Method and apparatus for refueling an electrochemical power source

• US 5,952,117 A
• Filed: 05/22/1997
• Issued: 09/14/1999
• Est. Priority Date: 10/24/1996
• Status: Expired due to Term

• Current Assignee: ZincNyx Energy Solutions, Inc.
• Original Assignee: Metallic Power, Inc.
• Inventors: Gulino, Ronald, Wright, Kenneth A., Colborn, Jeffrey A.
• Primary Examiner(s): Nuzzolillo, Maria
• Assistant Examiner(s): Ruthkosky, Mark
• Application Number:
  US08/861,513
• Time in Patent Office: 845 Days
• Field of Search: 429/27, 429/49
• US Class Current: 429/404
• CPC Class Codes: H01M 50/77 with external circulating path
• CPC Class Codes: H01M 6/5077 Regeneration of reactants or electrolyte
• CPC Class Codes: H01M 8/04186 of liquid-charged or electrolyte-charged reactants
• CPC Class Codes: H01M 8/225 Fuel cells in which the fuel is based on materials comprising particulate active material in the form of a suspension, a dispersion, a fluidised bed or a paste
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A transportable container for refueling a refuelable battery includes a case, an electrolyte reservoir within the case, a first valve connected to the electrolyte reservoir, a fuel compartment within the case, a second valve connected to the fuel compartment, and a conduit connected to the electrolyte reservoir and the fuel compartment. When the transportable container is attached to a refuelable battery, a closed flow circuit for the circulation of electrolyte is defined. Fuel particles and electrolyte are fed from the transportable container into the refuelable battery. When the refuelable battery is discharged, the transportable container, containing spent electrolyte and reaction products, is detached from the refuelable battery.

Claims

1. A transportable container for refueling a refuelable battery having an electrochemical cell employing a particulate electrode, comprising:

(a) a case;

(b) an electrolyte reservoir, within the case, capable of holding a volume of electrolyte solution;

(c) a first valve, in fluid connection with the electrolyte reservoir, which passes through the case and is capable of connecting to a refuelable battery;

(d) a fuel compartment, within the case, capable of holding electrochemically active fuel particles and electrolyte solution;

(e) a second valve, in fluid connection with the fuel compartment, which passes through the case and is capable of connecting to a refuelable battery; and

(f) a conduit, in fluid connection with the electrolyte reservoir and the fuel compartment, such that the transportable container and a refuelable battery define a closed flow circuit for the circulation of electrolyte solution through the transportable container and the refuelable battery while the transportable container is connected to a refuelable battery during operation of the refuelable battery.

2. The transportable container of claim 1, further comprising a filter capable of preventing the passage of fuel particles between the fuel compartment and the electrolyte reservoir.

3. The transportable container of claim 1, the conduit being sufficiently narrow to prevent the passage of fuel particles, yet capable of allowing passage of electrolyte solution.

4. The transportable container of claim 1, the first valve and the second valve being comprised of flexible channels, the transportable container further comprising a sealing member, movably attached to the transportable container, which is capable of pinching closed the flexible channels.

5. The transportable container of claim 1, further comprising a cover capable of sealing the first valve and the second valve when the transportable container is not connected to a refuelable battery.

6. The transportable container of claim 5, the cover being attached to the case.

7. The transportable container of claim 1, the case being liquid sealed.

8. A transportable container for refueling a refuelable battery having an electrochemical cell employing a particulate electrode, comprising:

(a) a case;

(b) an electrolyte reservoir, within the case, capable of holding a volume of electrolyte solution;

(c) a first valve, comprised of a first flexible channel, in fluid connection with the electrolyte reservoir, which passes through the case and is capable of connecting to a refuelable battery;

(d) a fuel compartment, within the case, capable of holding electrochemically active fuel particles and electrolyte solution;

(e) a second valve, comprised of a second flexible channel, in fluid connection with the fuel compartment, which passes through the case and is capable of connecting to a refuelable battery;

(f) a conduit, in fluid connection with the electrolyte reservoir and the fuel compartment, such that the transportable container and a refuelable battery define a closed flow circuit for the circulation of electrolyte solution through the transportable container and the refuelable battery while the transportable container is connected to a refuelable battery during operation of the refuelable battery;

(g) a sealing member, movably attached to the transportable container and capable of pinching closed the first and second flexible channels; and

(h) a cover capable of sealing the first valve and the second valve when the transportable container is not connected to a refuelable battery.

