Oxide sensor

• US 5,942,190 A
• Filed: 02/19/1997
• Issued: 08/24/1999
• Est. Priority Date: 02/23/1996
• Status: Expired due to Term

• Current Assignee: NGK Insulators Limited
• Original Assignee: NGK Insulators Limited
• Inventors: Kato, Nobuhide, Nakagaki, Kunihiko
• Primary Examiner(s): Le, Long V.
• Application Number:
  US08/802,280
• Time in Patent Office: 916 Days
• Field of Search: 422/83, 422/90, 422/98, 436/116, 436/117, 436/118, 73/31.05, 204/425, 204/426, 204/427, 204/406
• US Class Current: 422/98
• CPC Class Codes: G01N 27/4074 for detection of gases other than oxygen
• CPC Class Codes: G01N 27/419 Measuring voltages or currents with a combination of oxygen pumping cells and oxygen concentration cells
• CPC Class Codes: Y10T 436/177692 Oxides of nitrogen
• CPC Class Codes: Y10T 436/179228 Both nitrogen oxide and dioxide

Abstract

Disclosed is an oxide sensor in which a measuring electrode is arranged at a distance d to satisfy -3t≦d≦3t for a downstream end of an inner pumping electrode for a first chamber, i.e., the end located on a side of a second diffusion rate-determining section, provided that d represents a distance between the measuring electrode and the downstream end in a positive direction directed from the first chamber to a second chamber, and t represents a height of the first chamber. A partial pressure of oxygen in the first chamber is measured by using the measuring electrode. A main pumping cell is subjected to feedback control on the basis of a measured value so that the partial pressure of oxygen in the first chamber is controlled. After that, a measurement gas is introduced into the second chamber. Oxides contained in the measurement gas are decomposed by the aid of a detecting electrode or a catalyst. A partial pressure of oxygen produced by the decomposition is measured to determine the concentration of the oxides. Accordingly, it is possible to measure the oxides contained in the measurement gas with an extremely high degree of accuracy. Moreover, the obtainable oxide sensor is compact and inexpensive.

Claims

1. An oxide sensor comprising:

a main pumping means including a first solid electrolyte for contacting with external space, and inner and outer electrodes formed on inner and outer surfaces of the first solid electrolyte, for performing a pumping process for oxygen contained in a measurement gas introduced from said external space, on said basis of a control voltage applied between said electrodes;

a concentration-measuring means including a second solid electrolyte, an inner measuring electrode formed on the second solid electrolyte on a side opposite to inner measuring electrode, for measuring an electromotive force of an oxygen concentration cell, generated corresponding to a difference in partial pressure between oxygen resulting from said pumping process performed by said main pumping means and oxygen contained in a gas existing on a side of said outer measuring electrode;

a main pumping control means for adjusting a level of said control voltage so that said electromotive force of said oxygen concentration cell detected by said concentration-measuring means has a predetermined value; and

an electric signal-generating conversion means including the second solid electrolyte and inner and outer detecting electrodes provide in contact with the second solid electrolyte, for providing, by conversion, an electric signal corresponding to an amount of oxygen contained in said measurement gas after being subjected to said pumping process performed by said main pumping means, wherein;

said inner measuring electrode is arranged at a position at which -3t≦

d is satisfied provided that a downstream direction along a space for said pumping process performed by said main pumping means is defined as a positive direction, a height of said space for said pumping process is represented by t, and a protective distance between a downstream end of said inner pumping electrode of said main pumping means and a center of said inner measuring electrode of said concentration-measuring means is represented by d, and wherein;

oxides in said measurement gas are measured on the basis of said electric signal supplied from said electric signal-generating conversion means.

2. The oxide sensor according to claim 1, wherein said electric signal-generating conversion means further comprises:

a measuring pumping means including the second solid electrolyte, said inner detecting electrode formed on the second solid electrolyte on a side opposite to said inner detecting electrode, for performing a pumping process for said oxygen contained in said measurement gas after being subjected to said pumping process performed by said main pumping means, on the basis of a measuring voltage applied between said inner and outer detecting electrodes; and

a current-detecting means for detecting a pumping current generated corresponding to an amount of said oxygen subjected to said pumping process performed by said measured pumping means, wherein;

said oxides in said measurement gas are measured on the basis of said pumping current detected by said current-detecting means.

3. The oxide sensor according to claim 2, wherein said measuring pumping means performs said pumping process for said oxygen produced by any one of or both of actions of application of a voltage sufficient to decompose said oxides between said inner and outer detecting electrodes, and an oxide-decomposing catalyst arranged in said measuring pumping means, on the basis of said measuring voltage applied between said inner and outer detecting electrodes.

