Direct metal fabrication (DMF) using a carbon precursor to bind the "green form" part and catalyze a eutectic reducing element in a supersolidus liquid phase sintering (SLPS) process

• US 5,932,055 A
• Filed: 11/11/1997
• Issued: 08/03/1999
• Est. Priority Date: 11/11/1997
• Status: Expired due to Term

• Current Assignee: Teledyne Scientific & Imaging, LLC (Teledyne Technologies Incorporated)
• Original Assignee: Rockwell Science Center LLC
• Inventors: Newell, Kenneth J., Goldberg, Ira B.
• Primary Examiner(s): MAYES, MELVIN C
• Application Number:
  US08/967,463
• Time in Patent Office: 630 Days
• Field of Search: 156/155, 156/264, 156/272.8, 156/308.2, 156/242, 156/62.2, 156/62.6, 156/245, 156/246, 419/14, 419/15, 419/17, 419/25, 419/36, 419/37, 419/38, 419/44, 419/47, 419/54
• US Class Current: 156/245
• CPC Class Codes: B22F 1/09 Mixtures of metallic powders
• CPC Class Codes: B22F 10/10 Formation of a green body
• CPC Class Codes: B22F 10/28 Powder bed fusion, e.g. selective laser melting [SLM] or electron beam melting [EBM]
• CPC Class Codes: B22F 2998/00 Supplementary information concerning processes or compositions relating to powder metallurgy
• CPC Class Codes: B22F 3/1017 Multiple heating or additional steps B22F3/101 takes precedence
• CPC Class Codes: B22F 3/1021 Removal of binder or filler removal of binder from ceramics C04B35/638
• CPC Class Codes: B22F 3/1035 Liquid phase sintering
• CPC Class Codes: B33Y 80/00 Products made by additive manufacturing
• CPC Class Codes: Y02P 10/25 Process efficiency
• CPC Class Codes: Y10T 156/1075 of plural laminae from single stock and assembling to each other or to additional lamina

Abstract

Direct Metal Fabrication of metal parts is accomplished with a continuous thermal process in which partial reduction of the "green form" part leaves a thin carbon film that maintains the part'"'"'s structural integrity. The remaining carbon catalyzes a eutectic reducing element to diffuse throughout the part forming organo-metallic bonds that bind the homogenized metal alloy. Supersolidus liquid phase sintering (SLPS) densities the alloy to provide a final part of parent material quality. The DMF process can be used in magnetographic printing to imprint an image.

Claims

1. A method of direct metal fabrication (DMF) of metal parts, comprising:

using a carbon precursor to wet a metal powder alloy (X) whose particles are mixed with a eutectic reducing element (A) and bind the particles into a green form part with a specified shape, said particles each having a plurality of grains that are bound together along grain boundaries;

partially reducing the carbon precursor such that a thin carbon (C) film remains whose C═

C bonds maintain the part'"'"'s specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile;

diffusing the eutectic reducing element along the particles'"'"' grain boundaries such that the reducing element interacts with the carbon film at the interface between the particles to form organo-metallic bonds C═

A that are much stronger than the film'"'"'s C═

C bonds; and

initiating supersolidus liquid phase sintering (SLPS) to form a liquid film along the particles'"'"' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═

A bonds maintain the specified shape.

2. The method of claim 1, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form the organo-metallic bonds, and c) assist SLPS, and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

3. The method of claim 2, wherein the eutectic reducing element is small enough to become diffusely mobile along the grain boundaries and is highly reactive with carbon.

4. The method of claim 3, wherein the eutectic reducing element is boron.

5. The method of claim 2, wherein the eutectic reducing element is introduced in a metal powder alloy Y that comprises:

(a) the same elemental components which comprise the metal powder alloy X, and (b) the eutectic reducing element in a concentration greater than any concentration of the eutectic element present in the metal powder alloy X.

6. The method of claim 5, wherein the mixture is comprised of 75-85% by volume of alloy X, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the carbon precursor.

7. The method of claim 2, wherein the carbon precursor is melted layer-by-layer using selective laser sintering to form the green form part.