9. The transportable container of claim 8, further comprising a filter capable of preventing the passage of fuel particles between the fuel compartment and the electrolyte reservoir.

10. The transportable container of claim 8, the conduit being sufficiently narrow to prevent the passage of fuel particles, yet capable of allowing passage of electrolyte solution.

11. A transportable container for refueling a refuelable battery having multiple electrochemical cells employing particulate electrodes, comprising:

(a) a case;

(b) one or more fuel compartments, within the case, capable of holding electrochemically active fuel particles and electrolyte solution;

(c) a plurality of valves, in fluid connection with the one or more fuel compartments, which pass through the case and are capable of connecting to a refuelable battery; and

(d) one or more conduits connecting the one or more fuel compartments to each other, such that the transportable container and a refuelable battery define a closed flow circuit for the circulation of electrolyte solution through the transportable container and the refuelable battery while the transportable container is connected to a refuelable battery during operation of the refuelable battery.

12. The transportable container of claim 11, further comprising an electrolyte reservoir, within the case and connected to the one or more fuel compartments, and a second valve, in fluid connection with the electrolyte reservoir and which passes through the case and is capable of connecting to a refuelable battery.

13. The transportable container of claim 11, the one or more conduits being capable of substantially minimizing electrical conductivity between each of the one or more fuel compartments through the conduits when the transportable container contains electrolyte solution.

14. The transportable container of claim 13, the one or more conduits being sufficiently narrow and relatively long to substantially minimize electrical conductivity between each of the one or more fuel compartments through the conduits when the transportable container contains electrolyte solution.

15. The transportable container of claim 11, further comprising one or more filters capable of preventing the passage of fuel particles between each of the one or more fuel compartments.

16. The transportable container of claim 11, the one or more conduits being sufficiently narrow to prevent the passage of fuel particles, yet capable of allowing passage of electrolyte solution.

17. The transportable container of claim 12, the plurality of valves and the second valve comprising flexible channels, the transportable container further comprising a sealing member, movably attached to the transportable container, which is capable of pinching closed the flexible channels.

18. The transportable container of claim 12, the plurality of valves and the second valve comprising openings through the case of the transportable container, and a thin band, movably attached to the transportable container, which is capable of moving between an open and closed position to unseal and seal, respectively, the openings through the case.

19. The transportable container of claim 11, further comprising a cover capable of sealing the plurality of valves when the transportable container is not connected to a refuelable battery.

20. The transportable container of claim 19, the cover being attached to the case of the transportable container.

21. The transportable container of claim 11, the case being liquid sealed.

22. The transportable container of claim 11, the one or more fuel compartments being connected in parallel for the flow of electrolyte solution.

23. A refuelable electrochemical power source comprising:

(a) a refuelable battery having one or more electrochemical cells which employ particulate electrodes, and one or more conduits connecting the one or more electrochemical cells to each other; and

(b) a transportable container, removably attached to the refuelable battery, having;

a case;

a compartment within the case capable of holding a volume of electrolyte solution, and

a first valve and a second valve in fluid connection with the compartment and which pass through the case and are removably connected to the refuelable battery, such that the transportable container and the refuelable battery define a closed flow circuit for the circulation of electrolyte solution through the transportable container and the electrochemical cells of the refuelable battery while the transportable container is connected to the refuelable battery during operation of the refuelable battery.