4. The oxide sensor according to claim 3, wherein said oxide-decomposing catalyst is an Rh cermet.

5. The oxide sensor according to claim 1, wherein, said electric signal-generating conversion means further comprises:

a concentration-detecting means including the second solid electrolyte, an inner detecting electrode formed on the second solid electrolyte, and said outer electrode formed on the second solid electrolyte on a side opposite to said inner detecting electrode, for generating an electromotive force corresponding to a difference between an amount of oxygen contained in said measurement gas after being subjected to said pumping process performed by said main pumping means and an amount of oxygen contained in said gas existing on said side of said outer detecting electrode; and

a voltage-detecting means for detecting said electromotive force generated by said concentration-detecting means, wherein;

said oxides in said measurement gas are measured on the basis of said electromotive force detected by said voltage-detecting means.

6. The oxide sensor according to claim 5, wherein said concentration-detecting means generates said electromotive force of an oxygen concentration cell, corresponding to a difference in partial pressure between oxygen produced by an action of an oxide-decomposing catalyst arranged in said concentration-detecting means and said oxygen contained in said gas existing on said side of said outer detecting electrode.

7. The oxide sensor according to claim 6, wherein said oxide-decomposing catalyst is an Rh cermet.

8. The oxide sensor according to claim 1, wherein said inner measuring electrode of said concentration-detecting means is arranged at a position at which -3t≦

d≦

3t is satisfied.

9. The oxide sensor according to claim 1, wherein said inner measuring electrode of said concentration-measuring means has a width w along said downstream direction which satisfies w≦

5t.

10. The oxide sensor according to claim 1, wherein said inner pumping electrode of said main pumping means is composed of an inactive material having a low catalytic activity on said oxides.

11. The oxide sensor according to claim 1, wherein said oxides are nitrogen oxides.

12. The oxide sensor according to claim 1, further comprising an auxiliary pumping means including an auxiliary pumping electrode formed in the vicinity of said inner detecting electrode, wherein said oxygen contained in said measurement gas after being subjected to said pumping process performed by said main pumping means is subjected to a pumping process on the basis of a voltage applied between said auxiliary pumping electrode and said outer detecting electrode.

13. The oxide sensor according to claim 1, wherein said outer measuring electrode is arranged at a position exposed to a space into which a reference gas is introduced.

14. The oxide sensor according to claim 1, wherein said outer measuring electrode and said outer detecting electrode are combined into a common unit.

15. The oxide sensor according to claim 1, wherein:

said main pumping means includes said inner and outer pumping electrodes formed at the inside and the outside of a first chamber surrounded by solid electrolyte substrates, for introducing said measurement gas thereinto, and said substrate interposed between said both electrodes;

said concentration-measuring means includes said measuring electrode formed at the inside of said first chamber, a reference electrode formed in a reference gas-introducing space surrounded by said solid electrolyte substrates, for introducing a reference gas thereinto, and said substrate interposed between said measuring electrode and said reference electrode; and

said electric signal-generating conversion means includes said detecting electrode formed at the inside of a second chamber surrounded by said solid electrolyte substrates, for introducing said measurement gas thereinto after being subjected to said pumping process performed by said main pumping means, a reference electrode formed at the inside of said reference gas-introducing space, and said substrate interposed between said detecting electrode and said reference electrode.

16. The oxide sensor according to claim 15, further comprising:

a first diffusion rate-determining section for giving a predetermined diffusion resistance to said measurement gas, provided at a passage for introducing said measurement gas from said external space into said first chamber; and

a second diffusion rate-determining section for giving a predetermined diffusion resistance to said measurement gas, provided at a passage for introducing said measurement gas into said second chamber after being subjected to said pumping process performed by said main pumping means.

17. The oxide sensor according to claim 15, wherein said inner pumping electrode and said measuring electrode are arranged on an identical plane of any one of said substrates in said first chamber.

18. The oxide sensor according to claim 15, further comprising:

a plurality of diffusion rate-determining sections for giving predetermined diffusion resistances to said measurement gas supplied from said first chamber; and

a plurality of second chambers as defined above for measuring said oxides of different types respectively.

19. The oxide sensor according to claim 18, wherein said plurality of second chambers are arranged in series to said first chamber.

20. The oxide sensor according to claim 18, wherein said plurality of second chambers are arranged in parallel to said first chamber.

21. The oxide sensor according to claim 15, further comprising a third diffusion rate-determining section for giving a predetermined diffusion resistance to said measurement gas, provided at a passage for allowing said measurement gas in said second chamber to approach said detecting electrode.