Electrolytic exhaust sensor with diffusion layer inhibiting formation of a liquid phase

• US 5,925,814 A
• Filed: 02/06/1998
• Issued: 07/20/1999
• Est. Priority Date: 02/06/1997
• Status: Expired due to Term

• Current Assignee: NGK Spark PLUG Company Limited (Niterra Co., Ltd.)
• Original Assignee: NGK Spark PLUG Company Limited (Niterra Co., Ltd.)
• Inventors: Tsuzuki, Masashi, Kawai, Takeshi
• Primary Examiner(s): BROCK, MICHAEL J
• Application Number:
  US09/019,605
• Time in Patent Office: 529 Days
• Field of Search: 73/31.05, 73/31.06, 73/23.31, 73/23.32, 204/424, 204/425, 204/426, 204/427, 204/428, 204/429
• US Class Current: 73/23.32
• CPC Class Codes: G01N 27/417 using cells , i.e. more than one cell and probes with solid electrolytes

Abstract

A gas sensor has a sensor cell unit which includes a detection member made up of an oxygen concentration cell, oxygen pump cell and a spacer interposed between the oxygen concentration cell and the oxygen pump cell to define therebetween a measurement gas chamber. The spacer has a pair of communicating holes for providing communication between the measurement gas chamber and the outside. Diffusion control layers made of porous material are formed within the communicating holes of the spacer so as to control flow of the detection gas into the measurement gas chamber, etc. The diffusion control layer is made of alumina and has on the outer surface thereof (i.e., on the inner peripheral surfaces thereof defining gas permeating pores) a thin Ca coating which inhibits formation of a substance which is in a liquid phase at a temperature range in which the gas sensor is used, due to reaction of the alumina forming the diffusion control layer with a suspended component of the detection gas such as phosphorus (P) in an engine exhaust gas.

Claims

1. A gas sensor including a detection portion and a porous member having gas permeating pores through which detection gas is introduced into said detection portion, wherein said porous member includes a material inhibiting formation of a substance which is in a liquid phase at a temperature range in which the gas sensor is used, due to reaction of said porous member with a suspended component of the detection gas.

2. A gas sensor according to claim 1, wherein said suspended component is phosphorus (P).

3. A gas sensor according to claim 1, wherein said porous member comprises a diffusion control layer.

4. A gas sensor according to claim 3, wherein said diffusion control layer has a larger diffusion resistance at an inner part thereof and a smaller resistance at an outer part thereof.

5. A gas sensor according to claim 1, wherein said porous member comprises a porous, protective layer covering a measurement electrode of the gas sensor.

6. A gas sensor according to claim 1, wherein said temperature range is equal to or larger than 500°

C.

7. A gas sensor according to claim 1, wherein at least part of said porous member is made of calcium phosphate whose Ca/P ratio is 1.0 or more.

8. A gas sensor according to claim 1, wherein said porous member comprises a plurality of porous layers including an outermost layer which is made of calcium phosphate whose Ca/P ratio is 1.0 or more.

9. A gas sensor according to claim 1, wherein said material of said porous member is Mg or Ca and in the form of a coating applied to an outer surface of said porous member.

10. A gas sensor according to claim 1, wherein said porous member is coated with Mg or Ca.