Advanced engineering resin and wood fiber composite

• US 5,948,524 A
• Filed: 01/08/1996
• Issued: 09/07/1999
• Est. Priority Date: 01/08/1996
• Status: Expired due to Term

• Current Assignee: Andersen Corporation
• Original Assignee: Andersen Corporation
• Inventors: Deaner, Michael J., Seethamraju, Kasyap V.
• Primary Examiner(s): McCamish, Marion E.
• Assistant Examiner(s): GRAY, JILL M
• Application Number:
  US08/585,320
• Time in Patent Office: 1,338 Days
• Field of Search: 428/402, 428/407, 428/323, 428/373, 428/375, 428/361, 428/393, 428/326, 428/507, 428/510, 428/511, 521/13, 521/14, 521/16, 521/34, 521/551, 521/567, 521/908, 523/222
• US Class Current: 428/326
• CPC Class Codes: B29B 9/14 fibre-reinforced
• CPC Class Codes: B29K 2001/00 Use of cellulose, modified cellulose or cellulose derivatives, e.g. viscose, as moulding material
• CPC Class Codes: B29K 2001/12 Cellulose acetate
• CPC Class Codes: C08J 5/045 with vegetable or animal fibrous material
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2666/26 Natural polymers, natural resins or derivatives thereof according to C08L1/00 - C08L5/00, C08L89/00, C08L93/00, C08L97/00 or C08L99/00
• CPC Class Codes: Y10T 428/253 Cellulosic [e.g., wood, paper, cork, rayon, etc.]
• CPC Class Codes: Y10T 428/2904 Staple length fiber
• CPC Class Codes: Y10T 428/2907 with coating or impregnation
• CPC Class Codes: Y10T 428/2938 Coating on discrete and individual rods, strands or filaments
• CPC Class Codes: Y10T 428/2965 Cellulosic
• CPC Class Codes: Y10T 428/31591 Next to cellulosic
• CPC Class Codes: Y10T 428/31779 Next to cellulosic
• CPC Class Codes: Y10T 428/31783 Paper or wood
• CPC Class Codes: Y10T 428/3188 Next to cellulosic

Abstract

The invention relates to a composition including an engineering resin and wood fiber composite that can be used in the form of a linear extrudate or thermoplastic pellet used to manufacture structural members. The resin/wood fiber composite structural members can be manufactured in an extrusion process or an injection molding process as a linear extrudate or pellet that can have a cross-section of any arbitrary shape, or can be a regular geometric shape and have a volume of at least about 12 mm³. Preferably the pellet is a right cylindrical pellet having a minimum radius of about 1.5 mm and a minimum length of 1 mm weighing at least 14 mg. The invention also relates to the environmentally sensitive recycle of waste streams. The resin/wood fiber composite can contain an intentional recycle of a waste stream including polymer flakes, polymer particles, or wood fiber as well as adhesives, paint, or preservatives. The initial mixing step before extrusion of the composite material insures substantial mixing and melt contact between molten resin and wood fiber. The extruded pellet includes a useful proportion of resin, wood fiber and water. During the extrusion, water is removed intentionally to dry the material to a maximum water content of less than about 10 wt % based on the pellet weight. The pellet is then introduced into an extruder or injection molding apparatus wherein the composite pellet material is shaped into a useful cross-section.

Claims

1. A resin and fiber composite thermoplastic pellet, capable of formation into a structural member, which pellet comprises a thermoplastic extrudate having a width of about 0.1 to 5 millimeters and a length of about 0.1 to 10 millimeters, the thermoplastic extrudate consisting essentially of:

(a) a continuous phase comprising a thermoplastic engineering resin, comprising repeating monomer units substantially free of vinyl chloride, the resin having a surface energy greater than 40 dynes/cm, a processing temperature less than 250°

C., and a moisture sensitivity such that the resin does not have a substantial reduction in melt index or molecular weight during processing in the presence of water; and

(b) an effective amount of wood fiber having a minimum dimension of about 0.1 millimeter and a minimum aspect ratio of about 1.5 to provide structural properties to the composite;

wherein the resin and wood fiber are mixed at elevated temperatures and pressure such that an intimate admixture is formed, the wood fibers are dispersed in the a continuous thermoplastic phase, the pellet is a recyclable thermoplastic and the composite has a Young'"'"'s modulus of at least 500,000 psi.

2. The composite of claim 1 wherein the engineering resin comprises a condensation polymer.

3. The composite of claim 2 wherein the condensation polymer comprises a polyphenylene oxide.

4. The composite of claim 2 wherein the condensation polymer comprises a polybutylene terephthalate.

5. The composite of claim 2 wherein the condensation polymer comprises a polyethylene naphthalate.

6. The composite of claim 2 wherein the condensation polymer comprises cellulose acetate butyrate.

7. The composite of claim 2 wherein the condensation polymer has a melt flow index of about 1 to 10 gm/10 min.

8. The composite of claim 7 wherein the pellet comprises about 0.01 to 7% water.

9. The composite of claim 2 wherein the resin comprises a thermoplastic polyurethane.

10. The composite of claim 1 wherein the engineering resin comprises a vinyl polymer.

11. The composite of claim 10 wherein the vinyl polymer comprises a copolymer comprising styrene.

12. The composite of claim 11 wherein the copolymer comprises acrylonitride and styrene.

13. The composite of claim 11 wherein the copolymer comprises acrylonitrile, butadiene and styrene.

14. The composite of claim 10 wherein the vinyl polymer comprises an acrylic polymer having repeating units derived from a monomer selected from the group consisting of acrylic acid, methacrylic acid, methylacrylate, methylmethacrylate, acrylamide and mixtures thereof.

