Optical state-of-charge monitor for batteries

• US 5,949,219 A
• Filed: 07/24/1998
• Issued: 09/07/1999
• Est. Priority Date: 07/24/1998
• Status: Expired due to Term

• Current Assignee: United States Department of Energy (Government of the United States of America)
• Original Assignee: United States Department of Energy (Government of the United States of America)
• Inventors: Weiss, Jonathan D.
• Primary Examiner(s): Wong, Peter S.
• Assistant Examiner(s): SHIN, KYUNG E
• Application Number:
  US09/121,975
• Time in Patent Office: 410 Days
• Field of Search: 320/136, 320/DIG. 21, 320/DIG. 25, 429/90-93, 324/427, 356/135
• US Class Current: 320/136
• CPC Class Codes: G01N 21/31 Investigating relative effect of material at wavelengths characteristic of specific elements or molecules, e.g. atomic absorption spectrometry G01N21/72 takes precedence
• CPC Class Codes: G01R 31/379 for lead-acid batteries
• CPC Class Codes: H01M 10/0525 Rocking-chair batteries, i.e. batteries with lithium insertion or intercalation in both electrodes; Lithium-ion batteries
• CPC Class Codes: H01M 10/06 Lead-acid accumulators semi-lead accumulators H01M10/20
• CPC Class Codes: H01M 10/48 Accumulators combined with arrangements for measuring, testing or indicating the condition of cells, e.g. the level or density of the electrolyte constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: H01M 10/488 Cells or batteries combined with indicating means for external visualization of the condition, e.g. by change of colour or of light density
• CPC Class Codes: Y02E 60/10 Energy storage using batteries
• CPC Class Codes: Y10S 320/21 State of charge of battery

Abstract

A method and apparatus for determining the instantaneous state-of-charge of a battery in which change in composition with discharge manifests itself as a change in optical absorption. In a lead-acid battery, the sensor comprises a fiber optic system with an absorption cell or, alternatively, an optical fiber woven into an absorbed-glass-mat battery. In a lithium-ion battery, the sensor comprises fiber optics for introducing light into the anode to monitor absorption when lithium ions are introduced.

Claims

1. A system for determining the state-of-charge of a battery having a conductor that changes in chemical composition with discharge, comprising:

a means for emitting light at a pre-determined wavelength and a pre-determined pathlength into the conductor, wherein said predetermined wavelength is chosen from a plot of the absorption coefficient of the conductor versus a plurality of wavelengths at a chosen limit of the chemical composition of the conductor and said pre-determined pathlength is chosen to correspond to said pre-determined wavelength and the transparency of the conductor;

a means for optically interrogating the conductor to obtain optical absorption at said pre-determined wavelength, the optical absorption varying with the changes in chemical composition in the conductor with discharge;

a means for detecting the varying optical absorption in the conductor, said detecting means being operably connected to said optically interrogating means;

a means for converting the detected optical absorption to state-of-charge information capable of being read by a user of the battery; and

a means for displaying the state-of-charge information to the user of the battery.

2. The system of claim 1, wherein the battery is a lithium-ion battery.

3. The system of claim 1, wherein the battery is a lead-acid battery.

4. The system of claim 3, wherein said pre-determined wavelength is 1.45 μ

m and said pre-determined pathlength is 1 mm.

5. The system of claim 3, wherein said pre-determined wavelength is 0.97 μ

m and said pre-determined pathlength is 20 mm.

6. The system of claim 3, wherein said pre-determined wavelength is 1.20 μ

m and said pre-determined pathlength is 10 mm.

7. The system of claim 1,

(a) wherein said optically interrogating means comprises:

a means for transmitting light from said light-emitting means through the conductor, thereby generating an optical signal that changes in optical power concurrently and proportionally with changes in the optical absorption in the conductor at said pre-determined wavelength, the changes, in optical absorption in the conductor occurring with battery discharge,

a means for extracting the changing optical signal as output from the conductor, and

a means for receiving the signal output from the conductor, said receiving means being operably connected to said detecting means, and for communicating said signal output to said detecting means; and

(b) wherein said detecting means detects the optical power changes in the signal output.