8. The method of claim 2, wherein the powder mixture is imprinted onto a substrate carrier using a magnetographic printing process and laminated to form the green form part.

9. The method of claim 2, wherein the powder is mixed in a pre-cast mold to form the green form part.

10. The method of claim 1, wherein the green form part is placed in a furnace and subjected to a thermal cycle that partially reduces the carbon precursor, diffuses the eutectic reducing element, and initiates SLPS.

11. The method of claim 10, wherein in the thermal cycle the temperature of the furnace is

a) raised from its ambient value to a first temperature range in which the precursor is partially reduced and the carbon film is deposited on the surface of the part;

b) raised to a second temperature range to initiate grain boundary diffusion of the eutectic reducing element until the reducing element reaches its equilibrium state;

c) raised to a third temperature range to initiate SLPS; and

d) cooled to its ambient temperature to complete densification to the final part.

12. The method of claim 11, wherein the first, second, and third temperature ranges are approximately (200-500°

C.), (500-1200°

C.), and (1200-1300°

C.), respectively.

13. The method of claim 11, wherein the green form part is reduced in an environment that is incapable of eliminating all of the carbon from the carbon precursor.

14. The method of claim 2, wherein the concentrations of carbon and the eutectic reducing element in the final part are small enough that the final part exhibits the material quality of the parent metal powder alloy X.

15. A method of direct metal fabrication (DMF) of metal parts, comprising:

providing a mixture of a polymer (P) having a concentration of carbon (C) and metal powder alloys (X) and (Y) having substantially the same elemental compositions except that alloy Y includes a eutectic reducing element A at a concentration higher than any concentration of said eutectic reducing element A present in alloy X, said X and Y alloys'"'"' particles each having a plurality of grains that are bounded together along grain boundaries;

using the polymer to wet and bind the X and Y alloy particles into a green form part with a specified shape; and

in a single thermal cycle,

heating the green form part to partially reduce the polymer so that a thin carbon film remains whose C═

C bonds maintain the part'"'"'s specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile;

increasing the temperature to accelerate the diffusion of the eutectic reducing element along the grain boundaries of the alloy Y particles, through the carbon film, and along the grain boundaries of the adjacent alloy X particles until equilibrium of element A in the mixture is achieved so that the mixture is a fully homogenized metal powder alloy Z that is held together by the organo-metallic bonds C═

A formed when said element A interacts with the carbon film;

increasing the temperature above a solidus temperature for alloy Z to initiate supersolidus liquid phase sintering (SLPS) where a liquid film forms along the particles'"'"' grain boundaries so that the grains slide relative to each other and densify in response to surface tension and capillary pressure to form a final part whose organo-metallic C═

A bonds maintain the specified shape, said carbon and eutectic reducing elements constituting such a small portion of said final part that it exhibits the properties of the parent alloy X; and

cooling the final part to complete densification.

16. The method of claim 15, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloys X and Y, b) react with the carbon at the interface between alloy particles to form a sufficient number of organo-metallic bonds, and c) assist SLPS, and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

17. The method of claim 16, wherein the mixture is comprised of 75-85% by volume of alloy X, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

18. The method of claim 15, wherein the polymer is melted layer-by-layer using selective laser sintering to form the green form part.

19. The method of claim 15, wherein the powder mixture is imprinted onto a carrier using a magnetographic printing process and laminated to form the green form part.

20. The method of claim 15, wherein the powder is mixed in a pre-cast mold to form the green form part.

21. A method of direct metal fabrication (DMF) of metal parts, comprising:

a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture;

b) spreading a layer of said mixture on a platform;

c) directing a beam of energy onto selected areas of said layer to cause localized melting of said polymer, said polymer resolidifying to bind said metal powders in said selected areas;

d) repeating steps b and c to build up a green form part; and

e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═

C bonds maintain the part'"'"'s specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═

A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═

A bonds maintain the specified shape, and i)cools the final part to complete densification.

