Antistatic composition

• US 5,965,206 A
• Filed: 09/08/1997
• Issued: 10/12/1999
• Est. Priority Date: 09/16/1996
• Status: Expired due to Term

• Current Assignee: Ciba Specialty Chemicals Corp (BASF SE)
• Original Assignee: Ciba Specialty Chemicals Corp (BASF SE)
• Inventors: Grob, Markus, Minder, Ernst, Pfeiffer, Jurgen, Hilti, Bruno
• Primary Examiner(s): Hoke, Veronica P.
• Application Number:
  US08/925,015
• Time in Patent Office: 764 Days
• Field of Search: 428/357, 427/393.1, 524/911, 524/405, 524/415, 524/423, 524/436
• US Class Current: 427/393.1
• CPC Class Codes: C08L 101/00 Compositions of unspecified macromolecular compounds
• CPC Class Codes: C08L 2201/04 Antistatic
• CPC Class Codes: C08L 23/06 Polyethene
• CPC Class Codes: C08L 2666/02 Organic macromolecular compounds, natural resins, waxes or and bituminous materials
• CPC Class Codes: C08L 77/02 Polyamides derived from omega-amino carboxylic acids or from lactams thereof C08L77/10 takes precedence
• CPC Class Codes: Y10S 524/911 Composition to apply to a substrate to be destaticized
• CPC Class Codes: Y10T 428/29 Coated or structually defined flake, particle, cell, strand, strand portion, rod, filament, macroscopic fiber or mass thereof

Abstract

The invention relates to a composition that comprises a thermoplastic or elastomeric polymeric substrate (A) and an antistatic mixture (B) in the form of contiguous fibers, which mixture comprises (b1) an organic polymeric material that is fibrous or forms fibers on mixing and is not soluble in the thermoplastic or elastomeric polymeric substrate (A); (b2) a polymer or copolymer capable of ion conduction that has blocks for complexing or solvating a salt of an inorganic or low-molecular-weight organic protonic acid (b3) and has a better compatibility with the organic polymer (b1) that is fibrous or forms fibers on mixing than with the polymeric organic substrate (A); and (b3) a salt of an inorganic or low-molecular-weight organic protonic acid such as NaClO₄ or K P F₆ that has been complexed or solvated in the polymer or copolymer (b2). The invention relates also to the antistatic mixture (B) as such, to its use in rendering polymers antistatic and to a process for the preparation of antistatic thermoplastic or elastomeric polymeric substrates.

Claims

1. A composition comprising a thermoplastic or elastomeric polymeric substrate-forming material (A) and an antistatic mixture (B) in the form of contiguous fibres, which mixture comprises

(b1) an organic polymeric material that is fibrous or forms fibres on mixing and is not soluble in the thermoplastic or elastomeric polymeric substrate-forming material (A) which is selected from the group consisting of a polyacrylic acid ester, polymethacrylic acid ester, polyacrylonitrile, polyvinyl alchol, polyvinyl acetate, polyamide, polyurethane or polyester;

(b2) a polymer or copolymer capable of ionic charge conduction that has blocks for complexing or solvating a salt of an inorganic protonic acid, which is selected from the group consisting of polyether urea, polyether amide, polyether ester amide or polyether ester; and

(b3) a salt selected from the group consisting of LiClO₄, LiCF₃ SO₃, NaClO₄, LiBF₄, NaBF₄, KBF₄, NaCF₃ SO₃, KClO₄, KPF₆, KCF₃ SO₃, KC₄ F₉ SO₃, Ca(ClO₄)₂, Ca(PF₆)₂, Mg(ClO₄)₂, Mg(CF₃ SO₃)₂, Zn(ClO₄)₂, Zn(PF₆)₂ or Ca(CF₃ SO₃)₂, that has been complexed or solvated in the polymer or copolymer (b2).

2. A composition according to claim 1, wherein component (A) is a polyolefin, a polystyrene, a copolymer of acrylonitrile/butadiene/styrene (ABS), a polymer of α

,β

-unsaturated acids, a halogen-containing polymer, a homo- or co-polymer of cyclic ethers, a polymer of unsaturated alcohols and amines, a polyacetal, a polyphenylene oxide, a polyurethane, a polyamide, a polyester, a polyurea, a polycarbonate, a polysulfone or natural rubber.

3. A composition according to claim 2, wherein component (A) is a polyolefin, a polystyrene, an acrylonitrile/butadiene/styrene (ABS) copolymer, a polymer of α

,β

-unsaturated acids, a halogen-containing polymer or a homo- or co-polymer of cyclic ethers.