8. The system of claim 7, wherein said optically interrogating means comprises a fiber optic means for transmitting the emitted light through the conductor and a fiber optic means for receiving the signal output from the conductor.

9. The system of claim 8, wherein said fiber optic transmitting means comprises at least one optical fiber and said fiber optic receiving means comprises a plurality of optical fibers.

10. The system of claim 8, wherein:

said fiber optic transmitting means and said fiber optic receiving means comprise a fiber optic bundle, said bundle comprising at least one central transmitting fiber for introducing emitted light into the conductor, at least six receiving fibers surrounding said central transmitting fiber for receiving the signal output from the conductor, a first end operably connected to said detecting means, and a second end, and said second end having a polished face for preventing light from scattering randomly at an interface between said fiber optic means and the conductor.

11. The system of claim 8, wherein said fiber optic transmitting means and said fiber optic receiving means comprise a single unclad optical fiber, the conductor is contained by a material that forms a cladding surrounding said optical fiber, and said fiber is woven into said cladding material.

12. The system of claim 11, wherein the battery is an absorbed-glass-mat battery.

13. The system of claim 8, wherein said fiber optic transmitting means and said fiber optic receiving means comprise a single optical fiber having a means for splitting light emitted into the conductor from said light-emitting means into transmitted light and received light.

14. The system of claim 8, wherein said fiber optic transmitting means and said fiber optic receiving means comprise at least one optical fiber having an axis, an input end and an output end, and wherein said input end of said optical fiber is beveled and light from said emitting means is emitted into the conductor at a predetermined angle to the axis of said optical fiber.

15. The system of claim 7, wherein said extracting means comprises a reflecting means.

16. The system of claim 8, wherein said reflecting means comprises a reflecting surface, said reflecting surface shaped to maximize the reflected signal output returned to said receiving means.

17. The system of claim 7, wherein said extracting means comprises an interface between said optically interrogating means and the conductor, and the length of said optically interrogating means is chosen to maximize the signal output returned to said receiving means.

18. The system of claim 7, wherein said detecting means comprises a photodetector that receives the signal output from said receiving means and converts detected power changes therein to an electric current, said current changing in direct proportion to the optical power changes in the transmitted light.

19. The system of claim 1, wherein said converting means comprises a means for converting detected optical adsorption into a voltage signal, and a means for converting the voltage signal to state-of-charge information capable of being communicated to the user of the battery.

20. The system of claim 1, wherein said converting means comprises a means for mathematically adjusting the optical absorption information to provide directly proportional state-of-charge information.

21. The system of claim 1, further comprising a means for compensating for temperature-induced error in optical absorption obtained by said optically interrogating means.

22. The system of claim 21, wherein said means for compensating for temperature-induced error comprises a means for pre-determining a temperature dependence of absorption in the conductor, an electrical means for determining exact temperature of the conductor, and a means for combining the pre-determined temperature dependence with the exact temperature, and said means for converting further comprises a means for calculating an adjustment to correct for temperature induced errors in the detected absorption information at the chosen wavelength.

23. The system of claim 1, wherein

the conductor comprises at least one pair of electrodes, one of said pair being the cathode and the other being the anode, and

said optically interrogating means comprises a means for transmitting light through the anode, a means for extracting the transmitted light out of the anode, the transmitted light changing in optical power corresponding to variation in optical absorption in the conductor during transmission, a means for receiving the changing transmitted light and a means for communicating the optical power changes in the transmitted light to said detector.

24. The system of claim 1, wherein said means for optically interrogating the conductor to obtain optical absorption information comprises:

an absorption cell in operable association with said conductor, said cell having a housing comprising a first end, a second end and an interior reflecting surface located at said second end of said housing, said reflecting surface shaped to maximize the reflected signal output returned to said receiving means,

a fiber optic means for transmitting light into the conductor and for receiving reflected light from the conductor, said fiber optic means having a first end and a second end, said first end of said fiber optic means being operably attached to said light-emitting means and to said detecting means, and said second end of said fiber optic means being operably attached to said cell at at least one opening at said first end of said housing,

whereby said fiber optic means transmits light emitted by said light emitting means through the conductor, said light changing in optical power corresponding to changing optical absorption during transmission through the conductor, and said changing transmitted light is reflected by said interior reflecting surface back to said fiber optic means, thereby providing absorption information communicable to said detecting means.

