Thermoplastic polyether urethane

• US 5,959,059 A
• Filed: 06/10/1997
• Issued: 09/28/1999
• Est. Priority Date: 06/10/1997
• Status: Expired due to Term

• Current Assignee: Noveon, Inc. (Berkshire Hathaway Incorporated)
• Original Assignee: Goodrich Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Vedula, Ravi Ram, Goscewski, Stanley Raymond
• Primary Examiner(s): GORR, RACHEL F
• Application Number:
  US08/872,663
• Time in Patent Office: 840 Days
• Field of Search: 528/76, 528/79, 528/906, 428/364, 428/423.1, 152/151, 473/351
• US Class Current: 528/76
• CPC Class Codes: C08G 18/4854 Polyethers containing oxyalkylene groups having four carbon atoms in the alkylene group
• CPC Class Codes: C08G 18/6674 with compounds of group C08G18/3203
• CPC Class Codes: D01F 6/70 from polyurethanes
• CPC Class Codes: Y10S 528/906 Fiber or elastomer prepared from an isocyanate reactant
• CPC Class Codes: Y10T 152/10 Tires, resilient
• CPC Class Codes: Y10T 428/2913 Rod, strand, filament or fiber
• CPC Class Codes: Y10T 428/31551 Of polyamidoester [polyurethane, polyisocyanate, polycarbamate, etc.]

Abstract

A thermoplastic polyether polyurethane having good rebound resilience and low hysteresis properties is prepared by the reaction of a diisocyanate with a hydroxyl terminated polyether having a weight average molecular weight of at least 1,400 and a glycol chain extender. The polyether contains alkylene oxide repeat units having from 2 to 6 carbon atoms and the chain extender glycol has from 2 to 16 carbon atoms. The amount of the chain extender glycol is from about 0.25 to about 2 moles per mole of the polyether.

Claims

1. A thermoplastic urethane polymer, comprising:

a polyether urethane derived from a diisocyanate reacted with a hydroxyl terminated polyether and a glycol chain extender,

said hydroxyl terminated polyether having alkylene oxide repeat units containing from 2 to 6 carbon atoms and having a weight average molecular weight of at least 1,400,

said chain extender being a substantially non-branched glycol having from 2 to 16 carbon atoms,

wherein the amount of said chain extender is from about 0.7 to less than 1.0 mole per male of said hydroxyl terminated polyether and wherein the thermoplastic urethane polymer has a rebound of at least 60 percent when measured in accordance with ASTM D2632.

2. A thermoplastic polymer according to claim 1, wherein said polyether has alkylene oxide repeat units containing from 2 to 4 carbon atoms.

3. A thermoplastic polymer according to claim 1, wherein said diisocyanate has a total of from 4 to 20 carbon atoms, and wherein the mole ratio of said diisocyanate to said hydroxyl terminated polyether and said glycol chain extender is from about 0.98 to about 1.03.

4. A thermoplastic polymer according to claim 1, wherein said chain extender is an aromatic having a total of from 6 to 12 carbon atoms, and wherein said diisocyanate is an aromatic diisocyanate having a total of from 8 to 16 carbon atoms.

5. A thermoplastic polymer according to claim 1, wherein said hydroxyl terminated polyether has a weight average molecular weight of at least 2500, wherein said polyether is polytetramethylene glycol, and wherein said thermoplastic polymer has a weight average molecular weight of from about 100,000 to about 500,000.

6. A thermoplastic polymer according to claim 1 wherein said polyether is polytetramethylene glycol having a molecular weight of from about 2,500 to about 10,000, wherein said chain extender is benzene glycol, and wherein said diisocyanate is diphenylmethane diisocyanate.

7. A thermoplastic polymer according to claim 1, wherein said polymer has a rebound of at least 65 percent.

8. A thermoplastic polymer according to claim 1, wherein said polymer has a rebound of at least 70 percent.

9. A thermoplastic polymer according to claim 1, wherein the hysteresis of said polymer at 10 percent elongation is 15 percent or less.

10. A thermoplastic polymer according to claim 1, wherein the hysteresis of said polymer at 10 percent elongation is 12 percent or less.

11. A thermoplastic polymer according to claim 6, wherein the hysteresis of said polymer at 10 percent elongation is 6 percent or less.

12. A thermoplastic polymer according to claim 5, wherein said polymer has a rebound of at least 70 percent, and wherein the hysteresis of said polymer at 10 percent elongation is 9 percent or less.

13. A golf ball core, comprising;

the thermoplastic polymer of claim 1.

14. A golf ball core, comprising;

the thermoplastic polymer of claim 5.

15. A cord, comprising;

the thermoplastic polymer of claim 1.

16. A cord, comprising;

the thermoplastic polymer of claim 6.

17. A recreational wheel, comprising;

the thermoplastic polymer of claim 1.

18. A recreational wheel, comprising;

the thermoplastic polymer of claim 6.

19. A profile belt, comprising;

the thermoplastic polymer of claim 1.

20. A profile belt, comprising;

the thermoplastic polymer of claim 6.

21. An article containing fibers, comprising;

the thermoplastic polymer of claim 1.

22. An article containing fibers, comprising;

the thermoplastic polymer of claim 6.

27. An article comprising a thermoplastic urethane polymer according to claim 1.

28. An article comprising a thermoplastic urethane polymer according to claim 1, wherein the polymer has a rebound of at least 70 percent when measured in accordance with ASTM D2632.

29. An article comprising a thermoplastic urethane polymer according to claim 1, wherein the polymer has a rebound of at least 75 percent when measured in accordance with ASTM D2632.

23. A process for producing a thermoplastic urethane polymer comprising steps of:

mixing and reacting a hydroxyl terminated polyether, a glycol chain extender, and a diisocyanate, said hydroxyl terminated polyether having alkylene oxide repeat units containing from 2 to 6 carbon atoms and having a weight average molecular weight of at least 1400, wherein the mole ratio of said chain extender to said hydroxyl terminated polyether is from about 0.7 to less than 1.0 and wherein said polymer has a rebound of at least 60 percent when measured in accordance with ASTM D2632.

24. A process according to claim 23, wherein said polyether has alkylene oxide repeat units containing from 2 to 4 carbon atoms, and wherein said diisocyanate has a total of from 4 to 20 carbon atoms.

25. A process according to claim 23, wherein said chain extender is an aromatic glycol having a total of from 6 to 12 carbon atoms, and wherein said diisocyanate is an aromatic diisocyanate having a total of from 8 to 16 carbon atoms.

26. A process according to claim 23, wherein the weight average molecular weight of said hydroxyl terminated polyether is at least 2,500, wherein said polyether is polytetramethylene glycol, wherein said chain extender is benzene glycol, and wherein said diisocyanate is diphenylmethane diisocyanate, and wherein the mole ratio of said diisocyanate to said hydroxyl terminated polyether and said glycol chain extender is from about 0.98 to about 1.03.