Switchable volume hologram materials and devices

• US 5,942,157 A
• Filed: 07/12/1996
• Issued: 08/24/1999
• Est. Priority Date: 07/12/1996
• Status: Expired due to Term

• Current Assignee: Adams W. Wade, Air Force Government of The United States of America As Represented By The Secretary, Leidos, Inc. (Leidos Holdings, Inc.)
• Original Assignee: Science Applications International Corporation
• Inventors: Tondiglia, Vince P., Sutherland, Richard L., Bunning, Timothy J., Natarajan, Lalqudi V., Adams, W. Wade
• Primary Examiner(s): KELLY, CYNTHIA HARRIS
• Application Number:
  US08/680,292
• Time in Patent Office: 1,138 Days
• Field of Search: 252/299.01, 252/582, 349/2, 359/15
• US Class Current: 252/582
• CPC Class Codes: C09K 19/544 as dispersing or encapsulating medium around the liquid crystal
• CPC Class Codes: C09K 2323/00 Functional layers of liquid crystal optical display excluding electroactive liquid crystal layer characterised by chemical composition
• CPC Class Codes: C09K 2323/03 Viewing layer characterised by chemical composition
• CPC Class Codes: G02F 1/13342 Holographic polymer dispersed liquid crystals
• CPC Class Codes: G03F 7/001 Phase modulating patterns, e.g. refractive index patterns
• CPC Class Codes: G03F 7/031 Organic compounds not covered by group G03F7/029
• CPC Class Codes: G03H 1/02 Details of features involved during the holographic process; Replication of holograms without interference recording
• CPC Class Codes: G03H 1/0248 Volume holograms
• CPC Class Codes: G03H 2001/026 Recording materials or recording processes G03H2226/11 takes precedence; corresponding details, see subgroups of G03H2260/00
• CPC Class Codes: G03H 2260/12 Photopolymer
• CPC Class Codes: G03H 2260/33 Having dispersed compound
• CPC Class Codes: Y10T 428/24802 Discontinuous or differential coating, impregnation or bond [e.g., artwork, printing, retouched photograph, etc.]

Abstract

A new photopolymerizable material allows single-step, fast recording of volume holograms with properties that can be electrically controlled. Polymer-dispersed liquid crystals (PDLCs) in accordance with the invention preferably comprise a homogeneous mixture of a nematic liquid crystal and a multifunctional pentaacrylate monomer, in combination with photoinitiator, coinitiator and cross-linking agent. Optionally, a surfactant such as octanoic acid may also be added. The PDLC material is exposed to coherent light to produce an interference pattern inside the material. Photopolymerization of the new PDLC material produces a hologram of clearly separated liquid crystal domains and cured polymer domains. Volume transmission gratings made with the new PDLC material can be electrically switched between nearly 100% diffraction efficiency and nearly 0% diffraction efficiency. By increasing the frequency of the switching voltage, switching voltages in the range of 50 Vrms can be achieved. The optional use of surfactant allows low switching voltages at lower frequencies than without surfactant. In an alternative embodiment, a PDLC material in accordance with the invention can be utilized to form reflection gratings, including switchable reflection gratings. In still further embodiments, a PDLC material in accordance with the invention can be used to form switchable subwavelength gratings. By further processing, static transmission reflection, and subwavelength PDLC materials can be formed.

Claims

1. A reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

whereby the polymer-dispersed liquid crystal material is adapted to reflect radiation after exposure.

2. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material further comprises, before exposure, a surfactant.

3. The reflection hologram of claim 1, wherein:

(a) the liquid crystal comprises 10-40% by total weight of the polymer-dispersed liquid crystal material;

(b) the cross-linking monomer comprises 5-15% by total weight of the polymer-dispersed liquid crystal material;

(c) the amount of coinitiator is 10^-3 to 10^-4 gram moles; and

(d) the amount of photoinitiator dye is 10^-5 to 10^-6 gram moles.

