Permanent antistatic coating and coated polymeric film

• US 5,925,447 A
• Filed: 07/18/1996
• Issued: 07/20/1999
• Est. Priority Date: 07/18/1996
• Status: Expired due to Term

• Current Assignee: Mitsubishi Plastics Incorporated (Mitsubishi Chemical Holdings Corporation)
• Original Assignee: Mitsubishi Plastics Incorporated (Mitsubishi Chemical Holdings Corporation)
• Inventors: Caines, Ronald S., Gust, Stephen J.
• Primary Examiner(s): Chen, Vivian
• Application Number:
  US08/683,336
• Time in Patent Office: 1,097 Days
• Field of Search: 428/323, 428/331, 428/480, 428/483, 428/910, 428/219, 428/341, 428/412, 428/476.3, 428/515, 428/520, 428/522, 430/527, 430/528, 430/531, 430/532, 430/533, 430/534, 430/535, 430/536, 430/529, 427/322, 427/331, 427/371, 427/372.2, 427/385.5, 427/393.5, 264/289.3, 264/289.6, 264/290.2
• US Class Current: 428/219
• CPC Class Codes: C08J 2433/00 Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
• CPC Class Codes: C08J 7/0427 with only one layer of a composition containing a polymer binder with more layers C08J7/042
• CPC Class Codes: C08J 7/044 Forming conductive coatings; Forming coatings having anti-static properties
• CPC Class Codes: C08J 7/046 Forming abrasion-resistant coatings; Forming surface-hardening coatings
• CPC Class Codes: C08L 2666/44 Silicon-containing compounds
• CPC Class Codes: C08L 2666/54 Inorganic substances
• CPC Class Codes: C09D 133/26 Homopolymers or copolymers of acrylamide or methacrylamide
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/259 Silicic material
• CPC Class Codes: Y10T 428/273 of coating
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31909 Next to second addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31928 Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31935 Ester, halide or nitrile of addition polymer

Abstract

A thermoplastic film coated with a permanent antistatic composition to form an antistatic coating thereon, and a method for priming a thermoplastic film with the antistatic composition. The antistatic composition comprises: from 2 to 11% by weight of an antistatic copolymer; from 0 to 0.45% by weight of an antistatic compound; from 0.25 to 2% by weight glycidoxy silane; from about 0.3 to 2% by weight spherical silica particles having an average diameter of 10-100 nanometers; and water, or a mixture or water and organic solvent, wherein the total weight percent of all components equals 100%.

Claims

1. A permanent antistatic coating composition for polymeric films, said coating composition comprising:

a) from about 2 to 11% by weight of an antistatic copolymer, wherein said antistatic copolymer is a copolymer of;

1) from about 60% by weight to about 85% by weight of a quaternary salt of an alkylamino acrylamide or alkylamino acrylate;

2) from about 5% by weight to about 40% by weight of one or more acrylates; and

3) from 0 to about 10% by weight of a crosslinker;

wherein the total weight percent of components 1, 2, and 3 equals 100%;

b) from about 0 to 0.45% by weight of an antistatic compound;

c) from about 0.25 to 2% by weight glycidoxy silane;

d) from about 0.3 to 2% by weight spherical silica particles having an average diameter of about 10-100 nanometers; and

e) water, wherein the total weight percent of a-e equals 100%.

2. The coating composition of claim 1, wherein the quatemary salt a)1) is a quatemary salt of an alkylamino acrylate of the general formula ##STR4## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from the group consisting of halogens, sulfates, sulfonates, alkyl sulfates, alkyl sulfonates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

3. The coating composition of claim 2, wherein R₁ and R₂ are hydrogen;

R₃ is a methyl group;

y is 2; and

X is methyl sulfate.

4. The coating composition of claim 1, wherein the quatemary salt a)1) is a quatemary salt of an alkylamino acrylamide of the general formula ##STR5## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from halogens, sulfates, sulfonates, alkyl sulfonates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

5. The coating composition of claim 4, wherein R₁, R₂ and R₃ are hydrogen, y=3, and X is chloride.

6. The coating composition of claim 1, wherein said acrylates are selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, hexyl acrylate, 2-ethyl-hexyl acrylate, octyl acrylate, and mixtures of these.

7. The coating composition of claim 1, wherein said crosslinker is selected from the group consisting of N-methylolacrylamide;

N-methylol methacrylamide;

melamine or urea formaldehyde crosslinked with one or more of itaconic acid, itaconic anhydride, acrylic add, allyl alcohol, maleic acid and maleic anhydride;

acrylamide and methacrylamide crosslinked with melamine formaldehyde or urea formaldehyde;

aziridines;

glycoluril formaldehyde;

benzoguanamines;

acrylamido glycolic acid;

bis-acrylamide glycol;

glyoxal;

formaldehyde; and

diacrylamide acetic acid.