25. The system of claim 24, wherein the conductor is an electrolyte, and said cell is inserted in the electrolyte and comprises at least two openings whereby at least a portion of the conductor flows through said cell.

26. The system of claim 25, wherein said cell comprises a third opening whereby emitted light from said light emitting means is transmitted into and out of the conductor.

27. The system of claim 26, wherein said third opening comprises a window.

28. A method for determining the state-of-charge of a battery having a conductor that changes in chemical composition with discharge, comprising the steps of:

choosing a wavelength from a plot of the absorption coefficient of the conductor versus a plurality of wavelengths;

choosing a pathlength to correspond to said pre-determined wavelength and the transparency of the conductor;

emitting light at the pre-determined wavelength and the pre-determined pathlength into the conductor;

optically interrogating the conductor to obtain changes in absorption in the conductor during discharge of the battery, the changes in absorption being manifested as changes in optical power in the light;

detecting the optical power changes;

converting the optical power changes to state-of-charge information communicable to a user of the battery; and

displaying the state-of-charge information to the user of the battery.

29. The method of claim 28, wherein the step of optically interrogating the conductor comprises the steps of:

(a) transmitting light through the conductor, whereby the optical power of the transmitted light changes corresponding to changes in optical absorption characteristics of the conductor proportional to changes in state-of-charge of the battery, and

(b) extracting the optical power changes out of the conductor as a changing electrical signal output.

30. The method of claim 28, wherein the battery is a lead-acid battery, the conductor is an aqueous electrolytic solution of sulfuric acid, and the step of optically interrogating the conductor to obtain changes in optical absorption comprises the step of measuring the decline in optical attenuation in the conductor at at least one characteristic absorption peak of pure water.

31. The method of claim 28, further comprising the step of compensating for errors in state-of-charge information resulting from temperature dependence of optical absorption at the predetermined wavelength.

32. The method of claim 31, wherein said temperature-compensating step comprises the steps of pre-determining a temperature dependence of absorption in the conductor, electrically measuring the actual temperature of the battery, mathematically combining said actual temperature with the pre-determined temperature, and said converting step further comprises the step of calculating an adjustment to correct for temperatureinduced variation in absorption at the pre-determined wavelength.

33. The method of claim 31, wherein said temperature-compensating step comprises the steps of obtaining optical absorption at at least two pre-determined wavelengths and said converting step further comprises the step of calculating an adjustment to correct for errors in the detected optical absorption at said at least two pre-determined wavelengths.

35. The method of claim 33, wherein said at least two pre-determined wavelengths are chosen to provide absorption coefficients with differing temperature correction, whereby at least one of said at least two wavelengths is temperature-dependent but independent of the concentration of the conductor, and the other of said at least two wavelengths is temperature-dependent and concentration-dependent, and

comprising the step of using said at least one temperature-dependent, concentration-independent wavelength as a temperature correction.

36. The method of claim 35, wherein said at least one temperature-dependent, concentration-independent wavlength is 1.08 μ

m.

37. The system of claim 28, wherein the step of converting the optical absorption information to state-of-charge information further comprises the steps of:

converting the optical power changes into a voltage signal,

converting the voltage signal to a state-of-charge information capable of being communicated to the user of the battery,

mathematically adjusting the voltage signal to provide directly proportional state-of-charge information.

34. The method of 33, wherein said at least two pre-determined wavelengths are chosen to provide absorption coefficients having the same additive temperature correction, and said calculating step further comprises the step of subtracting optical signals obtained at said two pre-determined wavelengths, thereby canceling the temperature dependence and providing a temperature-independent optical signal.