15. The composite of claim 10 wherein the vinyl polymer has a processing temperature less than 235°

C. and a melt flow index of about 0.1 to 20 gm/10 min.

16. The composite of claim 10 wherein the polymer is a polyacetal with a melt flow of about 0.001 to 0.1 gm/10 min.

17. The composite of claim 1 wherein the wood fiber comprises a by-product of milling or sawing wooden members and the pellet comprises less than about 10 wt % water.

18. The composite of claim 1 wherein the composite additionally comprises an agent that promotes the compatibility of the engineering resin and the wood fiber.

19. The composite of claim 1 wherein the wood fiber has a fiber length of about 0.1 to 2 millimeters and an aspect ratio of about 2 to 7.

20. The composite of claim 1 wherein the pellet comprises a right circular cylinder having a radius of about 0.1 to 5 mm and a length of about 0.1 to 10 mm.

21. The composite of claim 1 wherein the polymer comprises an additive selected from a lubricant, an antioxidant, a pigment, a thermal stabilizer, or a mixture thereof.

22. The composite of claim 1 wherein the aspect ratio of said wood fiber is at least about 1.8.

23. The composite of claim 1 wherein the composite has a Young'"'"'s modulus of at least 600,000 psi.

24. The composite of claim 1 wherein the composite has a Young'"'"'s modulus of at least 1×

10⁶ psi.

25. The composite of claim 1 wherein the resin comprises a polyvinylidene fluoride.

26. The composite of claim 1 wherein the resin comprises a polymer alloy.

27. The composite of claim 26 wherein the polymer alloy comprises a polycarbonate resin and an acrylonitrile-butadiene-styrene resin.

28. A resin and fiber thermoplastic composite, capable of formation into a structural member, which composite comprises a thermoplastic engineering resin and fiber, the composite consisting essentially of:

(a) a continuous phase of a thermoplastic engineering resin, comprising repeating monomer units substantially free of vinyl chloride, the resin having a surface energy greater than 40 dynes/cm, a processing temperature less than 250°

C., and a moisture sensitivity such that the resin does not have a substantial reduction in either melt index or molecular weight during processing in the presence of water; and

(b) an effective amount of wood fiber having a minimum dimension of about 0.1 millimeter and a minimum aspect ratio of about 1.5 to provide structural properties to the composite;

wherein the resin and wood fiber are mixed at elevated temperatures and pressure such that an intimate admixture is formed, the wood fibers disperse throughout a continuous thermoplastic resin phase, the pellet is recyclable and the composite has a Young'"'"'s modulus of at least 500,000 psi.

29. The composite of claim 28 wherein the engineering resin comprises a condensation polymer.

30. The composite of claim 29 wherein the condensation polymer comprises a polyphenylene oxide.

31. The composite of claim 29 wherein the condensation polymer comprises a polybutylene terephthalate.

32. The composite of claim 29 wherein the condensation polymer comprises a polyethylene naphthalate.

33. The composite of claim 29 wherein the condensation polymer comprises a cellulose acetate butyrate.

34. The composite of claim 29 wherein the condensation polymer has a melt flow index of about 1 to 10 gm/10 min.

35. The composite of claim 28 wherein the engineering resin comprises a vinyl polymer.

36. The composite of claim 35 wherein the vinyl polymer comprises a copolymer comprising styrene.

37. The composite of claim 36 wherein the copolymer comprises acrylonitrile and styrene.

38. The composite of claim 36 wherein the copolymer comprises acrylonitrile, butadiene and styrene.

39. The composite of claim 35 wherein the vinyl polymer has a processing temperature less than 236°

C. and a melt flow index of about 0.1 to 20 gm/10 min.

40. The composite of claim 28 wherein the engineering resin comprises an acrylic polymer having repeating units derived from a monomer selected from the group consisting of acrylic acid, methacrylic acid, methylacrylate, methylmethacrylate, acrylamide and mixtures thereof.

41. The composite of claim 28 wherein the wood fiber comprises a by-product of milling or sawing wooden members and the pellet comprise less than about 10 wt % water.

42. The composite of claim 28 wherein the composite additionally comprises an agent that promotes the compatibility of the engineering resin and the wood fiber.

43. The composite of claim 28 wherein the wood fiber has a fiber length of about 0.1 to 2 millimeters and an aspect ratio of about 2 to 7.

44. The composite of claim 28 wherein the polymer is a polyacetal with a melt flow of about 0.001 to 0.1 gm/10 min.

45. The composite of claim 28 wherein the pellet comprises about 0.01 to 7% water.

46. The composite of claim 28 wherein the resin additionally comprises an additive selected from a lubricant, an antioxidant, a pigment, a thermal stabilizer, or a mixture thereof.

47. The composite of claim 28 wherein the aspect ratio of said wood fiber is at least about 1.8.

48. The composite of claim 28 wherein the composite has a Young'"'"'s modulus of at least 600,000 psi.

49. The composite of claim 28 wherein the composite has a Young'"'"'s modulus of at least 1×

10⁶ psi.

50. The composite of claim 28 wherein the resin comprises a polyvinylidene chloride.

51. The composite of claim 28 wherein the resin comprises a thermoplastic polyurethane.