Electrochemical multigas sensor

• US 5,932,079 A
• Filed: 12/09/1997
• Issued: 08/03/1999
• Est. Priority Date: 06/07/1996
• Status: Expired due to Term

• Current Assignee: Dragerwerk AG
• Original Assignee: Dragerwerk AG
• Inventors: Lagois, Johannes, Bernstein, Christoph, Haupt, Stephan, Sagasser, Gero
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US08/987,206
• Time in Patent Office: 602 Days
• Field of Search: 204/415, 204/431, 204/432, 204/412, 205/783, 205/785.5, 205/786, 205/786.5, 205/793, 205/794.5
• US Class Current: 204/415
• CPC Class Codes: G01N 27/4045 for gases other than oxygen

Abstract

An electrochemical measuring cell for the simultaneous detection of different gas components in a gas sample, with a plurality of measuring electrodes (4, 5, 6) behind a diffusion barrier (7), with a common reference electrode (8) and counterelectrode (9) in an acid electrolyte, and with a potentiostatic evaluating circuit. Improvements in terms of service life for a sensor for the simultaneous detection of oxygen and carbon monoxide is provided with a reference electrode formed of a sintered mixture of metal and its metal oxide, preferably from the platinum group, the iridium group or gold and the potential of the CO-measuring electrode (5) relative to the reference electrode (8) is set at about 0 to 300 mV, and that of the O₂ -measuring electrode (4) is set at a value between -300 and -800 mV.

Claims

1. An electrochemical measuring cell for the simultaneous detection of different gas components in a gas sample, the measuring head comprising:

a diffusion barrier;

a plurality of measuring electrodes behind said diffusion barrier;

a common reference electrode comprised of a sintered mixture of metal and its metal oxide;

a common counterelectrode;

an acid electrolyte, said common reference electrode and said common counterelectrode being in said acid electrolyte;

a potentiostatic evaluating circuit maintaining electric potentials of said measuring electrodes at a predetermined value relative to said reference electrode independently from one another for the combined detection of CO and O₂, wherein one of said measuring electrodes is a CO-measuring electrode with an electric potential relative to said reference electrode set at a value of about 0 mV to 300 mV; and

one of said measuring electrodes is an O₂ -measuring electrode with an electric potential set at a value between -300 and -800 mV.

2. The electrochemical measuring cell in accordance with claim 1, wherein said sintered mixture of metal and its metal oxide is from the platinum group, the iridium group or is gold.

3. The electrochemical measuring cell in accordance with claim 1, wherein one of said measuring electrodes is a H₂ S-measuring electrode formed of gold, iridium or carbon/graphite, with an electrical potential relative to said reference electrode set at a value of about 0 to 200 mV;

and further comprising cross sensitivity means for compensating for cross sensitivity.

4. The electrochemical measuring cell in accordance with claim 3, further comprising a gas-selective filter provided before said CO-measuring electrode as a means of compensating H₂ S at said CO-measuring electrode.

5. An electrochemical measuring cell for the simultaneous detection of different gas components in a gas sample, the measuring head comprising:

a diffusion barrier;

a plurality of measuring electrodes behind said diffusion barrier;

a common reference electrode comprised of a sintered mixture of metal and its metal oxide;

a common counterelectrode;

an acid electrolyte, said common reference electrode and said common counterelectrode being in said acid electrolyte;

a potentiostatic evaluating circuit maintaining electric potentials of said measuring electrodes at a predetermined value relative to said reference electrode independently from one another for the combined detection of H₂ S and O₂, one of said measuring electrodes being a H₂ S-measuring electrode with an electric potential set relative to the said reference electrode at a value of about 0 to 200 mV, and another of said measuring electrodes is an O₂ -measuring electrode with an electric potential set at a between -300 mV and -800 mV, said H₂ S-measuring electrode being formed of gold, iridium or carbon/graphite.

6. The electrochemical measuring cell in accordance with claim 5, further comprising a gas-selective filter provided before said CO-measuring electrode as a means of compensating H₂ S at said CO-measuring electrode.

7. Electrochemical measuring cell in accordance with claim 5, wherein said cross sensitivity means is an electrolyte barrier within said diffusion barrier.

8. The electrochemical measuring cell in accordance with claim 5, wherein said sintered mixture of metal and its metal oxide is from the platinum group, the iridium group or is gold.

9. A method for simultaneous detection of gases in a sample, the method comprising;

providing a housing;

providing an acid electrolyte in said housing;

providing a diffusion barrier in said housing;

providing a CO measuring electrode in said electrolyte and against said diffusion barrier;

providing a O₂ measuring electrode in said electrolyte and against said diffusion barrier;

providing a common reference electrode in said electrolyte and formed of a sintered mixture of metal and metal oxide;

providing a common counterelectrode in said electrolyte;

setting an electric potential of said CO measuring electrode relative to said reference electrode to a value in a range of approximately 0 mV to 300 mV;

setting an electric potential of said O₂ measuring electrode relative to said reference electrode to a value in a range of approximately -300 mV to -800 mV wherein the detection of CO and O₂ in the sample are obtained.

10. A method in accordance with claim 9, wherein:

said metal of said reference electrode is formed from one of a platinum group, an iridium group and a gold group.

11. A method in accordance with claim 9, further comprising:

providing a H₂ S measuring electrode in said electrolyte and formed of one of gold, iridium and carbon graphite;

setting an electric potential of said H₂ S measuring electrode relative to said reference electrode to a value in a range of approximately 0 mV to 200 mV;

providing means for compensating H₂ S at said CO measuring electrode wherein detection of H₂ S in the sample is obtained.

12. A method for simultaneous detection of gases in a sample, the method comprising;

providing a housing;

providing an acid electrolyte in said housing;

providing a diffusion barrier in said housing;

providing a H₂ S measuring electrode in said electrolyte and against said diffusion barrier, said H₂ S measuring electrode being formed of one of gold, iridium and carbon/graphite;

providing a O₂ measuring electrode in said electrolyte;

providing a common reference electrode in said electrolyte formed of a sintered mixture of metal and metal oxide;

providing a common counterelectrode in said electrolyte;

setting an electric potential of said H₂ S measuring electrode relative to said reference electrode to a value in a range of approximately 0 mV to 200 mV;

setting an electric potential of said O₂ measuring electrode relative to said reference electrode to a value in a range of approximately -300 mV to -800 mV wherein the detection of H₂ S and O₂ in the sample are obtained.

13. A method in accordance with claim 12, wherein:

said metal of said reference electrode is formed from one of a platinum group, an iridium group and a gold group.