Extruder glass-melter process for vitrification of nuclear and other toxic wastes

• US 5,947,887 A
• Filed: 04/01/1998
• Issued: 09/07/1999
• Est. Priority Date: 02/21/1996
• Status: Expired due to Fees

• Current Assignee: Extruder Vitrification Group LLC
• Original Assignee: Extruder Vitrification Group LLC
• Inventors: Wolf, David, Sembira, Asher N., White, Donald H.
• Primary Examiner(s): Taylor, Dennis L.
• Application Number:
  US09/053,340
• Time in Patent Office: 524 Days
• Field of Search: 588/252, 588/256, 588/257, 405/128, 405/131, 252/628, 252/629, 65/134.8, 65/27, 65/134.6
• US Class Current: 588/11
• CPC Class Codes: A62D 2101/08 Toxic combustion residues, e.g. toxic substances contained in fly ash from waste incineration
• CPC Class Codes: A62D 2101/43 containing heavy metals, in the bonded or free state
• CPC Class Codes: A62D 2203/10 Apparatus specially adapted for treating harmful chemical agents; Details thereof
• CPC Class Codes: A62D 3/33 by chemical fixing the harmful substance, e.g. by chelation or complexation
• CPC Class Codes: B09B 3/29 involving a melting or softening step
• CPC Class Codes: C03B 3/02 combined with preheating, premelting or pretreating the glass-making ingredients, pellets or cullet
• CPC Class Codes: C03B 5/00 Melting in furnaces; Furnaces so far as specially adapted for glass manufacture
• CPC Class Codes: C03B 5/005 of glass-forming waste materials disposal or transformation of solid waste in general B09B; treatment of radioactive waste G21F9/00
• CPC Class Codes: C03B 7/096 for heating
• CPC Class Codes: C03C 1/002 Use of waste materials, e.g. slags
• CPC Class Codes: G21F 9/305 Glass or glass like matrix C03B5/005 takes precedence; compositional aspects C03C
• CPC Class Codes: Y02P 40/50 Glass production, e.g. reusing waste heat during processing or shaping

Abstract

A toxic waste and glass frit are fed into an extruder having a helical screw. The glass frit, as well as any glassy material and glass-forming component in the waste, are melted in the extruder as the screw transports the waste and the frit through the extruder. The screw further mixes the waste and the frit and homogenizes the resulting mixture. The extruder is designed to generate high shear rates and high internal friction and at least a portion of the heat for melting is produced by such friction. A vitrified mass of the toxic waste is discharged from the extruder. The vitrified mass can be stored as is or can be pelletized and/or encapsulated.

Claims

1. A continuous method for vitrifying waste material comprising the steps of:

(a) introducing the waste material and a vitrification constituent selected from the group consisting of glass and glass formers into an extruder;

(b) conveying the waste material and the vitrification constituent through the extruder applying shear rates and pressures sufficiently high to cause melting of the vitrification constituent while maintaining a maximum temperature in the extruder below 1,050°

C., thereby producing a vitrified waste product; and

(c) removing the vitrified waste product from the extruder;

wherein all steps are carried out on a substantially continuous basis.

2. The method of claim 1, further comprising the step of homogenizing the vitrified waste product.

3. The method of claim 2, wherein the homogenizing step is performed substantially entirely in the extruder.

4. The method of claim 2, further comprising the step of transferring the vitrified waste product from the extruder to a holding vessel and further homogenizing the vitrified waste product in the vessel.

5. The method of claim 1, further comprising the step of providing heat to the waste material and the vitrification constituent in the extruder by direct electric heating or by induction, radiant or other indirect heating.

6. The method of claim 1, wherein step (b) is carried out maintaining a maximum temperature in the extruder between about 900 and 1050 degrees Centigrade.

7. The method of claim 1, further comprising the step of combining the waste material and the vitrification constituent prior to step (a).

8. The method of claim 1, further comprising the step of combining the waste material and the vitrification constituent while carrying out step (a).

9. The method of claim 1, further comprising the step of encapsulating the vitrified waste product following step (c).

10. The method of claim 9, wherein said vitrified waste product is encapsulated using a substance selected from the group consisting of glass and lead, or mixtures thereof.

11. The method of claim 10, further comprising the steps of admitting a mass selected from the group consisting of glass and glass formers into additional extruder means, and melting said mass in said additional extruder means to form a glass melt;

and wherein the encapsulating step is performed using said glass melt.

12. The method of claim 10, further comprising the steps of admitting said vitrified waste product into a container, and melting a mass of lead to form a lead melt;

and wherein the encapsulating step comprises introducing said lead melt into said container.

13. The method of claim 1, wherein step (a) comprises admitting the waste material into a first zone of the extruder and admitting the vitrification constituent into a second zone of the extruder;

and wherein step (b) further comprises the steps of removing moisture from the waste material in said first zone, discharging the moisture from the extruder, and combining the waste material and the vitrification constituent in said second zone following the moisture removing step.

14. The method of claim 13, further comprising the steps of generating at least one gas in the second zone of the extruder, and discharging said one gas from the extruder.

15. The method of claim 14, wherein said moisture is discharged from the extruder at a predetermined location of the first zone and said one gas is discharged from the extruder at a predetermined location of the second zone.

16. The method of claim 1, further comprising the step of pelletizing the vitrified waste product following step (c).

17. The method of claim 1, wherein said waste material is a toxic waste.

18. The method of claim 17, wherein said toxic waste comprises a radioactive waste.

19. The method of claim 1, wherein said vitrification constituent comprises frit.

20. The method of claim 2, wherein said vitrification constituent comprises a member of the group consisting of borosilicate glass and borosilicate glass frit.

21. The method of claim 1, wherein said step (b) is carried out with an extruder comprising a screw and screw channels less than one tenth the diameter of the screw.