4. A composition according to claim 3, wherein component (A) is polyvinyl chloride (PVC), polyethylene, polystyrene or polypropylene.

5. A composition according to claim 1, wherein the polymeric material (b1) that is fibrous or forms fibres on mixing is a polyester, polyamide (x) or polyamide (x,y) in which x and y are each independently a number from 4 to 14.

6. A composition according to claim 1, wherein the polymer or copolymer (b2) is a block copolymer polyether ester amide in which the polyether segments consist of polyethylene glycol units having a molecular weight M_n of from 200 to 6000 daltons and the polyamide segments consist of polyamide (x) or polyamide (x,y) having a molecular weight M_n of from 200 to 6000 daltons, x and y being a number from 4 to 14.

7. A composition according to claim 1, wherein the inorganic salt (b3) is present in an amount of from 0.05 to 10% by weight, based on the copolymer (b2).

8. A composition according to claim 7, wherein the inorganic salt (b3) is present in an amount of from 0.5 to 5% by weight, based on the copolymer (b2).

9. A composition according to claim 1, wherein the ratio by mass of organic polymeric material (b1) that is fibrous or forms fibres on mixing to copolymer (b2) is from 20:

1 to 1;

10.

10. A composition according to claim 9, wherein the ratio by mass of organic polymeric material (b1) that is fibrous or forms fibres on mixing to copolymer (b2) is from 10:

1 to 1;

3.

11. A composition according to claim 1, wherein the antistatically active mixture of components (b1), (b2) and (b3) is present in a total amount of from 0.1 to 15% by weight, based on the thermoplastic or elastomeric polymeric substrate.

12. A composition according to claim 1, wherein the thermoplastic or elastomeric polymeric substrate (A) is PVC, polyethylene or polypropylene, the fibrous or fibre-forming organic polymeric material (b1) is a polyester or a polyamide, the copolymer (b2) capable of ion conduction is a polyether ester amide or a polyether ester and the inorganic salt of a protonic acid (b3) is NaClO₄, KPF₆ or LiCF₃ SO₃.

13. An antistatic mixture for a thermoplastic or elastomeric polymeric-substrate forming material comprising

(b1) an organic polymeric material that is fibrous or forms fibres on mixing and is not soluble in thermoplastic or elastomeric polymeric substrate-forming material (A) which is selected from the group consisting of a polyacrylic acid ester, polymethacrylic acid ester, polyacrylonitrile, polyvinyl alcohol, polyvinyl acetate, polyamide, polyurethane or polyester;

(b2) a polymer or copolymer capable of ionic charge conduction that has blocks for complexing or solvating a salt of an inorganic protonic acid, which is selected from the group consisting of polyether urea, polyether amide, polyether ester amide or polyether ester; and

(b3) a salt selected from the group consisting of LiClO₄, LiCF₃ SO₃, NaClO₄, LiBF₄, NaBF₄, KBF₄, NaCF₃ SO₃, KClO₄, KPF₆, KCF₃ SO₃, KC₄ F₉ SO₃, Ca(ClO₄)₂, Ca(PF₆)₂, Mg(ClO₄)₂, Mg(CF₃ SO₃)₂, Zn(ClO₄)₂, Zn(PF₆)₂ or Ca(CF₃ SO₃)₂, that has been complexed or solvated in the polymer or copolymer (b2).

14. A process for the preparation of an antistatic thermoplastic or elastomeric polymeric substrate-forming material (A) which comprises incorporating an antistatic mixture (B) comprising

(b1) an organic polymeric material that is fibrous or forms fibres on mixing and is not soluble in the thermoplastic or elastomeric polymeric substrate-forming material (A) which is selected from the group consisting of a polyacrylic acid ester, polymethacrylic acid ester, polyacrylonitrile, polyvinyl alchol, polyvinyl acetate, polyamide, polyurethane or polyester;

(b2) a polymer or copolymer capable of ionic charge conduction that has blocks for complexing or solvating a salt of an inorganic protonic acid, which is selected from the group consisting of polyether urea, polyether amide, polyether ester amide or polyether ester; and

(b3) a salt selected from the group consisting of LiClO₄, LiCF₃ SO₃, NaClO₄, LiBF₄, NaBF₄, KBF₄, NaCF₃ SO₃, KClO₄, KPF₆, KCF₃ SO₃, KC₄ F₉ SO₃, Ca(ClO₄)₂, Ca(PF₆)₂, Mg(ClO₄)₂, Mg(CF₃ SO₃)₂, Zn(ClO₄)₂, Zn(PF₆)₂ or Ca(CF₃ SO₃)₂, that has been complexed or solvated in the polymer or copolymer (b2).