Liquid crystalline polymer composites having high dielectric constant

• US 5,962,122 A
• Filed: 11/28/1995
• Issued: 10/05/1999
• Est. Priority Date: 11/28/1995
• Status: Expired due to Term

• Current Assignee: CNA Holdings Incorporated (Celanese Corporation)
• Original Assignee: Hoechst Celanese Corporation (Sanofi )
• Inventors: Eckhardt, Helmut, Pleban, William M., Walpita, Lak M.
• Primary Examiner(s): Acquah, Samuel A.
• Application Number:
  US08/563,473
• Time in Patent Office: 1,407 Days
• Field of Search: 524/81, 524/174, 524/176, 524/177, 524/178, 524/183, 524/261, 524/401, 524/404, 524/408, 524/413, 524/442, 524/445, 524/449, 524/451, 524/539, 524/540, 428/325, 428/327, 428/339, 428/402, 428/411.1, 428/412, 428/457, 428/480, 428/689
• US Class Current: 428/325
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: H01B 3/30 plastics; resins; waxes
• CPC Class Codes: H05K 1/0373 containing additives, e.g. fillers H05K1/036 takes precedence
• CPC Class Codes: H05K 1/162 incorporating printed capacitors
• CPC Class Codes: Y10T 428/252 Glass or ceramic [i.e., fired or glazed clay, cement, etc.] [porcelain, quartz, etc.]
• CPC Class Codes: Y10T 428/254 Polymeric or resinous material
• CPC Class Codes: Y10T 428/269 including synthetic resin or polymer layer or component
• CPC Class Codes: Y10T 428/2982 Particulate matter [e.g., sphere, flake, etc.]
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/31678 Of metal
• CPC Class Codes: Y10T 428/31786 Of polyester [e.g., alkyd, etc.]

Abstract

Polymeric compositions having a high dielectric constant are made from a thermotropic liquid crystalline and a ceramic having a dielectric constant which is greater than about 50 at a frequency of 1.0 GHz. The compositions have a dielectric constant of at least about 4, and preferably at least about 6. Preferred compositions also have a low loss tangent.

Claims

1. A polymeric composition having a high dielectric constant comprising a thermotropic liquid crystalline polymer and a high dielectric ceramic in the form of fine particles having an average diameter of from about 0.2 to about 10 microns selected from the group consisting of SrTiO₃, barium neodymium titanate, and mixtures thereof, wherein said high dielectric ceramic is included in an amount of at least about 30% by volume and in sufficient quantity that said composition has a dielectric constant of at least about 6.0 at a frequency of 1.0 GHz.

2. The polymeric composition as recited in claim 1, wherein said composition has a loss tangent of less than about 0.02 at 1.0 GHz.

3. The polymeric composition recited in claim 1, wherein said composition has a loss tangent of less than about 0.01 at 1.0 GHz.

4. The polymeric composition as recited in claim 1, wherein said high dielectric ceramic is SrTiO₃.

5. The polymeric composition as recited in claim 1, wherein said thermotropic liquid crystalline polymer comprises monomer units derived from one or more monomers selected from the group consisting of 4-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, 2,6-naphthalenedicarboxylic acid, terephthalic acid, isophthalic acid, 1,4-hydroquinone, 4,4"-biphenol, 4-aminophenol, 4,4"-biphenyidicarboxylic acid, and 4-aminobenzoic acid.

6. The polymeric composition as recited in claim 1, wherein said high dielectric constant ceramic is included in said composition in an amount of about 30% to about 50% by volume.

7. The polymeric composition as recited in claim 1, said composition further comprising one or more solid or reinforcing fillers.

8. The polymeric composition as recited in claim 7, wherein said solid or reinforcing fillers are selected from the group consisting of carbon, wollastonite, mica, talc, silicates, silica, clay, poly(tetrafluoroethylene), alumina, glass, rock wool, silicon carbide, diamond, fused quartz, aluminum nitride, beryllium oxide, boron nitride, and mixtures thereof, where said fillers are particles, fibers, or mixtures thereof.

19. A capacitor comprising the polymeric composition recited in claim 1.

20. A multichip module comprising the polymeric composition recited in claim 1.

21. A printed circuit antenna comprising the polymeric composition recited in claim 1.

22. A printed rf or microwave circuit element comprising the polymeric composition recited in claim 1.

23. A printed rf or microwave circuit element as recited in claim 22, where said rf or microwave circuit element is selected from the group consisting of transmission lines, inductors, capacitors, filters, signal couplers, branch line couplers, power splitters, signal splitters, impedance transformers, half wave and quarter wave transformers, impedance matching circuits, and mixtures thereof.

9. A high dielectric constant laminate comprising:

(a) a flat substrate comprising a polymeric composition having a high dielectric constant, said substrate having two surfaces, said polymeric composition comprising a thermotropic liquid crystalline polymer and a high dielectric ceramic in an amount of at least about 30% by volume and in the form of fine particles having an average diameter of from about 0.2 microns to about 10 microns selected from the group consisting of SrTiO₃, barium neodymium titanate, and mixtures thereof; and

(b) one or more layers of metal, each layer adhering to one surface of said substrate;

wherein said laminate has a dielectric constant of at least about 6.0 at a frequency of 1.0 GHz.

10. The high dielectric constant laminate as recited in claim 9, wherein said high dielectric constantceramic is SrTiO₃.

11. The high dielectric constant laminate as recited in claim 9, wherein said laminate has a loss tangent of not more than about 0.02 at 1.0 GHz.

12. The high dielectric constant laminate as recited in claim 9, wherein said metal is copper.

13. A high dielectric constant laminate as recited in claim 12, wherein the thickness of said substrate is in the range of about 30 mils to about 500 mils, and the thickness of said copper layer is in the range of about 1/8 mil to about 12 mils.

14. A high dielectric constant laminate as recited in claim 12, said laminate comprising a flat substrate of said polymeric composition and two layers of copper, said polymeric composition comprising about 30% to about 50% by volume of said ceramic.

15. A method of making a laminate having a high dielectric constant, comprising the steps of:

(a) compounding a thermotropic liquid crystalline polymer and a ceramic in an amount of at least about 30% by volume and in the form of fine particles having an average diameter of from about 0.2 to about 10 microns selected from the group consisting of SrTiO₃, barium neodymium titanate, and mixtures thereof to yield a polymeric composition having a dielectric constant of at least about 6.0 at 1.0 GHz;

(b) shaping said polymeric composition to form a flat substrate; and

(c) applying metal onto one or both surfaces of said substrate.

16. A method of making a laminate having a high dielectric constant as recited in claim 15, wherein said step of applying metal to one or both surfaces of said substrate is carried out by laminating metal foil onto one or both surfaces of said substrate.

17. A method of making a laminate as recited in claim 16, wherein said metal is copper.

18. The method of making a laminate as recited in claim 15, wherein said laminate has a dielectric constant of at least about 6 at a frequency of 1 GHz and a loss tangent of not more than about 0.01 at a frequency of 1 GHz.