Coated articles

• US 5,942,338 A
• Filed: 02/13/1998
• Issued: 08/24/1999
• Est. Priority Date: 04/25/1996
• Status: Expired due to Term

• Current Assignee: Vitro Flat Glass LLC (Compagnie De Saint-Gobain)
• Original Assignee: PPG Industries Ohio Incorporated (Nouryon BV)
• Inventors: Medwick, Paul A., Arbab, Mehran, Marietti, Gary J., Criss, Russell C.
• Primary Examiner(s): ACHUTAMURTHY, PONNATHAPURA N
• Application Number:
  US09/023,746
• Time in Patent Office: 557 Days
• Field of Search: 428/623, 428/630, 428/632, 428/633, 428/670
• US Class Current: 428/623
• CPC Class Codes: C03C 17/36 at least one coating being a metal
• CPC Class Codes: C03C 17/3618 Coatings of type glass/inorganic compound/other inorganic layers, at least one layer being metallic
• CPC Class Codes: C03C 17/3639 Multilayers containing at least two functional metal layers
• CPC Class Codes: C03C 17/3642 the multilayer coating containing a metal layer
• CPC Class Codes: C03C 17/3644 the metal being silver
• CPC Class Codes: C03C 17/3652 the coating stack containing at least one sacrificial layer to protect the metal from oxidation
• CPC Class Codes: C03C 17/366 Low-emissivity or solar control coatings
• CPC Class Codes: C03C 17/3681 the multilayer coating being used in glazing, e.g. windows or windscreens
• CPC Class Codes: C03C 2217/78 Coatings specially designed to be durable, e.g. scratch-resistant
• CPC Class Codes: G02B 1/116 including electrically conducting layers
• CPC Class Codes: G02B 1/14 Protective coatings, e.g. hard coatings
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: Y10T 428/12549 Adjacent to each other
• CPC Class Codes: Y10T 428/12597 Noncrystalline silica or noncrystalline plural-oxide component [e.g., glass, etc.]
• CPC Class Codes: Y10T 428/12611 Oxide-containing component
• CPC Class Codes: Y10T 428/12618 Plural oxides
• CPC Class Codes: Y10T 428/12875 Platinum group metal-base component

Abstract

Multilayer high transmittance, low emissivity coatings deposited over transparent substrates have improved mechanical durability, e.g. scratch resistance by the inclusion of at least one mechanical durability enhancing layer (hereinafter "MDE layer"). The MDE layer includes one or more pairs of a zinc oxide sublayer having deposited thereover a sublayer of an oxide of zinc and tin. In one embodiment of the present invention, the MDE layer is composed of two sublayers which includes a first sublayer of an oxide of zinc having deposited thereover a second sublayer of an oxide of zinc and tin. In another embodiment of the invention, the MDE layer is composed of four sublayers which includes a first sublayer of an oxide of zinc, having deposited thereover a second sublayer of an oxide of zinc and tin, having deposited thereover a third sublayer of an oxide of zinc, having deposited thereover a fourth sublayer of an oxide of zinc and tin. Coated articles having the MDE layer of the invention can be thermally processed for tempering, heat strengthening, annealing or bending without haze formation and can be manipulated prior to such thermal processing with little or no surface scratching appearing after such thermal processing.

Claims

1. A high transmittance, low emissivity mechanically durable coated article comprising:

a transparent, nonmetallic substrate;

a dielectric, antireflective base layer deposited over the substrate;

a metallic reflective layer deposited over the base layer;

a primer layer deposited over the metallic reflective layer; and

a mechanical durability enhancing layer deposited over the primer layer, wherein the mechanical durability enhancing layer comprises at least two sublayers, wherein a first sublayer deposited over the primer layer includes an oxide of zinc and a second sublayer deposited over the first sublayer includes an oxide of zinc and tin.

2. The coated article of claim 1 further comprising a protective overcoat layer deposited over the mechanical durability enhancing layer.

3. The coated article of claim 2 wherein said base layer is in contact with said substrate, said metallic reflective layer is in contact with said base layer, said primer layer is in contact with said metallic reflective layer, said mechanical durability enhancing layer is in contact with said primer layer and said protective overcoat layer is in contact with said mechanical durability enhancing layer.

4. The coated article of claim 1 wherein the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin.

5. The coated article of claim 2 wherein the base layer further comprises:

a crystalline metal-contacting film-part; and

a support part;

where the support part is in contact with the substrate and where the support part is comprised of a material other than the crystalline metal-contacting film-part.

6. The coated article of claim 5 wherein the transparent, nonmetallic substrate is glass, the support part is a zinc film, the crystalline metal-contacting film-part is a zinc oxide film;

the metallic reflective layer is a silver film, the primer layer is titanium metal, the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin and the protective overcoat layer is a titanium oxide film.

