Room temperature curable organopolysiloxane composition

• US 5,945,466 A
• Filed: 05/21/1997
• Issued: 08/31/1999
• Est. Priority Date: 05/21/1996
• Status: Expired due to Fees

• Current Assignee: Shin-Etsu Chemical Company Limited
• Original Assignee: Shin-Etsu Chemical Company Limited
• Inventors: Sugahara, Hideki, Ikeno, Masayuki
• Primary Examiner(s): Dawson, Robert
• Assistant Examiner(s): LU, C CAIXIA
• Application Number:
  US08/861,219
• Time in Patent Office: 832 Days
• Field of Search: 523/109, 524/779, 524/451, 524/495, 524/848
• US Class Current: 523/109
• CPC Class Codes: A61K 6/90 Compositions for taking dental impressions
• CPC Class Codes: C08K 3/34 Silicon-containing compounds
• CPC Class Codes: C08K 5/01 Hydrocarbons C08K5/0091 takes precedence
• CPC Class Codes: C08L 83/04 Polysiloxanes

Abstract

A room temperature curable organopolysiloxane composition including: (A) 100 parts by weight of a diorganopolysiloxane represented by the general formula (1):

HO Si(R.sup.1).sub.2 O!.sub.n H                            (1)

wherein R¹ represents a substituted or unsubstituted monovalent hydrocarbon group, and n is an integer of 15 or more;

(B) from 0.1 part by weight to 20 parts by weight of an organosilane, or a partially hydrolyzed product thereof, represented by the general formula (2):

(R.sup.2).sub.m S(OR.sup.2).sub.4-m                        (2)

wherein R² '"'"'s each independently represent a substituted or unsubstituted monovalent hydrocarbon group, and m is 0, 1 or 2;

(C) from 0.01 part by weight to 10 parts by weight of a curing catalyst;

(D) from 20 parts by weight to 600 parts by weight of a magnesium silicate; and

(E) from 5 parts by weight to 80 parts by weight of a paraffin type aliphatic hydrocarbon which is liquid or semi-solid at room temperature. This composition can be rapidly cured, even after a long-term storage.

Claims

1. A room temperature curable organopolysiloxane composition comprising;

(A) 100 parts by weight of a diorganopolysiloxane represented by the general formula (1);

space="preserve" listing-type="equation">HO Si(R.sup.1).sub.2 O!.sub.m H (1)

wherein R¹ represents a substituted or unsubstituted monovalent hydrocarbon group, and n is an integer of 15 or more;

(B) from 0.1 part by weight to 20 parts by weight of an organosilane, or a partially hydrolyzed product thereof, represented by the general formula (2);

space="preserve" listing-type="equation">(R.sup.2).sub.m Si(OR.sup.2).sub.4-m (

     2)

wherein R² '"'"'s each independently represent a substituted or unsubstituted monovalent hydrocarbon group, and m is 0, 1 or 2;

(C) from 0.01 part by weight to 10 parts by weight of a curing catalyst;

(D) from 20 parts by weight to 600 parts by weight of a magnesium silicate; and

(E) from 5 parts by weight to 80 parts by weight of a paraffin type aliphatic hydrocarbon which is liquid or semi-solid at room temperature.

2. The composition of claim 1, wherein in the general formula (1) representing the component (A), the R¹ each represent unsubstituted or substituted hydrocarbon groups having 1 to 12 carbon atoms but having no aliphatic unsaturated bonds.

3. The composition of claim 1, wherein the R¹ each represents alkyl groups, cycloalkyl groups, alkenyl groups, aryl groups, aralkyl groups, or corresponding substituted groups in which at least one of the hydrogen atoms possessed by these hydrocarbon groups has been substituted by a halogen atom(s) or a cyano group(s).

4. The composition of claim 1, wherein the R¹ is each a methyl group, a phenyl group or trifluoropropyl group.

5. The composition of claim 1, wherein n in the general formula (1) represents an integer of 15 to 2,000.

6. The composition of claim 1, wherein in the general formula (2) R² each represent unsubstituted or substituted hydrocarbon groups having 1 to 12 carbon atoms but having no aliphatic unsaturated bonds.

7. The composition of claim 1, wherein the organosilane of the component (B) is a tetraalkoxysilane, an organotrialkoxysilane, an alkylsilicate, a partially hydrolyzed product of these, or a mixture of two or more of the compounds.

8. The composition of claim 1, wherein the organosilane of the component (B) is present in an amount of from 0.1 to 20 parts by weight per 100 parts by weight of the component (A).

9. The composition of claim 1, wherein the curing catalyst of the component (C) is an organic metal compound containing tin, titanium, zirconium, iron, lead, zinc, cobalt, manganese or aluminum as a metallic element.

10. The composition of claim 9, wherein the curing catalyst is selected from dibutyltin dilaurate or dioctyltin dilaurate.

11. The composition of claim 1, wherein the component (C) curing catalyst is present in an amount of from 0.01 to 10 parts by weight per 100 parts by weight of the component (A).

12. The composition of claim 1, wherein the component (D) is magnesium tetrasilicate or hydrous magnesium silicate.

13. The composition of claim 1, wherein the magnesium silicate has an average particle diameter of from 0.1 to 50 μ

m.

14. The composition of claim 1, wherein the magnesium silicate of the component (D) is present in an amount of from 20 to 600 parts by weight per 100 parts by weight of the component (A).

15. The composition of claim 1, wherein the paraffin aliphatic hydrocarbon of the component (E) has 25 to 350 carbon atoms and containing substantially no lower hydrocarbon having not more than 18 carbon atoms.

16. The composition of claim 1, wherein the component (E) is present in an amount of from 5 to 80 parts by weight per 100 parts by weight of the component (A).

17. A impression material for molding the shape inside the hole of an ear, comprised of the composition as defined in claim 1.

18. A dental impression material for preparing the impression of a tooth or teeth, comprised of the composition as defined in claim 1.