Hybrid inorganic-organic composite for use as an interlayer dielectric

• US 5,965,202 A
• Filed: 08/14/1997
• Issued: 10/12/1999
• Est. Priority Date: 05/02/1996
• Status: Expired due to Term

• Current Assignee: Bell Semiconductor, LLC (Hilco Inc. (d/b/a Hilco Global))
• Original Assignee: Lucent Technologies, Inc. (Nokia Corporation)
• Inventors: Taylor-Smith, Ralph E., Valdes, Jorge Luis
• Primary Examiner(s): COPENHEAVER, BLAINE R
• Application Number:
  US08/911,489
• Time in Patent Office: 789 Days
• Field of Search: 428/315.5, 428/317.9, 257/637, 257/638, 427/123, 427/247, 427/245, 438/624, 438/780, 438/782, 521/55, 521/75, 521/92, 521/93, 523/202, 523/203, 523/216
• US Class Current: 427/245
• CPC Class Codes: C08F 292/00 Macromolecular compounds obtained by polymerising monomers on to inorganic materials
• CPC Class Codes: C08G 83/001 Macromolecular compounds containing organic and inorganic sequences, e.g. organic polymers grafted onto silica
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: Y10S 977/89 Deposition of materials, e.g. coating, cvd, or ald
• CPC Class Codes: Y10T 428/249954 With chemically effective material or specified gas other than air, N, or carbon dioxide in void-containing component
• CPC Class Codes: Y10T 428/249986 Void-containing component contains also a solid fiber or solid particle

Abstract

Three-phase composite materials system having a low dielectric constant and physico-chemical properties suitable for IC fabrication conditions, and a method for making such materials, are disclosed. The three-phase composite material includes an organic phase, an inorganic phase and a void phase. The organic phase is in the form of an organic polymer matrix, the void phase is represented by microporosity present in the matrix, and the inorganic phase is implemented as inorganic particles that are coupled, via a coupling agent, to the organic matrix. The low dielectric constant of the composite is attributable to the microporous organic polymer matrix. The inorganic particles are responsible, at least in part, for providing thermal stability and other required physico-chemical properties to the composite.

Claims

1. A method for forming a three-phase composite precursor formulation suitable for forming an interlayer dielectric, comprising the step of:

forming a mixture of (i) an organic-component precursor present in an amount in the range of about 40 to 90 weight percent of the mixture;

(ii) an inorganic-component precursor or a reaction product thereof having an organic functionality, wherein the organic functionality is selected for its ability to form a link to the organic-component precursor or a reaction product thereof, and further wherein the inorganic-component precursor or its reaction product is present in an amount in the range of between about 1 to 50 weight percent based on the combined amount of the inorganic-component precursor and the organic-component precursor in the mixture; and

(iii) a microporosity-generating agent.

2. The method of claim 1, and further wherein the organic functionality is provided by combining the inorganic-component precursor or the reaction product thereof with a coupling agent.

3. The method of claim 2, and further wherein the coupling agent has an inorganic functionality, wherein the inorganic functionality is selected for its ability to form a link to the inorganic-component precursor or the reaction product thereof.

4. The method of claim 1, and further wherein the inorganic-component precursor is an organometallic compound.

5. The method of claim 4, and further wherein the organometallic compound is selected from the group consisting of metal alkoxides and modified-metal alkoxides.

6. The method of claim 5, and further wherein the modified-metal alkoxide contains fluorine.

7. The method of claim 1, and further wherein the reaction product of the inorganic-component precursor is an inorganic component, wherein the inorganic component is a suspension of inorganic particles containing a metal and characterized by an average particle size of less than about one micron.

8. The method of claim 7, and further wherein the organic functionality is provided by a coupling agent.

9. The method of claim 8, and further wherein the coupling agent is present in an amount sufficient for coupling an amount of the inorganic component to a reaction product of the organic-component precursor.

10. The method of claim 1, and further wherein the inorganic-component precursor or the reaction product thereof is a reaction product of a coupling agent, wherein the organic functionality is provided by the coupling agent.

11. The method of claim 1, and further comprising the step of depositing the three-phase composite precursor formulation on a substrate.

12. The method of claim 11, and further wherein the step of depositing comprises spin coating.

13. The method of claim 11, and further comprising the step of generating a three-phase composite from the deposited three-phase precursor formulation.

14. The method of claim 13, and further wherein the step of generating comprises thermally processing the deposited three phase precursor formulation.

15. The method of claim 14, and further wherein thermally processing the deposited three-phase precursor formulation comprises the step of chemically reacting the organic-component precursor.

16. The method of claim 15, and further comprising causing the microporosity-generating agent to undergo a reaction that generates microporosity while the organic-component precursor is chemically reacted.