8. A polymeric film having permanent antistatic properties, said film comprising:

A) an oriented polymeric film; and

B) an effective amount of a coating on at least one side of said film, sufficient to provide antistatic properties to said film, said coating, on a dry weight basis, comprising;

a) from about 31 to 96% by weight of an antistatic copolymer, wherein said antistatic copolymer is a copolymer of;

1) from about 60% by weight to about 85% by weight of a quaternary salt of an alkylamino acrylamide or alkylamino acrylate;

2) from about 5% by weight to about 40% by weight of one or more acrylates; and

3) from 0 to about 10% by weight of a crosslinker;

wherein the total weight percent of components 1, 2, and 3 equals 100%;

b) from about 0 to 15% by weight of an antistatic compound;

c) from about 1 to 47% by weight glycidoxy silane; and

d) from about 2 to 48% by weight spherical silica particles having an average diameter about 10-100 nanometers in diameter, wherein the total weight percent of a-d equals 100%.

9. The polymeric film of claim 8, wherein the quatemary salt a)1) is a salt of an alkylamino acrylate of the general formula ##STR6## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from halogens, sulfates, sulfonates, alkyl sulfates, alkyl sulfonates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

10. The polymeric film of claim 9, wherein R₁ and R₂ are hydrogen;

R₃ is a methyl group;

y is 2; and

X is methyl sulfate.

11. A polymeric film according to claim 10 wherein at least one of the one ore more acrylates in the antistatic copolymer is ethyl acrylate and/or methyl methacrylate.

12. A polymeric film according to claim 11, wherein the antistatic copolymer is a copolymer of the quaternary salt, the ethyl acrylate and/or methyl methacrylate and, as crosslinker, N-methylolacrylamide.

13. A polymeric film according to claim 12 wherein the glycidoxy silane is glycidoxypropyltrimethoxysilane or glycidoxypropylmethyidiethoxysilane.

14. A polymeric film according to claim 13 which comprises, as an antistatic compound, stearamidopropyidimethyl-β

-hydroxyethylammonium nitrate.

15. A polymeric film according to claim 14 wherein the spherical silica particles have positively charged surfaces.

16. The polymeric film of claim 8, wherein the quatemary salt a)1) is a salt of an alkylamino acrylamide of the general formula ##STR7## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from halogens, sulfates, sulfonates, alkyl sulfonates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

17. The polymeric film of claim 16, wherein R₁, R₂ and R₃ are hydrogen, y=3, and X is chloride.

18. The polymeric film of claim 8, wherein said acrylates selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, methyl methacrylate, ethyl methacrylate, propyl methacrylate, hexyl acrylate, 2-ethyl, hexyl acrylate, octyl acrylate, and mixtures of these.

19. The polymeric film claim 8, wherein said crosslinker is selected from the group consisting of N-methylolacrylamide;

N-methylol methacrylamide;

melamine or urea formaldehyde crosslinked with one or more of itaconic acid, itaconic anhydride, acrylic acid, allyl alcohol, maleic acid and maleic anhydride;

acrylamide and methacrylamide crosslinked with melamine formaldehyde or urea formaldehyde;

aziridines;

glycoluril formaldehyde;

benzoguanamines;

acrylamido glycolic acid;

bis-acrylamide glycol;

glyoxal;

formaldehyde; and

diacrylamide acetic acid.

20. The polymeric film of claim 8, wherein said oriented polymeric film is selected from group consisting of polyester, polyolefin, polyamide, polyacetal, and polycarbonate.

21. The polymeric film of claim 20, wherein said film is biaxially oriented.

22. The polymeric film of claim 8, wherein said coating is on both sides of said polymeric film.

23. The polymeric film of claim 8, wherein said coating on said film is from 0.00305-0.400 g/m².

24. The polymeric film of claim 8, wherein said film has a surface resistivity of less than 1×

10¹² ohms/square, and a static decay time of less than 2 seconds.

25. The polymeric film of claim 8, wherein the antistatic copolymer is a copolymer of a quatermary salt of an alkylamino acrylamide or alkyl amino acrylate, one or mor acrylates and a crosslinker.

26. A polymeric film according to claim 25 wherein the spherical silica particles have positively charged surfaces.

27. A polymeric film according to claim 26 wherein the coating comprises, as an antistatic compound, a long chain quatemary ammonium compound.

