Pourable detergent concentrates which maintain or increase in viscosity after dilution with water

• US 5,922,664 A
• Filed: 05/06/1997
• Issued: 07/13/1999
• Est. Priority Date: 01/30/1995
• Status: Expired due to Fees

• Current Assignee: Colgate-Palmolive Company
• Original Assignee: Colgate-Palmolive Company
• Inventors: Pagnoul, Patricia, Cao, Hoai-Chau
• Primary Examiner(s): DOUYON, LORNA M
• Application Number:
  US08/851,938
• Time in Patent Office: 798 Days
• Field of Search: 510/405, 510/128, 510/223, 510/159, 510/229, 510/340, 510/351, 510/352, 510/356, 510/361, 510/424, 510/427, 510/428, 510/434, 510/495, 510/497
• US Class Current: 510/340
• CPC Class Codes: C11D 1/29 Sulfates of polyoxyalkylene ethers
• CPC Class Codes: C11D 1/721 End blocked ethers
• CPC Class Codes: C11D 1/83 Mixtures of non-ionic with anionic compounds
• CPC Class Codes: C11D 17/0026 Structured liquid compositions, e.g. liquid crystalline phases or network containing non-Newtonian phase
• CPC Class Codes: C11D 17/003 Colloidal solutions, e.g. gels; Thixotropic solutions or pastes

Abstract

Aqueous detergent concentrates containing a mixture of two or more surfactants having a differing resistance to electrolytic salting out in the form of micellar solutions and having pourable viscosities are converted into lamellar solutions upon dilution with water where the dispersion contains a viscosity promoting electrolyte present at a narrow range of concentration. Transformation from the micellar phase to the lamellar phase produces an increase in viscosity such that the diluted concentrate has a viscosity equal to or higher than the viscosity of the original concentrate.

Claims

1. An aqueous laundry detergent concentrate composition consisting of (i) a micellar dispersion of a mixture of at least two surfactants having differing resistance to electrolytic salting out such that at least one of said surfactants is resistant to salting out and at least one other of said surfactants is not resistant to salting out, said mixture consisting of at least one anionic surfactant which is an alkyl polyethoxy sulfate wherein the alkyl group ranges from 10 to 18 carbon atoms and the polyethoxy is of 2 to 11 ethylene oxide groups, and at least one nonionic surfactant which is an ethoxylated fatty alcohol wherein the fatty alcohol ranges from 6 to 18 carbon atoms and the ethoxylated fatty alcohol having 2 to 11 ethylene oxide groups, and (ii) a dissolved electrolyte salt which is an alkali metal citrate, said concentrate has a viscosity in the range of about 100 to 200 cps and said electrolyte salt is present in said concentrate at a level such that, upon dilution of said concentrate with an amount of water of from about 0.5 to about 5 volumes of water per volume of concentrate, said micellar surfactant dispersion is converted at least partially into a lamellar phase dispersion providing a diluted concentrate having a viscosity in excess of 400 cps.

2. The composition of claim 1 wherein said surfactants are present at a level of from about 10 to about 60% by weight.

3. The composition of claim 1 wherein said electrolyte salt is present at a level of from about 1 to about 30% by weight.

4. An aqueous detergent concentrate composition consisting of a micellar dispersion of surfactant consisting of C₁₀ to C₁₈ alkyl diethoxy sulfate and C₁₀ to C₁₈ alkyl triethoxy sulfate, and a dissolved electrolyte salt, said concentrate having a viscosity in the range of about 100 to 200 cps and said electrolyte salt is present in said concentrate at a level such that, upon dilution of said concentrate with an amount of water of from about 0.5 to about 5 volumes of water per volume of concentrate, said micellar surfactant dispersion is converted at least partially into a lamellar phase dispersion providing a diluted concentrate having a viscosity in excess of 200 cps.

5. A method for preparing a diluted laundry detergent concentrate having a viscosity at least equal to the viscosity of the undiluted concentrate consisting of:

(a) providing a detergent concentrate consisting of (i) an aqueous micellar dispersion of a mixture of at least two surfactants having differing resistance to electrolytic salting out such that at least one of said surfactants is resistant to salting out and at least one other of said surfactants is not resistant to salting out, said mixture consisting of at least one anionic surfactant which is an alkyl polyethoxy sulfate wherein the alkyl group ranges from 10 to 18 carbon atoms and the polyethoxy is of 2 to 11 ethylene oxide groups, and at least one nonionic surfactant which is an ethoxylated fatty alcohol wherein the fatty alcohol ranges from 6 to 18 carbon atoms and the ethoxylated fatty alcohol having 2 to 11 ethylene oxide groups, and (ii) a dissolved electrolyte salt which is an alkali metal citrate, said concentrate has a viscosity in the range of about 100 to 200 cps; and

(b) diluting said concentrate with sufficient water such that said concentrate is at least partially converted into a lamellar phase dispersion providing a diluted concentrate having a viscosity in excess of 400 cps.

6. The method of claim 5 wherein said concentrate is diluted with from about 0.5 to about 5 volumes of water per volume of concentrate.

7. The method of claim 5 wherein said surfactants are present at a level of from about 10 to about 60% by weight.

8. The method of claim 5 wherein said electrolyte salt is present at a level of from about 1 to about 30% by weight.