4. The reflection hologram of claim 1, wherein:

(a) the liquid crystal comprises 10-40% by total weight of the polymer-dispersed liquid crystal material;

(b) the cross-linking monomer comprises 10-18% by total weight of the polymer-dispersed liquid crystal material;

(c) the coinitiator comprises 2-3% by total weight of the polymer-dispersed liquid crystal material; and

(d) the photoinitiator dye comprises 0.2-0.4% by total weight of the polymer-dispersed liquid crystal material.

5. The reflection hologram according to claim 2, wherein the surfactant comprises about 6% by total weight of the polymer-dispersed liquid crystal material.

6. The reflection hologram according to claim 2, wherein the surfactant comprises about 5-10% by total weight of the polymer-dispersed liquid crystal material.

7. The reflection hologram according to claim 1, wherein the liquid crystal includes a mixture of cyano biphenyls.

8. The reflection hologram according to claim 1, wherein the cross linking monomer comprises N-vinylpyrrolidone.

9. The reflection hologram according to claim 1, wherein the coinitiator comprises N-phenylglycine.

10. The reflection hologram according to claim 1, wherein the photoinitiator dye comprises rose bengal ester.

11. The reflection hologram according to claim 2, wherein the surfactant comprises octanoic acid.

12. The reflection hologram of claim 1, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

13. The reflection hologram according to claim 1, wherein the liquid cystal comprises 4'"'"'-n-pentyl-4-cyanobiphenyl.

14. The reflection hologram according to claim 1, wherein the liquid crystal comprises 4'"'"'-n-pentyl-4-cyanobiphenyl.

15. The reflection hologram according to claim 1, wherein the liquid crystal comprises 4'"'"'-n-pentyl-4-cyanobiphenyl.

16. The reflection hologram according to claim 1, wherein the liquid crystal comprises 4'"'"'-n-pentyl-4-cyanobiphenyl.

17. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material comprises 0.2% by weight to 0.4% by weight of a photoinitiator dye.

18. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material comprises a photoinitiator dye comprising rose bengal sodium salt.

19. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material comprises about 2% by weight to 3% by weight of a coinitiator.

20. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material comprises a coinitiator comprising N-phenyglycine;

and a photoinitiator dye comprising camphorquinone.

21. The reflection hologram according to claim 1, wherein the polymer-dispersed liquid crystal material comprises about 10% by weight to 18% by weight of a cross-linking monomer.

22. A reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) more than about 20% by weight of liquid crustal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

whereby the polymer-dispersed liquid crystal material is adapted to reflect radiation after exposure.

23. The hologram according to claim 22, wherein the polymer-dispersed liquid crystal material, further comprises, before exposure a surfactant.

24. A reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) from about 20% by weight to 35% by weight of liquid crystal;

(c) a cross-linking monomer;

(d) a coinitiator; and

(e) a photoinitiator dye;

whereby the polymer-dispersed liquid crystal material is adapted to reflect radiation after exposure.

25. A reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a liquid crystal comprising 10-40% by total weight of the material;

(c) a cross-linking monomer comprising 5-15% by total weight of the material;

(d) 10^-3 to 10^-4 gram moles of a coinitiator; and

(e) 10^-5 to 10^-6 gram moles of a photoinitiator dye;

whereby the polymer-dispersed liquid crystal material is adapted to reflect radiation after exposure.

26. The reflection hologram of claim 25, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.

27. A reflection hologram made by exposing an interference pattern inside a polymer-dispersed liquid crystal material, the polymer-dispersed liquid crystal material comprising, before exposure:

(a) a polymerizable monomer;

(b) a liquid crystal comprising 10-40% by total weight of the material;

(c) a cross-linking monomer comprising 10-18% by total weight of the material;

(d) a coinitiator comprising 2-3% by total weight of the material; and

(e) a photoinitiator dye comprising 0.2-0.4% by total weight of the material;

whereby the polymer-dispersed liquid crystal material is adapted to reflect radiation after exposure.

28. The reflection hologram of claim 27, wherein the polymerizable monomer comprises dipentarythritol hydroxypentaacrylate.