28. A polymeric film according to claim 8 wherein the glyddoxy silane is a compound of the formula ##STR8## wherein X is a glycidoxy group,

Y is an alkylene group,

R₁ and R₂ are hydrolyzable groups and

R₃ is a hydrolyzable group or a non-hydrolyzable group.

29. A polymeric film according to claim 28 wherein Y is methylene, ethylene or propylene, the hydrolyzable groups as R₁, R₂ and R₃ are methoxy, ethoxy or acetoxy and the non-hydrolyzable group as R₃ is methyl, ethyl, phenyl or naphthyl.

30. A polymeric film according to claim 29 wherein the oriented polymeric film is polyethylene terephthalate, polybutylene terephthalate or polyethylene terephthalate isophthalate.

31. A polymeric film according to claim 29 wherein the coating comprises, as an antistatic compound, a long chain quatemary ammonium compound.

32. A polymeric film according to claim 28 wherein the oriented polymeric film is polyester.

33. A polymeric film according to claim 28 wherein the spherical silica particles have positively charged surfaces.

34. A method for priming a polymeric film to provide permanent antistatic properties, comprising:

A) coating a polymeric film with an effective amount of a permanent antistatic composition; and

B) drying said coating on said film, wherein said coating comprises;

a) from about 2 to 11% by weight of an antistatic copolymer, wherein said antistatic copolymer is a copolymer of;

1) from about 60% by weight to about 85% by weight of a quaternary salt of an alkylamino acrylamide or alkylamino acrylate;

2) from about 5% by weight to about 40% by weight of one or more acrylates; and

3) from 0 to about 10% by weight of a crosslinker;

wherein the total weight percent of components 1, 2, and 3 equals 100%;

b) from about 0 to 0.45% by weight of an antistatic compound;

c) from about 0.25 to 2% by weight glycidoxy silane;

d) from about 0.3 to 2% by weight spherical silica particles having an average diameter of about 10-100 nanometers; and

e) water, wherein the total weight percent of a-e equals 100%.

35. The method of claim 34, wherein the quatemary salt a)1) is a quatemary salt of an alkylamino acrylate of the general formula ##STR9## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from halogens, sulfates, sulfanates, alkyl sulfates, alkyl sulfanates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

36. The method of claim 35, wherein R₁ and R₂ are hydrogen;

R₃ is a methyl group;

y is 2; and

X is methyl sulfate.

37. The method of claim 34, wherein the quatemary salt a)1) is a quaternary salt of an alkylamino acrylamide of the general formula ##STR10## wherein R₁, R₂ and R₃ are the same or different and are hydrogen or an alkyl group containing 1-8 carbon atoms;

y=1 to 8; and

X is an anion selected from halogens, sulfates, sulfonates, alkyl sulfonates, carbonates, alkyl carbonates, nitrates, phosphates, alkyl phosphates, and mixtures of these.

38. The method of claim 37, wherein R₁, R₂ and R₃ are hydrogen, y=3, and X is chloride.

39. The method of claim 34, wherein said one or more acrylates selected from the group consisting of methyl acrylate, ethyl acrylate, propyl acrylate, butyl acrylate, hexyl acrylate, 2-ethyl, hexyl acrylate, octyl acrylate, methyl methacrylate, ethyl methacrylate and propyl methacrylate.

40. The method of claim 34, wherein said crosslinker is selected from the group consisting of N-methylolacrylamide;

N-methylol methacrylamide;

melamine or urea formaldehyde crosslinked with one or more of itaconic acid, itaconic anhydride, acrylic acid, allyl alcohol, maleic acid and maleic anhydride;

acrylamide and methacrylamide crosslinked with melamine formaldehyde or urea formaldehyde;

aziridines;

glycoluril formaldehyde;

benzoguanamines;

acrylamido glycolic acid;

bis-acrylamide glycol;

glyoxal;

formaldehyde; and

diacrylamide acetic acid.

41. The method of claim 34, wherein said polymeric film is corona treated before said coating step.

42. The method of claim 34, wherein said coating is effected in-line during the manufacturing of said polymeric film.

43. The method of claim 42, wherein said in-line coating occurs intradraw during the film manufacturing process.

44. The method of claim 42, wherein said coating is applied to said film, on a dry weight basis, in a range of from 0.00305 to 0.400 g/m².

45. The method of claim 34, wherein said polymeric film is selected from the group consisting of polyester, polyolefin, polyamide, polyacetal, and polycarbonate.

46. The method of claim 45, wherein said polymeric film is biaxially oriented.