22. The method of claim 21, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form the organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

23. The method of claim 22, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) that comprises:

(a) the same elemental components which comprise the parent metal powder, and

(b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in the parent metal powder.

24. The method of claim 23, wherein the mixture is comprised of 75-85% by volume of the parent metal, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

25. A method of direct metal fabrication of metal parts, comprising:

a) mixing powders of a parent metal, a eutectic reducing element A, and a polymer to form a mixture;

b) feeding the mixture to a magnetographic printer that sequentially prints latent images formed from said mixture onto respective sheets of a thermally activated substrate carrier as it moves through the printer;

c) cutting the next sheet off said substrate carrier;

d) registering and laminating each successive sheet on top of the previous sheet to buildup a green form part layer-by-layer; and

e) placing said green form part in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer leaving a thin carbon film whose C═

C bonds maintain the part'"'"'s specified shape and act as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent parent metal particles to form organo-metallic bonds C═

A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═

A bonds maintain the specified shape, and i)cools the final part to complete densification.

26. The method of claim 25, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form a sufficient number of organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

27. The method of claim 26, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) that comprises:

(a) the same elemental components which comprise the parent metal powder, and

(b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in the parent metal powder.

28. The method of claim 27, wherein the mixture is comprised of 75-85% by volume of the parent metal, 5-15% by volume of alloy Y with 0.15-0.5% by weight of element A with the remaining being the polymer.

29. The method of claim 25, wherein the substrate carrier comprises a polymer material that contributes carbon to the formation of the carbon film and the organo-metallic bonds.

30. The method of claim 25, wherein the magnetographic printer comprises:

a rotating drum;

a static writing head array that transfers an electronic latent image from a CAD file onto the rotating drum in the form of a magnetic latent image;

a powder feeder that feeds the mixture to the rotating drum so that it is transferred to the magnetic latent image;

a hot roller that thermally activates the substrate carrier and draws in past the rotating drum so that the mixture in the form of the latent image is transferred onto the next sheet of the substrate carrier;

an erasing bar that magnetical erases the magnetic latent image from the drum after the mixture has been transferred to the substrate carrier; and

a cold roller that thermally deactivates the substrate carrier so that it can be cut and laminated into the green form part.

31. A method of direct metal fabrication (DMF) of metal parts, comprising:

a) providing a master mold for a green form part;

b) mixing a metal powder alloy comprising alloy X particles and a eutectic reducing element with a polymer resin that wets and binds the particles in said mold to form the green form part;

c) placing said mold in a furnace where it is subjected to a thermal cycle that f) partially reduces the polymer resin leaving a thin carbon film whose C═

C bonds maintain the part'"'"'s specified shape and acts as a catalyst causing the eutectic reducing element to become diffusely mobile, g) accelerates the diffusion of the eutectic reducing element along the grain boundaries of the adjacent alloy X particles to form organo-metallic bonds C═

A, h) initiates supersolidus liquid phase sintering (SLPS) to densify the powder into a final part whose organo-metallic C═

A bonds maintain the specified shape, and i)cools the final part to complete densification; and

j) removing the final part from the mold.

32. The method of claim 31, wherein said master mold is formed using a rapid prototype manufacturing (RM) process.

33. The method of claim 31, wherein said final part has the material quality of the metal powder alloy.

34. The method of claim 31, wherein the green form part is reduced in an environment in said furnace that is incapable of eliminating all of the carbon in said polymer resin.

35. The method of claim 31, wherein the concentration of the eutectic reducing element is sufficient to a) completely diffuse through the grain boundaries of the metal powder alloy, b) react with the carbon to form a sufficient number of organo-metallic bonds, and c) assist SLPS and the concentration of carbon is sufficient to a) survive the reduction, b) form the thin carbon film and c) react with the eutectic reducing element to form the organo-metallic bonds.

36. The method of claim 35, wherein the eutectic reducing element is introduced in a metal powder alloy (Y) which comprises:

(a) the same elemental components which comprise alloy X, and

(b) the eutectic reducing element in a concentration greater than any concentration of said eutectic element present in alloy X.