Advanced polymer wood composite

• US 5,932,334 A
• Filed: 11/13/1997
• Issued: 08/03/1999
• Est. Priority Date: 08/31/1992
• Status: Expired due to Term

• Current Assignee: Andersen Corporation
• Original Assignee: Andersen Corporation
• Inventors: Deaner, Michael J., Heikkila, Kurt E., Puppin, Giuseppe
• Primary Examiner(s): Tsang, Cecilia J.
• Assistant Examiner(s): Delaney, Patrick R.
• Application Number:
  US08/969,686
• Time in Patent Office: 628 Days
• Field of Search: 428/292.4, 524/4, 524/405
• US Class Current: 428/292.4
• CPC Class Codes: B27N 3/007 and at least partly composed of recycled material
• CPC Class Codes: B27N 3/28 characterised by using extrusion presses
• CPC Class Codes: B29B 9/14 fibre-reinforced
• CPC Class Codes: B29K 2311/14 Wood, e.g. woodboard or fibreboard
• CPC Class Codes: C08J 11/06 without chemical reactions
• CPC Class Codes: C08J 2327/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08J 5/045 with vegetable or animal fibrous material
• CPC Class Codes: C08J 5/047 with mixed fibrous material
• CPC Class Codes: C08J 5/06 using pretreated fibrous materials
• CPC Class Codes: C08K 7/02 Fibres or whiskers
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2205/03 containing three or more polymers in a blend
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 2666/06 Homopolymers or copolymers of unsaturated hydrocarbons; Derivatives thereof
• CPC Class Codes: C08L 2666/08 Homopolymers or copolymers according to C08L7/00 - C08L21/00; Derivatives thereof
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: C08L 27/06 Homopolymers or copolymers of vinyl chloride
• CPC Class Codes: C08L 97/02 Lignocellulosic material, e.g. wood, straw or bagasse manufacture of articles made from lignocellulosic material by dry processes B27N
• CPC Class Codes: Y02W 30/62 Plastics recycling; Rubber recycling
• CPC Class Codes: Y10T 428/249925 : Fiber-containing wood product [e.g., hardboard, lumber, or wood board, etc.]
• CPC Class Codes: Y10T 428/253 : Cellulosic [e.g., wood, paper, cork, rayon, etc.]
• CPC Class Codes: Y10T 428/26 : Web or sheet containing structurally defined element or component, the element or component having a specified physical dimension
• CPC Class Codes: Y10T 428/2904 : Staple length fiber
• CPC Class Codes: Y10T 428/2907 : with coating or impregnation
• CPC Class Codes: Y10T 428/2938 : Coating on discrete and individual rods, strands or filaments
• CPC Class Codes: Y10T 428/2965 : Cellulosic
• CPC Class Codes: Y10T 428/2982 : Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/2998 : including synthetic resin or polymer
• CPC Class Codes: Y10T 428/31591 : Next to cellulosic
• CPC Class Codes: Y10T 428/31779 : Next to cellulosic
• CPC Class Codes: Y10T 428/31783 : Paper or wood
• CPC Class Codes: Y10T 428/3188 : Next to cellulosic
• CPC Class Codes: Y10T 428/31891 : Where addition polymer is an ester or halide
• CPC Class Codes: Y10T 428/31895 : Paper or wood
• CPC Class Codes: Y10T 428/31906 : Ester, halide or nitrile of addition polymer

Abstract

The invention relates to a composition or pellet comprising a polyvinyl chloride homopolymer and wood fiber composite that can be used in the form of a linear extrudate or thermoplastic pellet to manufacture structural members. The fiber in the pellet or extrudate is of a particular dimension that lends enhanced modulus to the composition or pellet formed. The extruded pellet comprises a consistent proportion of polymer, wood fiber and water.

Claims

1. A composite thermoplastic pellet, capable of formation into a structural member, which pellet consists essentially of a thermoplastic cylindrical extrudate having a width of about 1 to 5 mm, a length of about 1 to 10 mm;

the thermoplastic pellet composition consisting essentially of;

(a) a continuous phase comprising a polyvinyl chloride homopolymner;

(b) an effective amount of wood fiber having a minimum thickness of 0.1 mm and a minimum aspect ratio of about 1.8 to provide structural properties to the structural member; and

(c) less than about 8 wt % water; and

wherein the polyvinyl chloride homopolymer and wood fiber are mixed at elevated temperature and pressure such that an intimate admixture is formed and tic wood fiber is dispersed throughout a continuous polyvinyl chloride homopolymer phase and the composite has a Young'"'"'s modulus of at least about 600,000 psi.

