Fluorescent substance, fluorescent composition, fluorescent mark carrier and optical reader thereof

• US 5,932,139 A
• Filed: 11/17/1995
• Issued: 08/03/1999
• Est. Priority Date: 03/17/1994
• Status: Expired due to Term

• Current Assignee: Hitachi Maxell Limited (Maxell, Ltd.)
• Original Assignee: Hitachi Maxell Limited (Maxell, Ltd.)
• Inventors: Yamada, Yukinori, Kamoto, Takanori, Saibara, Shoji, Oshima, Toshio, Nabeshima, Tomio
• Primary Examiner(s): KOSLOW, CAROL M
• Application Number:
  US08/553,667
• Time in Patent Office: 1,355 Days
• Field of Search: 106/31.15, 106/31.64, 283/91, 283/92, 283/71, 252/301.36, 252/301.35, 252/301.16, 252/301.4 R
• US Class Current: 252/301.16
• CPC Class Codes: C09D 11/50 Sympathetic, colour changing or similar inks
• CPC Class Codes: C09K 11/02 Use of particular materials as binders, particle coatings or suspension media therefor
• CPC Class Codes: C09K 11/06 containing organic luminescent materials
• CPC Class Codes: C09K 11/08 containing inorganic luminescent materials
• CPC Class Codes: C09K 11/7701 Chalogenides
• CPC Class Codes: C09K 11/7706 Aluminates
• CPC Class Codes: C09K 11/7708 Vanadates; Chromates; Molybdates; Tungstates
• CPC Class Codes: C09K 11/7709 Phosphates
• CPC Class Codes: C09K 11/7756 containing neodynium
• CPC Class Codes: C09K 11/7769 Oxides C09K11/7768 takes precedence
• CPC Class Codes: C09K 11/7774 Aluminates
• CPC Class Codes: C09K 11/7776 Vanadates; Chromates; Molybdates; Tungstates
• CPC Class Codes: C09K 11/7777 Phosphates

Abstract

A fluorescent substance of the following general formula:

Ln.sub.X A.sub.1-X PO.sub.4

wherein Ln represents at least one element selected from the group consisting of Nd, Yb and Er; A represents at least one element selected from the group consisting of Y, La, Gd, Bi, Ce, Lu, In and Tb; and X represents a value within the range of 0.01 to 0.99.

Claims

1. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the fluorescent light, wherein the fluorescent substance is comprised of an organic metallic compound, and wherein the fluorescent substance contains Nd and Yb, the molar ratio of Nd relative to Yb (Nd:

Yb) being within the range of 9;

1 to 5;

5.

7. The fluorescent mark carrier as defined in any one of claims 1-6, wherein the fluorescent ink deposit is formed by an ink jet printer.

8. The fluorescent mark carrier as defined in any one of claims 1-6, wherein the fluorescent ink deposit contains a binder in a quantity not smaller than 5 wt %.

9. The fluorescent mark carrier as defined in any one of claim 1-6, wherein the fluorescent ink deposit is formed on a postal matter.

10. The fluorescent mark carrier as defined in any one of claims 1-6, wherein the fluorescent ink deposit is provided on a label to be affixed to the postal matter.

11. The fluorescent mark carrier as defined in any one of claims 1-6, wherein the fluorescent ink deposit bears information associated with a postal delivery.

2. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the exciting light, wherein the fluorescent substance is comprised of an organic metallic compound, and wherein the fluorescent substance contains Nd and Yb, the molar ratio of Nd relative to Yb (Nd:

Yb) being within the range of 9;

1 to 5;

5.

3. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the fluorescent light, wherein the fluorescent substance is at least one member selected from neodymium cinnamate, a complex salt of cinnamic acid with neodymium and ytterbium, a complex salt of benzoic acid with neodymium and ytterbium, neodymium naphthoate, and a complex salt of naphthoeic acid with neodymium and ytterbium.

4. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the exciting light, wherein the fluorescent substance is at least one member selected from neodymium cinnamate, a complex salt of cinnamic acid with neodymium and ytterbium, a complex salt of benzoic acid with neodymium and ytterbium, neodymium naphthoate, and a complex salt of naphthoeic acid with neodymium and ytterbium.

5. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the fluorescent light, wherein the fluorescent substance comprises Fe and Er, both as an optical active element, and, other than these optical active elements, at least one element selected from the group consisting of Sc, Ga, Al, In, Y, Bi, Ce, Gd, Lu and La.

6. A fluorescent mark carrier comprising a fluorescent ink deposit formed thereon, said fluorescent ink deposit containing a fluorescent substance capable of emitting a fluorescent light of a wavelength different from that of the exciting light and having an average particle size smaller than the wavelength of the maximum intensity of the exciting light, wherein the fluorescent substance comprises Fe and Er, both as an optical active element, and, other than these optical active elements, at least one element selected from the group consisting of Sc, Ga, Al, In, Y, Bi, Ce, Gd, Lu and La.