Process for controlling cone tilt angle in mixtures of smectic liquid crystal compounds
First Claim
1. Fluorine-containing liquid crystal compounds represented by the general formula I:
- ##STR98## where M, N, and P are each independently selected from the group consisting of ##STR99## a, b, and c are each independently zero or an integer of from 1 to 3, with the proviso that the sum of a+b +c be at least 1;
each A and B are non-directionally and independently selected from the group consisting of a covalent bond,
space="preserve" listing-type="equation">--C(═
O)--O--, --C(═
O)--S--, --C(═
O)--Se--,--C(═
O)--Te--, --(CH2 CH2)k -- where k is 1 to 4, --CH═
CH--, --C.tbd.C--, --CH═
N--, --CH2 --O--, --C(═
O)--, and --O--;
each X, Y, and Z are independently selected from the group consisting of --H, --Cl, --F, --Br, --I, --OH, --OCH3, --CH3, --CF3, --OCF3, --CN, and --NO2 ;
each l, m, and n are independently zero or an integer of 1 to 4;
D is non-directionally selected from the group consisting of a covalent bond, --C(═
O)--O--Cr H2r --, --O--Cr H2r --, --O--(O═
)C--Cr H2r --, --C.tbd.C--, --CH═
CH--, --C(═
O)--, --O.paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, --Cr H2r --, .paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, --O--, --S--, --OSO2 --, --SO2 --, --SO2 --Cr H2r --, ##STR100## --N(Cp H2p+1)--, ##STR101## --CH═
N--, and combinations thereof, where r and r'"'"' are independently integers of 0 to about 20, s is independently an integer of 1 to about 10 for each (Cs H2s O), t is an integer of 1 to about 6, and p is an integer of 0 to about 4;
R is selected from the group consisting of --O--((Cq'"'"' H2q'"'"'-v'"'"' --(R'"'"')v'"'"')--O)w --Cq H2q+1-v --(R'"'"')v, --((Cq'"'"' H2q'"'"'-v'"'"' --(R'"'"')v'"'"')--O)w --Cq H2q+1-v --(R'"'"')v, --C(═
O)--O--Cq H2q+1-v --(R'"'"')v, --O--(O═
)C--Cq H2q+1-v --(R'"'"')v, ##STR102## --CR'"'"'H--(D)g --CR'"'"'H--Cq H2q+1-v --(R'"'"')v, where each R'"'"' is independently selected from the group consisting of --Cl, --F, --CF3, --NO2, --CN, --H, --Cq H2q+1, --O--(O═
)C--Cq H2q+1, --C(═
O)--O--Cq H2q+1, --Br, --OH, and --OCq H2q+1 ;
q'"'"' is independently an integer of 1 to about 20 for each (Cq'"'"' H2q'"'"' --O);
q is an integer of 1 to about 20;
w is an integer of 0 to about 10;
v is an integer of 0 to about 6;
each v'"'"' is independently an integer of 0 to about 6;
g is an integer of 1 to about 3;
each D is independently and non-directionally selected from the group set forth for D above, with the proviso that the ring containing D has from about 3 to about 10 ring atoms;
each W is independently selected from the group consisting of N, CR'"'"', and SiR'"'"';
Rh is represented by the directional general formula .paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, wherein s is independently an integer of 2 to about 10 for each (Cs H2s O), t is an integer of 1 to about 6, and r'"'"' is an integer of 1 to about 10; and
Rf is fluoroether;
with the proviso that the compounds exhibit at least one tilted smectic mesophase.
1 Assignment
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Accused Products
Abstract
A process for controlling the cone tilt angle of a tilted smectic liquid crystal composition comprises the step of combining (a) at least one liquid crystal composition comprising at least one smectic or latent smectic liquid crystal compound comprising (i) an aliphatic fluorocarbon terminal portion comprising a terminal fluoroalkyl or fluoroether group and an alkylene group having at least two carbon atoms and containing at least one catenary ether oxygen atom, (ii) an aliphatic hydrocarbon terminal portion, and (iii) a central core connecting the terminal portions; and (b) at least one liquid crystal composition comprising at least one smectic or latent smectic liquid crystal compound; with the provisos that at least one of the compositions (a) and (b) comprises at least one chiral liquid crystal compound and that the combining of compositions (a) and (b) provides an optically active, tilted chiral smectic liquid crystal composition. The process enables control of cone tilt angle and thereby control of the brightness characteristics of liquid crystal display devices.