2. The pellet of claim 1 wherein the polyvinyl chloride homopolymer additionally comprises a polyvinyl chloride polymer alloy.

3. The pellet of claim 1 wherein the wood fiber comprises a by-product of milling or sawing wooden members.

4. The pellet of claim 1 wherein the wood fiber comprises sawdust.

5. The pellet of claim 1 wherein the composition additionally comprises a compatiblizing agent.

6. The pellet of claim 1 wherein the polyvinyl chloride homopolymer has a molecular weight of about 90,000±

50,000.

7. The pellet of claim 1 wherein the polyvinyl chloride homopolymer comprises a copolymer having a molecular weight of about 88,000±

10,000.

8. The pellet of claim 1 wherein the wood fiber has a fiber width of about 0.3 to 1.5 mm, a fiber length of about 1 to 10 mm and a aspect ratio of about 2 to 7.

9. The pellet of claim 1 wherein the water comprises about 0.01 to 5 wt % of the pellet.

10. A polymer and wood fiber thermoplastic composite capable of formation into a structural member, which composite consists essentially of a thermoplastic cylindrical linear extrudate having a radius of about 1 to 5 mm;

the linear thermoplastic extrudate composition consisting essentially of;

(a) a continuous phase comprising a polyvinyl chloride homopolymer;

(b) an effective amount of wood fiber having a minimum thickness of 0.1 mm and an aspect ratio of about 1.8 to provide structural properties to a composite;

(c) less than about 8 wt % water; and

wherein the polyvinyl chloride homopolymer and wood fiber are mixed at elevated temperature and pressure such that an intimate admixture is formed and the wood fiber is dispersed throughout a continuous phase and the composite has a Young'"'"'s modulus of at least about 600,000 psi.

11. The cumposite of claim 10 wherein the polyvinyl chloride homopolymer additionally comprises a polyvinyl chloride polymer alloy.

12. The composite of claim 10 wherein the wood fiber comprises a by-product of milling or sawing wooden members.

13. The composite of claim 12 wherein the wood fiber comprises sawdust.

14. The composite of claim 10 wherein the composition additionally comprises a compatibilizing agent.

15. The composite of claim 10 wherein the polyvinyl chloride homopolyer has a molecular weight of about 95,000±

50,000.

16. The composite of claim 10 wherein the polyvinyl chloride homopolymer comprises a copolymer has a molecular weight of about 88,000±

10,000.

17. The composite of claim 10 wherein the wood fiber has a fiber width of about 0.3 to 1.5 mm, a fiber length of about 1 to 10 mm and a aspect ratio of about 2 to 7.

18. The composite of claim 10 wherein the water comprises about 0.01 to 5 wt % of the pellet.

19. A thermoplastic composite composition, capable of extrusion into a dimensionally stable structural member, which consists essentially of a thermoplastic composition which comprises:

(a) a continuous phase comprising a polyvinyl chloride homopolymer;

(b) an effective amount of wood fiber having a minimum width of 0.1 mm and an aspect ratio of greater than about 1.8 to provide structural properties to the composite;

(c) about 0.01 to 25 wt % of an intentionally recycled impurity comprising thermoplastic polymer, an adhesive, a paint, a thermoplastic resin or mixtures thereof; and

(d) less than about 10 wt % water;

wherein the polyvinyl chloride homopolymer and wood fiber are mixed at elevated temperature and pressure such that an intimate admixture is formed and the wood fiber is dispersed throughout the continuous thermoplastic polyvinyl chloride homopolymer phase and the composite has a Young'"'"'s modulus of at least about 600,000 psi.

20. The composition of claim 19 wherein the polymer comprises a polyvinyl chloride homopolymer.

21. The composition of claim 19 wherein the polymer comprises a polyvinyl chloride polymer alloy.

22. The composition of claim 19 wherein the wood fiber comprises a by-product of milling or sawing wooden members.

23. The composition of claim 19 wherein the wood fiber comprises sawdust.

24. The composition of claim 20 wherein the polymer has a molecular weight of about 95,000±

50,000.

25. The composition of claim 21 wherein the polymer comprises a copolymer having a molecular weight of about 88,000±

10,000.

26. The composition of claim 19 wherein ther wood fiber has a fiber width of about 0.3 to 1.5 mm, a fiber length of about 1 to 10 mm and a aspect ratio of about 2 to 7.

27. The composition of claim 19 wherein water comprises about 0.01 to 3.5 wt % of the composition.