Removing carbon dioxide, ethane and heavier components from a natural gas

• US 5,960,644 A
• Filed: 06/05/1997
• Issued: 10/05/1999
• Est. Priority Date: 06/05/1996
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Robertson, Gary Alan, Nagelvoort, Robert Klein
• Primary Examiner(s): Capossela, Ronald C.
• Application Number:
  US08/869,899
• Time in Patent Office: 852 Days
• Field of Search: 62/622, 62/929, 62/621
• US Class Current: 62/622
• CPC Class Codes: C10L 3/10 Working-up natural gas or synthetic natural gas
• CPC Class Codes: F25J 2200/02 in a single pressure main column system
• CPC Class Codes: F25J 2200/74 Refluxing the column with at least a part of the partially condensed overhead gas
• CPC Class Codes: F25J 2200/78 Refluxing the column with a liquid stream originating from an upstream or downstream fractionator column
• CPC Class Codes: F25J 2205/02 using simple phase separation in a vessel or drum
• CPC Class Codes: F25J 2205/04 in the feed line, i.e. upstream of the fractionation step
• CPC Class Codes: F25J 2220/66 Separating acid gases, e.g. CO2, SO2, H2S or RSH
• CPC Class Codes: F25J 2240/02 Expansion of a process fluid in a work-extracting turbine (i.e. isentropic expansion), e.g. of the feed stream
• CPC Class Codes: F25J 2270/04 Internal refrigeration with work-producing gas expansion loop
• CPC Class Codes: F25J 2270/90 External refrigeration, e.g. conventional closed-loop mechanical refrigeration unit using Freon or NH3, unspecified external refrigeration
• CPC Class Codes: F25J 3/0209 Natural gas or substitute natural gas
• CPC Class Codes: F25J 3/0233 separation of CnHm with 1 carbon atom or more
• CPC Class Codes: F25J 3/0238 separation of CnHm with 2 carbon atoms or more
• CPC Class Codes: Y02C 20/40 of CO2
• CPC Class Codes: Y10S 62/929 From natural gas

Abstract

A method is provided for removing carbon dioxide, ethane and heavier components from high pressure natural gas (10) comprises: partly condensing and expanding the high pressure natural gas (10) to obtain a gaseous stream (30) enriched in methane and carbon dioxide and two liquid streams (37 and 40) enriched in ethane and heavier components which are introduced into fractionation column (35); removing from fractionation column (35) fluid stream (45), heating (46) the fluid stream to obtain a reboiling stream (47) which is introduced into the fractionation column (35); removing from fractionation column (35) liquid stream (50) enriched in carbon dioxide, ethane and heavier components; removing from the top of fractionation column (35) a gaseous overhead stream (55) enriched in methane; cooling (56) the gaseous overhead stream (55) to obtain a two-phase fluid, separating (58) the two-phase fluid into cooled gaseous overhead stream (60) and first reflux stream (62) which is introduced into the fractionation column (35); and expanding (65) the cooled gaseous overhead stream (60) to obtain a two-phase fluid at low pressure, separating (69) the two-phase fluid into gaseous product stream (70) and second reflux stream (72) which is introduced into the top of the fractionation column (35).

Claims

1. A method of removing carbon dioxide, ethane and heavier components from a high pressure natural gas stream comprising methane, carbon dioxide, ethane and heavier components, the method comprising the steps of:

(a) partly condensing and expanding the high pressure natural gas stream to obtain a stream enriched in methane and carbon dioxide and at least one liquid stream enriched in ethane and heavier components;

(b) introducing the stream enriched in methane and carbon dioxide at fractionation pressure into a fractionation column which includes a plurality of fractionation stages;

(c) introducing the liquid stream(s) at fractionation pressure into the fractionation column at a level which is below the level of introducing the stream enriched in methane and carbon dioxide;

(d) removing from the fractionation column, below the level of introducing the liquid stream(s), at least one fluid stream, heating the fluid stream(s) to obtain reboiling stream(s), and introducing the reboiling stream(s) into the fractionation column;

(e) removing from the bottom of the fractionation column a liquid stream enriched in carbon dioxide, ethane and heavier components;

(f) removing from the top of the fractionation column a gaseous overhead stream enriched in methane,

(g) cooling the gaseous overhead stream at fractionation pressure to obtain a two-phase fluid, separating the two-phase fluid into a cooled gaseous overhead stream and a liquid stream, and introducing the liquid stream as a first reflux stream into the fractionation column at a level above the level of introducing the stream enriched in methane and carbon dioxide; and

(h) expanding the cooled gaseous overhead stream to obtain a two-phase fluid at low pressure, separating the two-phase fluid into a gaseous product stream and a liquid stream, and introducing the liquid stream as a second reflux stream into the fractionation column at a level above the level of introducing the first reflux stream.

2. The method of claim 1 wherein the gaseous overhead stream is cooled by indirect heat exchange with the gaseous product stream.

3. The method of claim 1 wherein the stream enriched in methane and carbon dioxide at fractionation pressure is cooled by indirect heat exchange with the gaseous product stream before the stream is introduced into the fractionation column.

4. The method of claim 1 wherein part of the high pressure natural gas stream is cooled by indirect heat exchange with the gaseous product stream.

5. The method of claim 4 wherein the remainder of the high pressure natural gas stream is cooled by indirect heat exchange with a stream selected from the group of refrigerant, at least one of the at least one fluid streams removed from the fractionation column in step (d), and a combination of the two.

6. The method of claim 1 wherein the gaseous product stream is compressed to pipeline pressure to obtain compressed product gas.

7. The method of claim 6 wherein at least part of the heat of compression is removed from the compressed product gas by indirect heat exchange with part of the liquid stream removed from the bottom of the fractionation column to obtain a reboiling stream which is introduced into the fractionation column.

8. The method of claim 1 wherein steps (a), (b) and (c) comprise cooling at least part of the high pressure natural gas stream by indirect heat exchange with the gaseous product stream and cooling the remainder by indirect heat exchange with a stream selected from the group comprising a refrigerant, at least one of the fluid stream(s) removed from the fractionation column in step (d), and combinations thereof, to obtain partly condensed stream(s) at high pressure;

combining the partly condensed streams;

separating the combined partly condensed streams into a first gaseous stream and a first liquid stream which latter stream is introduced at fractionation pressure into the fractionation column;

expanding the first gaseous stream to obtain a partly condensed stream at lower pressure;

separating the partly condensed stream into a second gaseous stream and a second liquid stream which latter stream is introduced at fractionation pressure into the fractionation column at a level above the level of introducing the first liquid stream;

cooling the second gaseous stream by indirect heat exchange with the gaseous product stream, and introducing cooled second gaseous stream at fractionation pressure into the fractionation column above the level of introducing the second liquid stream.

9. The method of claim 8 wherein the gaseous product stream is compressed to pipeline pressure to obtain compressed product gas, and wherein at least part of the heat of compression is removed from the compressed product gas by indirect heat exchange with part of the liquid stream removed from the bottom of the fractionation column to obtain a reboiling stream which is introduced into the fractionation column.

10. The method of claim 1 which further comprises removing from the fractionation column below the level of introducing the liquid stream(s) in step (c) a liquid stream, removing carbon dioxide from this liquid stream to obtain a liquid stream having a reduced carbon dioxide concentration, and introducing into the fractionation column the liquid stream having a reduced carbon dioxide concentration into the fractionation column.