High energy density boride batteries

• US 5,948,558 A
• Filed: 03/27/1997
• Issued: 09/07/1999
• Est. Priority Date: 03/27/1997
• Status: Expired due to Fees

• Current Assignee: Millennium Cell Inc.
• Original Assignee: GP Strategies Corporation (Learning Technologies Group Plc)
• Inventors: Amendola, Steven
• Primary Examiner(s): KALAFUT, STEPHEN J
• Application Number:
  US08/829,497
• Time in Patent Office: 894 Days
• Field of Search: 429/27, 429/50, 429/101, 429/199, 429/218, 429/218.1, 423/297, 423/298
• US Class Current: 429/50
• CPC Class Codes: H01M 12/04 composed of a half-cell of the fuel-cell type and of a half-cell of the primary-cell type
• CPC Class Codes: H01M 4/00 Electrodes
• CPC Class Codes: H01M 4/38 of elements or alloys
• CPC Class Codes: H01M 4/388 Halogens
• CPC Class Codes: H01M 4/582 Halogenides
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

Borides generally can produce a cell with a high energy density. High power densities are also achievable using borides that are reasonably good conductors of electricity. High density is important to achieve high energy density. Another important factor is lower molecular weight per available electron. The borides generally provide a favorable balance of these factors compared to a number of other materials, such as lithium or zinc. Individual borides have other important characteristics. Titanium diboride is safe.

Claims

1. A battery having an anode and a cathode in electrical contact, the anode comprising an electrochemical storage medium,

said electrochemical storage medium comprising at least one reduced composition which is oxidizable to an oxidized composition in a reaction which yields an electric current, said reduced composition comprising boron or a boron-containing compound, said oxidized composition comprising a boron-containing compound in which the boron is oxidized relative to its oxidation state in said reduced composition.

5. The battery of any one of claims 1, 2, 3, or 4 in which the reduced composition comprises a boride.

6. The battery of any one of claims 1, 2, 3, or 4 in which the reduced composition contains elemental boron.

8. The battery of any one of claims 1, 2, 3, or 4 in which the oxidized composition comprises a borate or polyborate.

9. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium is in an aqueous system.

10. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium is in a non aqueous medium.

11. The battery of any one of claims 1, 2, 3, or 4 in which the oxidized composition comprises a boron halide or a boron oxyhalide.

12. The battery of any one of claims 1, 2, 3, or 4 comprising a conductive electrolyte.

13. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium further comprises a borohydride in addition to said boron-containing compound.

14. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium further comprises a metallic boride compound.

15. The battery of claim 11 in which the metallic boride compound is FeB or NiB₂.

16. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium further comprises a conductivity enhancer which itself is oxidized to provide addition current during oxidation of said reduced composition.

17. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium further comprises graphite.

18. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium further comprises an inert conductivity enhancer.

19. The battery of one of claims 1, 2, 3, or 4 in which the storage medium comprises titanium diboride.

20. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium comprises vanadium diboride.

21. The battery of any one of claims 1, 2, 3, or 4 in the storage medium comprises an aluminum boride.

22. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium comprises a compound selected from the group listed in table 1.

23. The battery of any one of claims 1, 2, 3, or 4 in which the oxidized composition comprises a metal oxide and a borate.

24. The battery of any one of claims 1, 2, 3, or 4 in which the oxidized composition contains a combination of corresponding metal oxides, halides and oxyhalides.

25. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium has a Ph above 8.5.

26. The battery of any one of claims 1, 2, 3, or 4 in which the storage medium has a pH above 11.0.

27. A battery according to any one of claims 1, 2, 3, or 4 in which the reduced composition is a material that is capable of being oxidized by contact with oxygen.

28. A battery according to claim 27 in which the reduced composition is oxidized by exposure to molecular oxygen.

29. A battery according to claim 8 in which the reduced composition is oxidized by exposure to air.

30. A battery according to any one of claims 1, 2, 3, or 4 in which the cathode comprises an oxygen-containing compound.

31. A battery according to claim 30 in which the oxidizing compound is selected from ferrates, MnO₂, CrO₃, KMnO₄, LiCoO₂, NiOOH, peroxides, perhalates, perchlorate, chlorates, bromates, perbromates, iodates, periodates, hypochlorites chlorites.

32. A battery according to any one of claims 1, 2, 3, or 4 in which the cathode comprises a non-oxygen containing oxidizing compound.

33. A battery according to claim 32 in which the non-oxygen containing compound comprises a metal which can be reduced to a lower valence.

34. A battery according to claim 33 in which the non-oxygen compound is a metal-halide in which the metal can be reduced to a lower valence.

35. A battery according to claim 33 in which the non-oxygen compound is an interhalogen.

36. A method of generating a current by contacting a load to the battery of any one of claims 1, 2, 3, or 4.

2. A battery having an anode and a cathode in electrical contact, the anode comprising an electrochemical storage medium,

said storage medium comprising at least one reduced composition which is capable of being oxidized to an oxidized composition in a reaction which yields an electric current, said reduced composition comprising boron or a boron-containing compound,

said cathode comprising a material that is oxidized by contact with oxygen.

7. The battery of claim 2 in which the boride is conductive.

3. A battery having an anode and a cathode in electrical contact, the anode comprising an electrochemical storage medium,

said storage medium comprising at least one reduced composition which is oxidizable to an oxidized composition in a reaction which yields an electric current, said reduced composition comprising boron or a boron-containing compound,

said cathode comprising a metal-halide in which the metal can be reduced to a lower valence.

4. A battery having an anode and a cathode in electrical contact, the anode comprising an electrochemical storage medium,

said storage medium comprising at least one reduced composition which is oxidizable to an oxidized composition in a reaction which yields an electric current, said reduced composition comprising boron or a boron-containing compound,

said cathode comprising an interhalogen.