7. A high transmittance, low emissivity mechanically durable coated article comprising:

a transparent, nonmetallic substrate;

a first dielectric, antireflective base layer deposited over the substrate,

a first metallic reflective layer deposited over the base layer;

a first primer layer deposited over the metallic reflective layer;

a second dielectric, antireflective base layer deposited over the first primer layer;

a second metallic reflective layer deposited over the second base layer;

a second primer layer deposited over the second metallic reflective film; and

a dielectric, antireflective mechanical durability enhancing layer deposited over the second primer layer, wherein the mechanical durability enhancing layer includes at least two sublayers, wherein a first sublayer deposited over the second primer layer includes an oxide of zinc and a second sublayer deposited over the first sublayer includes an oxide of zinc and tin.

8. The coated article of claim 7 further comprising a protective overcoat layer deposited over the mechanical durability enhancing layer.

9. The coated article of claim 8 wherein said first base layer is in contact with said substrate, said first metallic reflective layer is in contact with said first base layer, said first primer layer is in contact with said first metallic reflective layer, said second base layer is in contact with said first primer layer, said second metallic reflective layer is in contact with said second base layer, said second primer layer is in contact with said second metallic reflective layer, said mechanical durability enhancing layer is in contact with said second primer layer and said protective overcoat layer is in contact with said mechanical durability enhancing layer.

10. The coated article of claim 7 wherein the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin.

11. The coated article of claim 8 wherein the first base layer comprises a crystalline metal-contacting film-part and a support part where the support part is in contact with the substrate and where the support part is comprised of a material other than the crystalline metal-contacting film-part.

12. The coated article of claim 11 wherein the second base layer comprises a crystalline metal-contacting film-part and a support part where the support part is in contact with the primer layer and where the support part is comprised of a material other than the crystalline metal-contacting film-part of the second base layer.

13. The coated article of claim 12 wherein the transparent, nonmetallic substrate is glass, the support part of the first base layer is a zinc stannate film, the crystalline metal-contacting film-part of the first base layer is a zinc oxide film;

the first metallic reflective layer is a silver film, the first primer layer is deposited as titanium metal, the support part of the second base layer is a zinc stannate film, the crystalline metal-contacting film-part of the second base layer is a zinc oxide film;

the second metallic reflective layer is a silver film, the second primer layer is deposited as titanium metal, the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin, and the protective overcoat layer is a titanium oxide film.

14. A high transmittance, low emissivity coated article with improved shelf life and enhanced mechanical durability comprising:

a transparent, nonmetallic substrate;

a first dielectric, antireflective base layer deposited over the substrate;

a first metallic reflective layer deposited over the first base layer;

a first primer layer deposited over the metallic reflective film;

a second dielectric, antireflective base layer deposited over the first primer layer, the second base layer including a crystalline metal-contacting film-part which is a zinc oxide film, and a support part, wherein the support part is further comprised of a first layer of a zinc oxide film in contact with the first primer layer and a second layer of a zinc stannate film in contact with the crystalline metal-contacting film part;

a second metallic reflective layer deposited over the crystalline metal-contacting film-part of the second base layer;

a second primer layer deposited over the second metallic reflective film; and

a dielectric, antireflective mechanical durability enhancing layer deposited over the second primer layer, wherein the mechanical durability enhancing layer includes at least two sublayers, wherein a first sublayer deposited over the second primer layer includes an oxide of zinc and a second sublayer deposited over the first sublayer includes an oxide of zinc and tin.

15. The coated article of claim 14 further comprising a protective overcoat layer deposited over the mechanical durability enhancing layer.

16. The coated article of claim 15 wherein said first base layer is in contact with said substrate, said first metallic reflective layer is in contact with said first base layer, said first primer layer is in contact with said first metallic reflective layer, said second base layer is in contact with said first primer layer, said second metallic reflective layer is in contact with said second base layer, said second primer layer is in contact with said second metallic reflective layer, said mechanical durability enhancing layer is in contact with said second primer layer and said protective overcoat layer is in contact with said mechanical durability enhancing layer.

17. The coated article of claim 14 wherein the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin.

18. The coated article of claim 15 wherein the first base layer further comprises a crystalline metal-contacting film-part and a support part where the support part is in contact with the substrate and where the support part is comprised of a material other than the crystalline metal-contacting film-part.

19. The coated article of claim 18 wherein the transparent, nonmetallic substrate is glass, the support part of the first base layer is a zinc stannate film, the crystalline metal-contacting film-part of the first base layer is a zinc oxide film;

the first metallic reflective layer is a silver film, the first primer layer is deposited as titanium metal, the second metallic reflective layer is a silver film, the second primer layer is deposited as titanium metal, the mechanical durability enhancing layer includes four sublayers including a first sublayer which includes zinc oxide, having deposited thereover a second sublayer including an oxide of zinc and tin, having deposited thereover a third sublayer including zinc oxide, having deposited thereover a fourth sublayer including an oxide of zinc and tin, and the protective overcoat layer is a titanium oxide film.