24. A refuelable electrochemical power source comprising:

(a) a refuelable battery having one or more electrochemical cells which employ particulate electrodes, and one or more first conduits connecting the one or more electrochemical cells to each other; and

(b) a transportable container, removably attached to the refuelable battery, having;

a case,

one or more fuel compartments within the case, capable of holding a volume of electrochemically active fuel particles and electrolyte solution,

a plurality of valves in fluid connection with the one or more fuel compartments and which pass through the case and are removably connected to the refuelable battery, and

one or more second conduits, connecting the one or more fuel compartments to each other, such that the transportable container and the refuelable battery define a closed flow circuit for the circulation of electrolyte solution through the transportable container and the electrochemical cells of the refuelable battery while the transportable container is connected to the refuelable battery during operation of the refuelable battery.

25. The refuelable electrochemical power source of claim 24, the one or more electrochemical cells being connected in parallel for the flow of electrolyte solution.

26. The refuelable electrochemical power source of claim 25, the one or more first conduits being capable of substantially minimizing electrical conductivity through the electrolyte solution between each of the one or more electrochemical cells, and the one or more second conduits being capable of substantially minimizing electrical conductivity through the electrolyte solution between each of the one or more fuel compartments.

27. The refuelable electrochemical power source of claim 26, the one or more first conduits being sufficiently narrow and relatively long to substantially minimize electrical conductivity through the electrolyte between each of the one or more electrochemical cells, and the one or more second conduits being sufficiently narrow and relatively long to substantially minimize electrical conductivity through the electrolyte between each of the one or more fuel compartments.

28. The refuelable electrochemical power source of claim 24, the one or more electrochemical cells being connected in series for the flow of electrolyte solution.

29. The refuelable electrochemical power source of claim 24, the transportable container further having an electrolyte reservoir, within the case and connected to the one or more fuel compartments, and a second valve, in fluid connection with the electrolyte reservoir and which passes through the case and is removably connected to the refuelable battery.

30. The refuelable electrochemical power source of claim 24, the transportable container being capable of feeding fuel particles and electrolyte solution directly into each of the one or more electrochemical cells of the refuelable battery.

31. The refuelable electrochemical power source of claim 24, the refuelable battery further having one or more hoppers capable of containing a volume of fuel particles and electrolyte solution, and connected to the one or more electrochemical cells, the transportable container being capable of feeding fuel particles into the one or more hoppers.

32. The refuelable electrochemical power source of claim 31, the refuelable battery further having an electrolyte reservoir, capable of containing a volume of electrolyte solution, which is connected to the one or more hoppers.

33. The refuelable electrochemical power source of claim 24, the refuelable battery further having an electrolyte reservoir, capable of containing a volume of electrolyte solution, which is connected to the one or more electrochemical cells.

34. A method of operating a refuelable electrochemical power source, comprising the steps of:

(a) attaching a transportable container containing fuel particles and electrolyte to a refuelable battery, and allowing the fuel particles and electrolyte to dispense into the refuelable battery;

(b) circulating electrolyte solution through the refuelable battery and the attached transportable container for a period of time and thereby discharging the refuelable battery and dissolving some of the fuel particles into reaction products in spent electrolyte;

(c) detaching the transportable container with the reaction products and spent electrolyte from the refuelable battery; and

(d) attaching a transportable container containing fresh fuel particles and electrolyte to the refuelable battery.

35. The method of operating a refuelable electrochemical power source of claim 34, wherein after the transportable container with the reaction products and spent electrolyte is detached from the refuelable battery, the reaction products and spent electrolyte are removed and replaced with fresh fuel particles and electrolyte at a refilling apparatus.

36. The method of operating a refuelable electrochemical power source of claim 34, the fuel particles comprising zinc pellets.

37. The method of operating a refuelable electrochemical power source of claim 34, the fuel particles comprising aluminum pellets.