Fabric softening compositions with dye transfer inhibitors for improved fabric appearance

• US 5,932,253 A
• Filed: 06/12/1997
• Issued: 08/03/1999
• Est. Priority Date: 11/16/1992
• Status: Expired due to Term

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Wendland, Paul Arthur, Sung, Stephanie Lin-Lin, Trinh, Toan, Tordil, Helen Bernardo
• Primary Examiner(s): Jones, Dwayne C.
• Application Number:
  US08/873,787
• Time in Patent Office: 782 Days
• Field of Search: 252/8.81, 252/515, 252/519, 424/719
• US Class Current: 424/719
• CPC Class Codes: C11D 1/62 Quaternary ammonium compounds
• CPC Class Codes: C11D 17/041 Compositions releasably affixed on a substrate or incorporated into a dispensing means
• CPC Class Codes: C11D 3/001 Softening compositions
• CPC Class Codes: C11D 3/0015 liquid
• CPC Class Codes: C11D 3/0021 Dye-stain or dye-transfer inhibiting compositions
• CPC Class Codes: C11D 3/222 Natural or synthetic polysaccharides, e.g. cellulose, starch, gum, alginic acid or cyclodextrin
• CPC Class Codes: C11D 3/3769 (Co)polymerised monomers containing nitrogen, e.g. carbonamides, nitriles or amines
• CPC Class Codes: C11D 3/3773 in liquid compositions
• CPC Class Codes: C11D 3/3776 Heterocyclic compounds, e.g. lactam
• CPC Class Codes: C11D 3/3792 Amine oxide containing polymers
• CPC Class Codes: C11D 3/505 encapsulated or adsorbed on a carrier, e.g. zeolite or clay
• CPC Class Codes: D06P 1/5242 Polymers of unsaturated N-containing compounds
• CPC Class Codes: D06P 5/08 macromolecular

Abstract

The present invention relates to compositions and processes which incorporate water-soluble polymers, other than enzymes, containing ═N--C(═O)-- (including PVP) and/or N-oxide groups into the wash, rinse, and/or drying cycle of a laundering process (e.g., via fabric softening compositions) for dye transfer inhibition in the subsequent wash cycle. Multiple wash cycles optimize the dye transfer inhibitor performance of these polymers, remove unwanted dye discoloration caused by dye transfer, and provide soil antiredeposition benefits.

Claims

1. A liquid rinse added or solid particulate rinse added fabric softening composition capable of reducing the transfer of dyes during subsequent wash cycles, comprising:

I. from about 3% to about 90% of fabric softening agent; and

II. from about 0.03% to about 80% of water-soluble polymeric dye transfer inhibitor, selected from the group consisting of;

(A) polymers, which are not enzymes, with one or more monomeric units containing at least one ═

N--C(═

O)-- group having an average molecular weight of from about 500 to about 100,000;

(B) polymers with one or more monomeric units containing at least one N-oxide group having an average molecular weight of from about 500 to about 1,000,000;

(C) polymers containing both ═

N--C(═

O)-- and N-oxide groups of (A) and (B);

(D) mixtures thereof; and

wherein the composition is essentially free of aerosol propellant, bleach, sachets containing an active ingredient, and anionic surfactant; and

additionally when the composition is a liquid composition, and the fabric softening agent is methyl-1-oleylamidoethyl-2-oleylimidazolinium methosulfate, or analogous agent, the composition is essentially free of large amounts of highly ethoxylated material, propylated material, or mixtures thereof.

2. The fabric softening composition according to claim 1 wherein said dye transfer inhibitor is polyvinylpyrrolidone.

3. The fabric softening composition according to claim 1 wherein said dye transfer inhibitor is poly(4-vinylpyridine N-oxide).

4. Liquid rinse-added composition according to claim 1 comprising:

I. from about 3% to about 50% fabric softening agent; and

II. from about 0.03% to about 25% of said dye transfer inhibitor.

5. The liquid composition according to claim 4 wherein said dye transfer inhibitor is (A) having an average molecular weight of from about 500 to about 40,000.

6. The liquid composition according to claim 5 wherein said dye transfer inhibitor has an average molecular weight of from about 1,000 to about 30,000.

7. The liquid composition according to claim 4 wherein said dye transfer inhibitor is polyvinylpyrrolidone.

8. The liquid composition according to claim 4 wherein said dye transfer inhibitor is (B) having an average molecular weight of from about 1,000 to about 100,000.

9. The liquid composition according to claim 8 wherein said dye transfer inhibitor has an average molecular weight of from about 2,000 to about 100,000.

10. The liquid composition according to claim 4 wherein said dye transfer inhibitor is poly(4-vinylpyridine N-oxide).

11. The process of making the liquid composition of claim 4 comprising the following steps:

(a) Adding dye transfer inhibitor to the water seat, the water seat having a temperature of from about 100°

F. to about 190°

F.;

(b) Adding the fabric softening agent into the water seat with agitation;

(c) Optionally adding a viscosity control agent; and

(d) Cooling the composition.

12. The process of claim 11 in the dye transfer inhibitor is added after Step (b) but before Step (c).

13. The solid particulate composition according to claim 1 comprising:

I. from about 20% to about 90% fabric softening agent; and

II. from about 0.1% to about 80% said dye transfer inhibitor.

14. The solid particulate composition according to claim 13 wherein the fabric softening agent is from about 30% to about 70% and said dye transfer inhibitor is from about 0.5% to about 25%.

15. The solid, particulate composition according to claim 13 wherein said dye transfer inhibitor is (A) having an average molecular weight of from about 500 to about 40,000.

16. The solid, particulate composition according to claim 15 wherein said dye transfer inhibitor has an average molecular weight of from about 1,000 to about 30,000.

17. The solid, particulate composition according to claim 13 wherein said dye transfer inhibitor is polyvinylpyrrolidone.

18. The solid, particulate composition according to claim 13 wherein said dye transfer inhibitor is (B) having an average molecular weight of from about 1,000 to about 100,000.

19. The solid, particulate composition according to claim 18 wherein said dye transfer inhibitor has an average molecular weight of from about 2,000 about 100,000.

20. The solid, particulate composition according to claim 18 wherein said dye transfer inhibitor is poly(4-vinylpyridine N-oxide).