic strength of from about 0.001 molar (M) to about 5 molar, and optionally cooling.

2. A process in accordance with claim 1 wherein the latex contains a sodio sulfonated polyester resin of from about 5 to about 500 nanometers in size diameter, a solution of the monocationic salt is added to the latex and colorant mixture, and cooling is accomplished.

3. A process in accordance with claim 1 wherein said emulsion latex contains a resin, and which latex is prepared by heating said resin in water at a temperature of from about 65°

C. to about 90°

C.;

thereafter there is added said colorant dispersion with shearing, followed by the addition to said resulting mixture of said monocationic salt until there results an increase in the latex viscosity of from about 2 centipoise to about 100 centipoise, and which mixture possesses an ionic strength of from about 0.001 to about 5 M;

heating the resulting mixture at a temperature of from about 45°

C. to about 80°

C. thereby enabling the simultaneous aggregation and coalescence of particles of resin and colorant resulting in toner of from about 2 to about 20 microns in volume average diameter with the size of the toner being retained upon quenching, or cooling the product mixture, followed by filtration and drying.

4. A process in accordance with claim 2 wherein the salt is sodium chloride, potassium chloride, sodium bromide, or potassium bromide.

5. A process in accordance with claim 3 wherein the ionic strength of the monocationic salt and the temperature of the aggregation/coalescence controls the final toner particle size, and which size is from about 4 to about 10 microns, and wherein said shearing is completed by homogenizing at from about 1,000 revolutions per minute to about 10,000 revolutions per minute, at a temperature of from about 25°

C. to about 35°

C., and for a duration of from about 1 minute to about 120 minutes.

6. A process in accordance with claim 3 wherein the colorant dispersion is generated by microfluidization in a microfluidizer, or in nanojet for a duration of from about 1 minute to about 120 minutes.

7. A process in accordance with claim 3 wherein shearing or homogenization is accomplished by homogenizing at from about 1,000 revolutions per minute to about 10,000 revolutions per minute for a duration of from about 1 minute to about 120 minutes.

8. A process in accordance with claim 1 wherein the emulsion latex contains a resin of (i) a polyester of poly(1,2-propylene-sodio 5-sulfoisophthalate), poly(neopentylene-sodio 5-sulfoisophthalate), poly(diethylene-sodio 5-sulfoisophthalate), copoly (1,2-propylene-sodio 5-sulfoisophthalate)-copoly-(1,2-propylene-terephthalatephthalate), copoly(1,2-propylene-diethylene-sodio 5-sulfoisophthalate)-copoly-(1,2-propylene-diethylene-erephthalatephthalate), copoly-(ethyle-neneopentylene-sodio 5-sulfoisophthalate)-copoly-(ethylene-neopentylene-terephthalate-phthalate), or copoly(propoxylated bisphenol A)-copoly-(propoxylated bisphenol A-sodio 5-sulfoisophthalate);

and wherein the salt is sodium chloride, potassium chloride, sodium bromide, or potassium bromide.

9. A process in accordance with claim 2 wherein the emulsion latex contains a resin of (i) a polyester of poly(1,2-propylene-sodio 5-sulfoisophthalate), poly(neopentylene-sodio 5-sulfoisophthalate), poly(diethylene-sodio 5-sulfoisophthalate), copoly(1,2-propylene-sodio 5-sulfoisophthalate)-copoly-(1,2-propylene-terephthalatephthalate), copoly(1,2-propylene-diethylene-sodio 5-sulfoisophthalate)-copoly-(1,2-propylene-diethylene-terephthalatephthalate), copoly(ethylene-neopentylene-sodio 5-sulfoisophthalate)-copoly-(ethylene-neopentylene-terephthalate-phthalate), or copoly(propoxylated bisphenol A)-copoly-(propoxylated bisphenol A-sodio 5-sulfoisophthalate).

10. A process in accordance with claim 2 wherein the colorant is carbon black, cyan, yellow, magenta, and mixtures thereof.

11. A process in accordance with claim 3 wherein the resin is from about 0.01 to about 0.2 micron in volume average diameter, and the colorant in the form of particles is from about 0.01 to about 500 nanometers in volume average diameter.

12. A process in accordance with claim 2 wherein the toner particles isolated are from about 2 to about 15 microns in volume average diameter, and the geometric size distribution thereof is from about 1.15 to about 1.35.

13. A process in accordance with claim 2 wherein there is added to the surface of the formed toner metal salts, metal salts of fatty acids, silicas, metal oxides, or mixtures thereof, each in an amount of from about 0.1 to about 10 weight percent of the obtained toner particles.

14. A process in accordance with claim 3 wherein the toner obtained after quenching is from about 3 to about 15 microns in volume average diameter, and the geometric size distribution thereof is from about 1.15 to about 1.30.

15. A process in accordance with claim 3 wherein the resin Tg is from about 50°

C. to about 65°

C.

20. A process in accordance with claim 2 wherein the colorant dispersion is prepared with a microfluidizer at from about 75°

C. to about 85°

C. for a duration of from about 1 hour to about 3 hours.

21. A process in accordance with claim 2 wherein subsequent to cooling the toner resulting is cooled to about 25°

C., followed by washing and drying.

22. A process in accordance with claim 1 wherein said ionic strength is from about 0.01 to about 2 M.

23. A process in accordance with claim 2 wherein said ionic strength is from about 0.01 to about 2 M.

24. A process in accordance with claim 1 wherein said monocationic salt is sodium chloride.

25. A process in accordance with claim 24 wherein said sodium chloride is added in a solution thereof, and wherein said solution possesses an ionic strength of about 0.856 molar.

29. A process in accordance with claim 1 wherein said emulsion latex is comprised of water and a resin.

30. A process in accordance with claim 1 wherein said emulsion latex contains a resin of copoly(1,2-propylene-diethylene)terephthalate-copoly(sodium sulfoisophthalate dicarboxylate).

16. A process for the preparation of toner comprising

mixing an emulsion latex comprised of sodio sulfonated polyester resin particles of less than about 0.1 micron in size diameter by heating said resin particles in water at a temperature of from about 15°

C. to about 30°

C. above the resin glass transition temperature and a colorant dispersion followed by the addition of a monoatomic halide until an increase in viscosity results, and wherein the latex mixture possesses an ionic strength of from about 0.001 M to about 5 M;

heating the resulting mixture at a temperature of from about 45°

C. to about 80°

C. thereby enabling aggregation and coalescence of particles of resin and colorant simultaneously, followed by cooling, isolating, washing and drying, and wherein there results toner particles of from about 2 to about 20 microns in volume average diameter.

17. A process for the preparation of toner comprising mixing an emulsion latex comprised of sodio sulfonated polyester resin particles, a colorant and a monocationic salt;

and heating the resulting mixture thereby simultaneously causing aggregation and coalescence.

18. A process in accordance with claim 17 wherein subsequent to coalescence the toner product mixture is cooled, followed by recovery of the toner product, washing and drying, and wherein the colorant is of submicron size.

19. A process in accordance with claim 18 wherein the toner product mixture is recovered by cooling to about 25°

C., and thereafter there is accomplished said washing and said drying.

26. A process for the preparation of toner consisting essentially of mixing an emulsion latex, a colorant dispersion, and monocationic salt, and which mixture possesses an ionic strength of from about 0.001 molar (M) to about 5 molar.

27. A process in accordance with claim 26 wherein said monocationic salt is sodium chloride, sodium bromide, sodium iodide, potassium chloride or potassium bromide.

28. A process in accordance with claim 26 wherein said monocationic salt is sodium chloride.