Processing for producing shaped wholly aromatic polyamide resin composition article and shaped article produced thereby

• US 5,928,589 A
• Filed: 10/30/1991
• Issued: 07/27/1999
• Est. Priority Date: 12/28/1987
• Status: Expired due to Fees

• Current Assignee: Teijin Limited
• Original Assignee: Teijin Limited
• Inventors: Kobayashi, Akira, Kuwabara, Mitsuo, Komoriya, Tadao, Norota, Susumu, Adachi, Hiroyuki
• Primary Examiner(s): Schwartz, Pamela R.
• Assistant Examiner(s): GRAY, JILL M
• Application Number:
  US07/784,687
• Time in Patent Office: 2,827 Days
• Field of Search: 264/120, 264/122, 264/127, 264/175, 264/115
• US Class Current: 264/115
• CPC Class Codes: B29B 2009/163 Coating, i.e. applying a layer of liquid or solid material on the granule
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules
• CPC Class Codes: B29C 43/003 characterised by the choice of material
• CPC Class Codes: B29C 43/006 Pressing and sintering powders, granules or fibres
• CPC Class Codes: B29K 2077/10 Aromatic polyamides [polyaramides] or derivatives thereof
• CPC Class Codes: B29K 2227/18 PTFE, i.e. polytetrafluorethene , e.g. ePTFE, i.e. expanded polytetrafluorethene
• CPC Class Codes: C08L 27/12 containing fluorine atoms
• CPC Class Codes: C08L 77/10 Polyamides derived from aromatically bound amino and carboxyl groups of amino-carboxylic acids or of polyamines and polycarboxylic acids

Abstract

A shaped wholly aromatic polyamide resin composition article having an excellent mechanical strength, stain-proof property and antistatic property, and comprising a wholly aromatic polyamide resin matrix and a dispersoid comprising polytetrafluoroethylene resin particles in the form of fine networks of fibrils and, optionally, additional inorganic particles, dispersed in the matrix, is produced by mixing an aqueous dispersion of PTFE particles having an average size of 0.3 to 3 μm in an amount of 0.01% to 10% based on the total weight of the shaped article, with wholly aromatic polyamide particles having a melting point of at least 50° C. higher than that of PTFE and composed of porous secondary particles having an average size of 30 to 200 μm and consisting of primary particles having an average size of 0.1 to 2.0 μm; drying the mixture to provide composite particles composed of aromatic polyamide cores and PTFE coating layers on the cores; and shaping a feed powder comprising the composite particles at a temperature not lower than the glass-transition point but not lower than the melting point or heat decomposition point of the aromatic polyamide, under a pressure.

Claims

1. A process for producing a shaped wholly aromatic polyamide resin composite article, comprising the steps of:

(a) mixing an aqueous dispersion of polytetrafluoroethylene resin particles in an amount of 0.1% to 10% by weight based on the total weight of the shaped article, the polytetrafluoroethylene resin particles having an average size of from 0.3 to 3 μ

m, with wholly aromatic polyamide polymer particles comprising at least one type of aromatic polyamide polymer having at least 85 molar % of recurring m-phenyleneisophthalamide units of the formula;

##STR2## the aromatic polyamide polymer having a melting temperature at least 50°

C. higher than the melting temperature of the polytetrafluoroethylene resin particles, and composed of a plurality of primary polyamide particles having an average size of from 0.1 to 2.0 μ

m aggregated with each other to form secondary porous polyamide particles having an average size of from 30 to 200 μ

m, to form an aqueous mixture;

(b) drying the aqueous mixture to provide a dried product comprising coated composite particles which are composed of cores consisting of the wholly aromatic polyamide polymer particles and coating layers formed on the cores consisting of the polytetrafluoroethylene resin particles;

(c) preparing a shaping feed powder of a member selected from the group consisting of the product of the drying step (b) and mixtures of the product of the drying step (b) with an additional amount of the wholly aromatic polyamide polymer particles; and

(d) subjecting the shaping feed powder to a shaping procedure in which the shaping feed powder is preheated to a temperature lower than the glass transition temperature of the aromatic polyamide polymer, under compression, and then heat-compressed at a temperature of 30°

C. to 70°

C. above the glass transition temperature and 20°

C. to 80°

C. below the melting or decomposition temperature of the aromatic polyamide polymer;

the heat-compressed feed is shaped at the temperature above the glass transition temperature and below the melting or decomposition temperature of the polyamide polymer; and

the shaped article is cooled, to provide a shaped article wherein the polytetrafluoroethylene resin particles are in the form of fibrils dispersed in a matrix consisting of the wholly aromatic polyamide polymer and connected to each other to form fine networks of the fibrils in the matrix.

2. The process as claimed in claim 1, wherein the polytetrafluoroethylene resin particles in the aqueous dispersion are in a colloidal state.

3. The process as claimed in claim 1, wherein the aqueous mixture comprises a weight ration of the aqueous dispersion of the polytetrafluoroethylene resin particles to the aromatic polyamide polymer particles of 1:

4 to 2;

1.

4. The process as claimed in claim 1, wherein the shaping procedure is carried out by extruding the heat-compressed feed through a shaping die.

5. The process as claimed in claim 1, wherein in the mixing step, the aqueous dispersion of the polytetrafluoroethylene resin particles is mixed with the aromatic polyamide polymer particles and abrasive inorganic particles.

6. The process as claimed in claim 5, wherein in the mixing step (a), the sum of the aromatic polyamide polymer particles and the abrasive inorganic particles has a weight ratio to the aqueous dispersion of the polytetrafluoroethylene resin particles of from 1:

4 to 2;

1.

7. The process as claimed in claim 5, wherein in the mixing step, the abrasive inorganic particles are used in an amount of from 1% to 50% by weight based on the total weight of the shaped article.

8. The process as claimed in claim 5, wherein the resultant aqueous mixture of the mixing step containing the abrasive inorganic particles is dried and converted to a mixture of coated composite particles consisting essentially of cores consisting of the aromatic polyamide polymer particles and coating layers consisting of the polytetrafluoroethylene resin particles formed on the cores and additional coated composite particles consisting essentially of cores consisting of the additional inorganic particles and coating layers consisting of the polytetrafluoroethylene resin particles.

9. The process as claimed in claim 4, wherein the shaping feed powder further contains coated particles of cores consisting of the abrasive inorganic particles and coating layers formed on the cores, the coating layers consisting of the polytetrafluoroethylene resin particles.

10. The process as claimed in claim 5, wherein in the heat-compressing procedure, the preheated shaping feed powder is intermittently introduced into a heat-compressing zone by a reciprocating plunger and intermittently heat-compressed in the heat-compressing zone, the resultant heat-compressed feed is introduced into a shaping mold to form the feed into a predetermined shape and the resultant shaped article is extruded through the cooling die.

11. The process as claimed in claim 10, wherein the plunger is reciprocated at a rate of 0.5 to 300 cycles/min.

12. The process as claimed in claim 10, wherein the shaping feed powder is compressed at a compression ratio of 1:

1 to 100 in the heat-compressing zone.

13. The process as claimed in claim 10, wherein the intermittent compressing procedure, the feed powder is heated at a temperature between the glass transition temperature and 80°

C. above the glass transition temperature of the aromatic polyamide polymer.

14. The process as claimed in claim 10, wherein in cool-extruding procedure, the cooling die has a temperature lower than the glass transition temperature of the aromatic polyamide polymer.