Chlorine dioxide generation for water treatment

• US 5,965,004 A
• Filed: 10/28/1997
• Issued: 10/12/1999
• Est. Priority Date: 03/13/1996
• Status: Expired due to Term

• Current Assignee: Superior Plus LP (Superior Plus Corporation)
• Original Assignee: Sterling Pulp Chemicals, Ltd.
• Inventors: Schaible, Ron K., Lawless, Darren F., Tran, Ty V., Cowley, Gerald, Ranger, George Joseph, Lipsztajn, Marek
• Primary Examiner(s): Phasge, Arun S.
• Application Number:
  US08/959,031
• Time in Patent Office: 714 Days
• Field of Search: 205/499, 205/502, 205/503, 205/556, 423/478, 210/638, 210/640
• US Class Current: 205/499
• CPC Class Codes: B01D 61/00 Processes of separation using semi-permeable membranes, e.g. dialysis, osmosis or ultrafiltration; Apparatus, accessories or auxiliary operations specially adapted therefor separation of gases or vapours by diffusion B01D53/22
• CPC Class Codes: C01B 11/022 Chlorine dioxide (ClO2)
• CPC Class Codes: C02F 1/44 by dialysis, osmosis or reverse osmosis general membrane separation processes B01D61/00, membrane modules B01D63/00, electrodialysis C02F1/4693, combination of membrane modules and bioreactors C02F3/1268
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 1/76 with halogens or compounds of halogens C02F1/4674 takes precedence
• CPC Class Codes: C02F 2201/46115 Electrolytic cell with membranes or diaphragms
• CPC Class Codes: C02F 2303/04 Disinfection
• CPC Class Codes: C25B 1/26 Chlorine; Compounds thereof by simultaneous production of alkali metal hydroxides and chlorine, oxyacids or salts of chlorine C25B1/34

Abstract

Chlorine dioxide is generated by electrochemical oxidation of sodium chlorite in an anode compartment of a cation-exchange membrane-divided cell in the presence of significant quantities of sodium chlorate and is recovered in a suitable recipient medium by passing the chlorine dioxide through a hydrophobic microporous membrane. Water balance in a continuous operation is maintained by removing water from the anolyte by transporting the same partly across the hydrophobic microporous membrane in vapor form and partly across the cation-exchange membrane.

Claims

1. A method of forming an aqueous solution of chlorine dioxide, which comprises:

feeding an aqueous solution of sodium chlorite to an anodic compartment of an electrochemical cell divided by at least one ion-permeable separator from a cathode compartment to which water or an aqueous electrolyte is fed,

electrochemically generating a first aqueous solution of chlorine dioxide in the anodic compartment of said electrochemical cell in the presence of about 20 to about 450 gpL of sodium chlorate,

contacting said aqueous solution of chlorine dioxide with one face of a hydrophobic microporous membrane, and

providing a differential of partial pressure of both said chlorine dioxide and water vapor between said aqueous solution and an aqueous recipient medium in contact with the opposite face of said hydrophobic microporous membrane, whereby both chlorine dioxide and water vapor pass through the membrane to the recipient medium to form a second aqueous solution of chlorine dioxide as the product.

2. The method of claim 1 wherein the sodium chlorate concentration in the anode compartment is about 50 to about 250 gpL.

3. The method of claim 1 including directing a stream of anolyte from said anodic compartment of said electrochemical cell to a cathode compartment of said electrochemical cell and cathodically reducing sodium chlorate to sodium chloride in said cathode compartment.

4. The method of claim 1 including directing a stream of anolyte from said anodic compartment of said electrochemical cell to a cathode compartment to a second electrochemical cell and cathodically reducing sodium chlorate to sodium chloride in said cathode compartment.

5. The method of claim 1 wherein a second electrochemical cell is provided wherein sodium chlorite solution is acidified prior to passage to said anodic compartment of the first-mentioned electrochemical cell.

6. The method of claim 5 wherein effluent from an anodic compartment of the second electrochemical cell is forwarded to the anodic compartment of the first electrochemical cell.

7. The method of claim 1 wherein said sodium chlorite solution is substantially free from impurities.