Method for electroplating elastomer-modified polyphthalamide articles
First Claim
1. A process for metal plating an article of an elastomeric material dispersed in a polyphthalamide (PPA) matrix, said process comprising the steps of:
- etching a surface of said article with an etching solution comprising trivalent chromium ions, hexavalent chromium ions and sulfuric acid, said trivalent chromium ions being present in said etching solution in an amount of about 6.5 to about 7.5 ounces per gallon of said etching solution, said etching solution being at a temperature of approximately 140°
F. to 165°
F. (about 60°
C. to about 75°
C.) and contacting said surface for a duration sufficient to etch said PPA matrix and said elastomeric material whereby micropores are produced in said surface;
rinsing said surface with a rinse solution maintained at a temperature below about 100°
F.;
neutralizing said surface to remove remnant chromium from said etching step;
catalyzing said surface with a noble metal salt solution;
treating said surface with a sulfate-free accelerant solution; and
thenelectrolessly depositing a metal layer on said surface.
0 Assignments
0 Petitions
Accused Products
Abstract
A process for metal plating a high impact, high temperature plastic suitable for forming trim elements of an automobile. The process is particularly directed to plating an elastomer-modified PPA resin, and entails closely controlled process steps that include selectively etching the elastomer and the PPA matrix with a solution containing chromic acid, then effectively removing from the substrate any retained chromium which would adversely affect the ability of metal plating to adhere to the substrate, and thereafter protecting the substrate from attack by sulfuric acid. The process is particularly effective for electroplating a PPA resin modified with about five to about 30 weight percent EPDM.
-
Citations
19 Claims
-
1. A process for metal plating an article of an elastomeric material dispersed in a polyphthalamide (PPA) matrix, said process comprising the steps of:
-
etching a surface of said article with an etching solution comprising trivalent chromium ions, hexavalent chromium ions and sulfuric acid, said trivalent chromium ions being present in said etching solution in an amount of about 6.5 to about 7.5 ounces per gallon of said etching solution, said etching solution being at a temperature of approximately 140°
F. to 165°
F. (about 60°
C. to about 75°
C.) and contacting said surface for a duration sufficient to etch said PPA matrix and said elastomeric material whereby micropores are produced in said surface;rinsing said surface with a rinse solution maintained at a temperature below about 100°
F.;neutralizing said surface to remove remnant chromium from said etching step; catalyzing said surface with a noble metal salt solution; treating said surface with a sulfate-free accelerant solution; and
thenelectrolessly depositing a metal layer on said surface. - View Dependent Claims (2, 3, 4, 5, 6, 7, 8)
-
-
9. A process for metal plating an article of an ethylene-propylene diene monomer (EPDM)-modified polyphthalamide (PPA) material, said process comprising the steps of:
-
etching a surface of said article with an etching solution comprising trivalent chromium ions, hexavalent chromium ions and sulfuric acid, said trivalent chromium ions being present in said etching solution in an amount of about 6.5 to about 7.5 ounces per gallon of said etching solution, said etching solution being at a temperature of about 140°
F. to 165°
F. and contacting said surface for a duration sufficient to etch PPA material and EPDM material at said surface whereby micropores are produced in said surface;rinsing said surface with a water solution maintained at a temperature below about 100°
F.;treating said surface with a neutralizing solution to remove remnant chromium from said etching step; catalyzing said surface with a noble metal salt solution; treating said surface with an accelerant solution an; electrolessly depositing a metal layer on said surface; and
thenelectroplating metal onto said metal layer so as to form a decorative metal layer on said article. - View Dependent Claims (10, 11, 12, 13, 14, 15, 16, 17, 18)
-
-
19. A process for electroplating ethylene-propylene diene monomer (EPDM)-modified polyphthalamide (PPA) plastic article, said process comprising the steps of:
-
etching a surface of said article with a chromic acid-sulfuric acid etching solution comprising about 3.5 to about 4.5 lbs./gal chromic acid and about 8 to about 10 volume percent sulfuric acid, and containing about 6.5 to about 7.5 oz./gal. trivalent chromium ions, said etching solution being at a temperature of about 140°
F. to about 165°
F. and contacting said surface for a duration of about three to about fifteen minutes to etch PPA material and EPDM material at said surface whereby micropores are produced in said surface;rinsing said surface for a duration of less than ten minutes using a water solution maintained at a temperature below 100°
F. to control chromium contamination of said water solution as chromium is dragged into said water solution from said etching step;treating said surface with a neutralizing solution at a temperature of about 100°
F. to about 140°
F. for a duration of about 0.5 to about 4 minutes so as to remove remnant chromium from said etching step, said neutralizing solution comprising a reducing agent and about two to about eight volume percent hydrochloric acid;rinsing said surface to remove excess neutralizing solution; treating said surface with a catalyzing solution comprising hydrochloric acid, tin and palladium; rinsing to remove excess catalyzing solution from said surface; treating said surface with an accelerant solution to remove excess tin from said surface; electrolessly depositing a metal strike having a thickness of at least about 0.000020 inch on said surface, said metal strike being a metal selected from the group consisting of copper and nickel; and
thenelectroplating metal onto said metal strike with a solution containing sulfuric acid.
-
Specification