Bipolar electrode-electrolyte unit

• US 5,955,215 A
• Filed: 07/21/1997
• Issued: 09/21/1999
• Est. Priority Date: 07/19/1996
• Status: Expired due to Fees

• Current Assignee: Dornier GmbH (Government of France)
• Original Assignee: Dornier GmbH (Government of France)
• Inventors: Kurzweil, Peter, Schmid, Ottmar
• Primary Examiner(s): Bell, Bruce F.
• Application Number:
  US08/897,568
• Time in Patent Office: 792 Days
• Field of Search: 361/502, 429/210, 429/40, 429/41, 429/42, 204/290 R, 204/290 F, 204/294, 204/254, 204/255, 204/268, 204/269
• US Class Current: 429/468
• CPC Class Codes: H01G 11/26 characterised by their structure, e.g. multi-layered, porosity or surface features
• CPC Class Codes: H01G 11/46 Metal oxides
• CPC Class Codes: H01M 2004/8694 Bipolar electrodes
• CPC Class Codes: H01M 4/8631 Bipolar electrodes
• CPC Class Codes: H01M 4/8896 Pressing, rolling, calendering membrane electrode assemblies H01M8/1004
• CPC Class Codes: H01M 8/0206 Metals or alloys
• CPC Class Codes: H01M 8/1004 characterised by membrane-electrode assemblies [MEA] H01M8/12 takes precedence
• CPC Class Codes: Y02E 60/13 Energy storage using capacitors
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A bipolar electrode-electrolyte unit for an electrochemical cell includes a barrier layer, at least two carrier layers and at least two active layers, and an electrolyte. The active layers comprise an electroactive material with low resistance and high capacitance. The barrier layer is electrically conducting, is impermeable to matter, and is made of compressed carbon, impregnated carbon, compressed and impregnated carbon, plastic-bonded carbon or carbon-coated sheet metal. The carrier layers, each located between a barrier layer and an active layer, form an electrically conducting porous three-dimensional structure with a large specific surface that contains a material selected from the group consenting of carbon fiber papers, carbon fiber films, carbon fiber mats, carbon fiber fabrics, compressed graphite flakes and carbon fibers, conducting plastic, and carbon produced by pyrolysis or dehydration of organic materials.

Claims

1. Bipolar electrode-electrolyte unit for an electrochemical storage device, said electrode-electrolyte unit comprising a barrier layer, at least two carrier layers and at least two active layers, and an electrolyte, wherein

the active layers comprise an electroactive material with low resistance and high capacitance;

the barrier layer is electrically conducting, is impermeable to matter, and is made of a material selected from the group consisting of compressed carbon, impregnated carbon, compressed and impregnated carbon, plastic-bonded carbon; and

carbon-coated sheet metal;

the carrier layers, each located between a barrier layer and an active layer, form an electrically conducting porous three-dimensional structure with a large specific and geometric surface that contains a material selected from the group consisting of carbon fiber papers, carbon fiber films, carbon fiber mats, carbon fiber fabrics, compressed graphite flakes and carbon fibers, conducting plastic, and carbon produced by pyrolysis or dehydration of organic materials;

the barrier layer and carrier layer form a bond produced by gluing, rolling, or pressing that is stable, mechanical and electrically conducting; and

the electrolyte is a good electrical conductor.

2. Bipolar unit according to claim 1 wherein the active layer consists of a perovskite material.

3. Bipolar unit according to claim 1 wherein the active layer consists of a redox-active substoichiometric metal hydrated oxide with a prescribed water content.

4. Bipolar unit according to claim 3 wherein the metal hydrated oxide contains a proton-conducting platinum metal hydrated oxide that is produced from platinum metal compounds by the addition of dilute lye and subsequent drying at less than 325°

C.

5. Bipolar unit according to claim 4 wherein said proton conducting platinum metal hydrated oxide contains additives selected from the group consisting of tin, tantalum, and manganese.

6. Bipolar unit according to claim 1 wherein the barrier layer comprises plastic-bonded carbon which is a mixture or a compound of carbon and polymers selected from the group consisting of polyvinylidenefluoride, polysulfone, polypropylene, polyethylene, polytetrafluoroethylene, polyetheretherketone, polyphenylenesulfide, polystyrene, polymethylmethacrylate, phenolic resins, and polycarbonate.

7. Bipolar unit according to claim 1 wherein carrier layer comprises an adhesion-promoting connecting layer and a functional layer with a large surface area.

8. Bipolar unit according to claim 1 wherein that carrier layer is covered by active layer in a manner which is one of completely, incompletely, porously, and in the form of seeds.

9. Bipolar unit according to claim 1 wherein active layer is bonded to carrier layer by a binder selected from the group consisting of perfluorosulfonic acid solution, polytetrafluoroethylene, thick oil, and metal-organic compounds of titanium, aluminum, and silicon.

10. Bipolar unit according to claim 1 wherein the active layer forms a mechanical and electrical unit with carrier layer.

11. Bipolar unit according to claim 1 wherein the electrolyte contains a material selected from the group consisting of aqueous solutions, dilute acids, dilute lyes, superacids, and organic solvents with conducting salts.

12. Bipolar unit according claim 11 wherein the liquid in electrolyte layer is held by capillary forces in an absorbent material selected from the group consisting of zirconium dioxide, porous polytetrafluoroethylene, polypropylene and polyamide.

13. Bipolar unit according claim 1 wherein the electrolyte consists of a paste comprising a first material selected from the group consisting of inorganic acids and lyes, and a second material selected from the group consisting of aluminum oxide, silicon dioxide and fluoropolymers.

14. Bipolar unit according claim 1 wherein the electrolyte is one of an ion exchange membrane or an ion-conducting plastic.

15. Bipolar unit according claim 1 wherein the barrier layer is provided with gas channels or a flow field.

16. A double-layer capacitor comprising a bipolar electrode-electrolyte unit according to claim 1.

17. Bipolar electrode stack comprising a plurality of bipolar electrode-electrolyte units which are electrically connected in series, each of said bipolar electrode-electrolyte units comprising a barrier layer, at least two carrier layers and at least two active layers and an electrolyte, wherein

the active layers comprise an electroactive material with low resistance and high capacitance;

the barrier layer is electrically conducting, is impermeable to matter, and is made of a material selected from the group consisting of compressed carbon, impregnated carbon, compressed and impregnated carbon, plastic-bonded carbon; and

carbon-coated sheet metal;

the carrier layers, each located between a barrier layer and an active layer, form an electrically conducting porous three-dimensional structure with a large specific and geometric surface that contains a material selected from the group consisting of carbon fiber papers, carbon fiber films, carbon fiber mats, carbon fiber fabrics, compressed graphite flakes and carbon fibers, conducting plastic, and carbon produced by pyrolysis or dehydration of organic materials;

the barrier layer and carrier layer form a bond produced by gluing, rolling, or pressing that is stable, mechanical and electrically conducting; and

the electrolyte is a good electrical conductor.

18. Bipolar electrode stack according to claim 17 further comprising a structured layer which is transparent to matter and is located between adjoining bipolar electrode-electrolyte units.