55 Citations
11 Claims
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1. Fluorine-containing liquid crystal compounds represented by the general formula I:
- ##STR98## where M, N, and P are each independently selected from the group consisting of ##STR99## a, b, and c are each independently zero or an integer of from 1 to 3, with the proviso that the sum of a+b +c be at least 1;
each A and B are non-directionally and independently selected from the group consisting of a covalent bond,
space="preserve" listing-type="equation">--C(═
O)--O--, --C(═
O)--S--, --C(═
O)--Se--,--C(═
O)--Te--, --(CH2 CH2)k -- where k is 1 to 4, --CH═
CH--, --C.tbd.C--, --CH═
N--, --CH2 --O--, --C(═
O)--, and --O--;each X, Y, and Z are independently selected from the group consisting of --H, --Cl, --F, --Br, --I, --OH, --OCH3, --CH3, --CF3, --OCF3, --CN, and --NO2 ; each l, m, and n are independently zero or an integer of 1 to 4; D is non-directionally selected from the group consisting of a covalent bond, --C(═
O)--O--Cr H2r --, --O--Cr H2r --, --O--(O═
)C--Cr H2r --, --C.tbd.C--, --CH═
CH--, --C(═
O)--, --O.paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, --Cr H2r --, .paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, --O--, --S--, --OSO2 --, --SO2 --, --SO2 --Cr H2r --, ##STR100## --N(Cp H2p+1)--, ##STR101## --CH═
N--, and combinations thereof, where r and r'"'"' are independently integers of 0 to about 20, s is independently an integer of 1 to about 10 for each (Cs H2s O), t is an integer of 1 to about 6, and p is an integer of 0 to about 4;R is selected from the group consisting of --O--((Cq'"'"' H2q'"'"'-v'"'"' --(R'"'"')v'"'"')--O)w --Cq H2q+1-v --(R'"'"')v, --((Cq'"'"' H2q'"'"'-v'"'"' --(R'"'"')v'"'"')--O)w --Cq H2q+1-v --(R'"'"')v, --C(═
O)--O--Cq H2q+1-v --(R'"'"')v, --O--(O═
)C--Cq H2q+1-v --(R'"'"')v, ##STR102## --CR'"'"'H--(D)g --CR'"'"'H--Cq H2q+1-v --(R'"'"')v, where each R'"'"' is independently selected from the group consisting of --Cl, --F, --CF3, --NO2, --CN, --H, --Cq H2q+1, --O--(O═
)C--Cq H2q+1, --C(═
O)--O--Cq H2q+1, --Br, --OH, and --OCq H2q+1 ;
q'"'"' is independently an integer of 1 to about 20 for each (Cq'"'"' H2q'"'"' --O);
q is an integer of 1 to about 20;
w is an integer of 0 to about 10;
v is an integer of 0 to about 6;
each v'"'"' is independently an integer of 0 to about 6;
g is an integer of 1 to about 3;
each D is independently and non-directionally selected from the group set forth for D above, with the proviso that the ring containing D has from about 3 to about 10 ring atoms;
each W is independently selected from the group consisting of N, CR'"'"', and SiR'"'"';Rh is represented by the directional general formula .paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, wherein s is independently an integer of 2 to about 10 for each (Cs H2s O), t is an integer of 1 to about 6, and r'"'"' is an integer of 1 to about 10; and
Rf is fluoroether;
with the proviso that the compounds exhibit at least one tilted smectic mesophase. - View Dependent Claims (2, 3, 4, 5, 6, 8, 9)
- ##STR98## where M, N, and P are each independently selected from the group consisting of ##STR99## a, b, and c are each independently zero or an integer of from 1 to 3, with the proviso that the sum of a+b +c be at least 1;
-
7. Fluorine-containing liquid crystal compounds represented by the general formula I:
- ##STR103## where M is pyrimidine;
N is phenyl;
A is a covalent bond;
X and Y hydrogen;
a and b are integers of 1;
l is an integer of 2;
m is an integer of 4;
D is --O--;
R is an alkyl, fluoroalkyl, alkoxy, or fluoroalkoxy group having from about 4 to about 8 carbon atoms and optionally containing one or more catenary ether oxygen atoms;
Rh has from about 4 to about 8 carbon atoms and is represented by the directional general formula .paren open-st.Cs H2s O.paren close-st.t Cr'"'"' H2r'"'"' --, wherein s is independently an integer of 3 to about 7 for each (Cs H2s O), t is an integer of 1 to 2, and r'"'"' is an integer of 1; and
Rf is a perfluoroether group represented by the formula --(Cx F2x O)z Cy F2y+1, where x is independently an integer of 1 to about 10 for each (Cx F2x O), y is an integer of 1 to about 10, and z is an integer of 1 to about 10;
with the proviso that the compounds exhibit at least one tilted smectic mesophase. - View Dependent Claims (10, 11)
- ##STR103## where M is pyrimidine;
Specification